公开(公告)号：US09962688B2

公开(公告)日：2018-05-08

申请号：US15316119

申请日：2014-04-10

Applicant: BEIJING UNIVERSITY OF CHEMICAL TECHNOLOGY

Inventor： Runduo Zhang ,  Biaohua Chen ,  Ruinian Xu

IPC: B01J29/70 ,  C01B39/48 ,  B01J20/18 ,  B01J20/30 ,  B01J35/02 ,  B01J37/00 ,  B01J37/06 ,  B01J37/08 ,  B01J37/10 ,  C07C1/20

CPC classification number: B01J29/70 ,  B01J20/18 ,  B01J20/3071 ,  B01J20/3085 ,  B01J29/723 ,  B01J35/02 ,  B01J37/0018 ,  B01J37/06 ,  B01J37/082 ,  B01J37/10 ,  C01B39/48 ,  C01P2002/72 ,  C07C1/20 ,  C07C2529/70 ,  Y02P20/52 ,  Y02P30/42 ,  C07C11/04 ,  C07C11/06

Abstract: A method for synthesizing a crystalline molecular sieve SSZ-13, characterized in that the method comprises bringing the following raw materials into contact in water under a crystallization condition: at least one tetravalent silicon source, at least one trivalent aluminum source, at least one alkali metal compound, choline cations and/or SSZ-13 seed crystals, and hydroxide ions. The method avoids using benzyl trimethyl quaternary ammonium ions (BzTMA+) or N,N,N-trimethyl-1-amantadine cations as structure-directing agents, and obtains high-quality crystal molecular sieve SSZ-13. Due to the use of a low-cost nontoxic structure-directing agent, the method has low production price by employing a low-cost nontoxic template, and can be popularized for application.