公开(公告)号：US11753486B2

公开(公告)日：2023-09-12

申请号：US16771306

申请日：2018-12-20

Applicant: BOREALIS AG

Inventor： Alexander Reznichenko ,  Jari-Jussi Ruskeeniemi ,  Joseph Thorman ,  Xiao Dong Chen ,  Victor Sumerin

IPC: C08F4/02 ,  C08F4/654 ,  B01J2/04 ,  B01D1/18 ,  B01D1/20 ,  C08F4/651 ,  B01J4/00 ,  C08F210/16

CPC classification number: C08F4/651 ,  B01J2/04 ,  B01J4/002 ,  C08F4/022 ,  C08F4/6543 ,  C08F210/16 ,  B01D1/18 ,  B01D1/20 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/24

Abstract: The present invention relates to a process for producing of solid particulate olefin polymerisation catalyst or catalyst carrier comprising forming a solution of the catalyst or a catalyst carrier in a solvent, subjecting the solution into an atomization by spraying the solution via a capillary vibrating spray nozzle with a capillary orifice having a diameter of 5 to 100 μm generating a laminar jet of liquid, which disintegrates into liquid droplets entering into the spray-dryer, transforming the droplets with aid of a gas to solid particulate catalyst or carrier in the spray-dryer and recovering the solid particulate olefin polymerisation catalyst or carrier having particle size distribution defined by a volumetric SPAN of 0.7 or less. The invention further relates to the catalyst produced by the methods, and use thereof in olefin polymerisation process.

公开(公告)号：US11384170B2

公开(公告)日：2022-07-12

申请号：US16771307

申请日：2018-12-19

Applicant: BOREALIS AG

Inventor： Alexander Reznichenko ,  Noureddine Ajellal ,  Joseph Thorman ,  Bernard Binks

IPC: C08F4/6592 ,  C08F10/02 ,  C08F10/06 ,  C07F7/00 ,  C08F4/659

Abstract: A process for the preparation of a solid olefin polymerization catalyst or a solid olefin polymerization catalyst component comprising the steps of: (a) forming a liquid/liquid emulsion of (i) a first organic liquid comprising at least one olefin polymerization catalyst component and (ii) an optionally halogenated hydrocarbon liquid immiscible therewith; where the first organic liquid forms the dispersed phase and the optionally halogenated hydrocarbon liquid forms the continuous phase of the liquid/liquid emulsion and wherein the dispersed phase forms droplets in the continuous phase; and (b) transforming the droplets of the dispersed phase to solid particulate particles comprising said at least one olefin polymerization catalyst component, wherein the liquid/liquid emulsion is stabilized with a solid particulate stabilizer.

公开(公告)号：US12104001B2

公开(公告)日：2024-10-01

申请号：US18196110

申请日：2023-05-11

Applicant: BOREALIS AG

Inventor： Alexander Reznichenko ,  Jari-Jussi Ruskeeniemi ,  Joseph Thorman ,  Xiao Dong Chen ,  Victor Sumerin

IPC: C08F4/651 ,  B01J2/04 ,  B01J4/00 ,  B01J4/02 ,  C08F4/02 ,  C08F4/654 ,  C08F210/16 ,  B01D1/18 ,  B01D1/20

CPC classification number: C08F4/651 ,  B01J2/04 ,  B01J4/002 ,  C08F4/022 ,  C08F4/6543 ,  C08F210/16 ,  B01D1/18 ,  B01D1/20 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/24

Abstract: The present invention relates to a process for producing of solid particulate olefin polymerisation catalyst or catalyst carrier comprising forming a solution of the catalyst or a catalyst carrier in a solvent, subjecting the solution into an atomization by spraying the solution via a capillary vibrating spray nozzle with a capillary orifice having a diameter of 5 to 100 μm generating a laminar jet of liquid, which disintegrates into liquid droplets entering into the spray-dryer, transforming the droplets with aid of a gas to solid particulate catalyst or carrier in the spray-dryer and recovering the solid particulate olefin polymerisation catalyst or carrier having particle size distribution defined by a volumetric SPAN of 0.7 or less. The invention further relates to the catalyst produced by the methods, and use thereof in olefin polymerisation process.

