公开(公告)号：US20220186123A1

公开(公告)日：2022-06-16

申请号：US17554218

申请日：2021-12-17

Applicant: BP P.L.C.

Inventor： Alexander James PATERSON

IPC: C10G2/00 ,  B01J23/889 ,  B01J35/00 ,  B01J37/02

Abstract: A process for converting a mixture of hydrogen and carbon monoxide gases to a composition comprising alcohols and liquid hydrocarbons by means of a Fischer-Tropsch synthesis reaction, said process comprising contacting a mixture of hydrogen and carbon monoxide gases, preferably in the form of synthesis gas mixture, with a supported Co—Mn Fischer-Tropsch synthesis catalyst, wherein: the support material of the supported Co—Mn Fischer-Tropsch synthesis catalyst comprises a material selected from titania, zinc oxide, zirconia, and ceria; the supported synthesis catalyst comprises at least 2.5 wt % of manganese, on an elemental basis, based on the total weight of the supported synthesis catalyst; the weight ratio of manganese to cobalt, on an elemental basis, is 0.2 or greater; the molar ratio of hydrogen to carbon monoxide is at least 1; and, the Fischer-Tropsch synthesis reaction is conducted at a pressure in the range of from 1.0 to 10.0 MPa absolute.

公开(公告)号：US20190193068A1

公开(公告)日：2019-06-27

申请号：US16327824

申请日：2017-08-18

Applicant: BP P.L.C.

Inventor： Ewen James FERGUSON ,  Manuel OJEDA PINEDA ,  Alexander James PATERSON

IPC: B01J38/10 ,  B01J23/94 ,  B01J23/75 ,  B01J23/80 ,  B01J23/889 ,  B01J21/06 ,  C10G2/00

Abstract: The present invention relates to a process for treating a catalyst to improve performance, and more specifically to a process for treating a Fischer-Tropsch catalyst using a high hydrogen syngas to improve catalyst performance.

公开(公告)号：US20200156049A1

公开(公告)日：2020-05-21

申请号：US16485371

申请日：2018-02-09

Applicant: BP P.L.C.

Inventor： Manuel OJEDA PINEDA ,  Alexander James PATERSON

IPC: B01J23/889 ,  B01J23/75 ,  B01J35/02 ,  B01J37/02 ,  B01J21/06 ,  B01J37/00 ,  B01J35/00 ,  C10G2/00 ,  B01J37/18 ,  B01J37/08

Abstract: The present invention relates to a process for conveniently preparing a supported cobalt-containing Fischer-Tropsch synthesis catalyst having improved activity and selectivity for C5+ hydrocarbons. In one aspect, the present invention provides a process for preparing a supported cobalt-containing Fischer-Tropsch synthesis catalyst, said process comprising the steps of: (a) impregnating a support material with: i) a cobalt-containing compound and ii) acetic acid, or a manganese salt of acetic acid, in a single impregnation step to form an impregnated support material; and (b) drying and calcining the impregnated support material; wherein the support material impregnated in step (a) has not previously been modified with a source of metal other than cobalt; and wherein when the cobalt-containing compound is cobalt hydroxide, a manganese salt of acetic acid is not used in step (a) of the process.