公开(公告)号：US20210340288A1

公开(公告)日：2021-11-04

申请号：US17299953

申请日：2019-12-19

Applicant: BOREALIS AG

Inventor： Timo Leinonen ,  Peter Denifl ,  Alexander Reznichenko ,  Frrank Schröder

IPC: C08F4/642 ,  C08F110/06

Abstract: The present invention relates to a process for producing solid Ziegler-Natta catalyst component in the form of solid particles having a median particle size (D50vol) of 5 to 500 μm the process comprising steps I. providing a solution of a mixture of Group 2 metal compounds of i) a solution of a Group 2 metal dihalide and ii) at least one Group 2 metal alkoxide of the Periodic Table (IUPAC, Nomenclature of Inorganic Chemistry, 2005) II. contacting the solution of the mixture of Group 2 metal compounds of step I with a compound in a liquid form of a transition metal of Group 4 to 10, or of a lanthanide or actinide, preferably a transition metal of Group 4 to 6 of Periodic Table (IUPAC, Nomenclature of Inorganic Chemistry, 2005), and III. recovering the solid catalyst component, wherein the solution of a Group 2 metal dihalide i) is obtained by dissolving a solid Group 2 metal dihalide in an alcohol comprising at least a monohydric alcohol of formula ROH, where R is selected from hydrocarbyl of 3 to 16 C atoms, and wherein the amount of Group 2 metal originating from Group 2 metal dihalide in the solution of the mixture of Group 2 metal compounds is in the range of 5 to 90 mol-%. The invention further relates to a catalyst comprising the catalyst component and use thereof in olefin polymerisation process.

公开(公告)号：US11827733B2

公开(公告)日：2023-11-28

申请号：US17299953

申请日：2019-12-19

Applicant: BOREALIS AG

Inventor： Timo Leinonen ,  Peter Denifl ,  Alexander Reznichenko ,  Frank Schröder

IPC: C08F4/642 ,  C08F110/06 ,  C08F4/02

CPC classification number: C08F4/6421 ,  C08F110/06 ,  C08F2410/06

Abstract: The present invention relates to a process for producing solid Ziegler-Natta catalyst component in the form of solid particles having a median particle size (D50vol) of 5 to 500 μm the process comprising steps I. providing a solution of a mixture of Group 2 metal compounds of i) a solution of a Group 2 metal dihalide and ii) at least one Group 2 metal alkoxide of the Periodic Table (IUPAC, Nomenclature of Inorganic Chemistry, 2005) II. contacting the solution of the mixture of Group 2 metal compounds of step I with a compound in a liquid form of a transition metal of Group 4 to 10, or of a lanthanide or actinide, preferably a transition metal of Group 4 to 6 of Periodic Table (IUPAC, Nomenclature of Inorganic Chemistry, 2005), and III. recovering the solid catalyst component, wherein the solution of a Group 2 metal dihalide i) is obtained by dissolving a solid Group 2 metal dihalide in an alcohol comprising at least a monohydric alcohol of formula ROH, where R is selected from hydrocarbyl of 3 to 16 C atoms, and wherein the amount of Group 2 metal originating from Group 2 metal dihalide in the solution of the mixture of Group 2 metal compounds is in the range of 5 to 90 mol-%. The invention further relates to a catalyst comprising the catalyst component and use thereof in olefin polymerisation process.

公开(公告)号：US09670293B2

公开(公告)日：2017-06-06

申请号：US14914501

申请日：2014-10-22

Applicant: BOREALIS AG

Inventor： Alexander Reznichenko ,  Noureddine Ajellal ,  Pascal Castro ,  Irfan Saeed

IPC: C08F4/649 ,  C08F4/6592 ,  C08F10/00 ,  C08F4/659

CPC classification number: C08F10/00 ,  C08F4/649 ,  C08F4/65912 ,  C08F4/6592 ,  C08F4/65925 ,  C08F4/65927 ,  C08F2410/01 ,  C08F10/06 ,  C08F110/06 ,  C08F2500/12 ,  C08F210/16 ,  C08F210/14 ,  C08F110/02 ,  C08F2500/01

Abstract: Process for the preparation of a solid catalyst system comprising the steps of preparing a liquid clathrate comprising a mixing of an aluminoxane, an aromatic compound and an organo-silicon compound, wherein the mol-ratio between the organo-silicon compound and aluminum of the aluminoxane is below 0.1, mixing said liquid clathrate with an organometallic compound obtaining a liquid mixture, and precipitating the solid catalyst system out of said liquid mixture by adding a saturated aliphatic compound to said mixture liquid.