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公开(公告)号:US12084381B2
公开(公告)日:2024-09-10
申请号:US17117465
申请日:2020-12-10
Applicant: CORNING INCORPORATED
Inventor: Peter Joseph Lezzi , Liying Zhang
CPC classification number: C03C3/087 , C03C21/002
Abstract: Ion-exchanged alkali aluminosilicate glass articles with a ratio of peak compressive stress value to Young's modulus value of 14 or more. The glass articles may include Al2O3 mol %+RO mol %≥18 mol %, where RO mol %=MgO mol %+CaO mol %, and be substantially free of ZnO, SrO, BaO, B2O3, P2O5, Li2O, and K2O. The glass articles may have a peak compressive stress value in a range of 850 MPa to 1400 MPa. The glass articles are suitable for various high-strength applications, including cover glass applications that experience significant bending stresses during use, for example, cover glasses for flexible displays.
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公开(公告)号:US20240391827A1
公开(公告)日:2024-11-28
申请号:US18669842
申请日:2024-05-21
Applicant: CORNING INCORPORATED
Inventor: Jonathan Thomas Beall , Nikolaus Jon Deems , Yuhui Jin , Xinghua Li , Ying Liu , Lei Yuan , Liying Zhang
Abstract: A light-transmitting structure is disclosed. The light-transmitting structure includes a laminated glass substrate that has a core layer and a first clad layer fused to a first side of the core layer. The core layer comprises a core glass composition that is transparent and has a core refractive index nC. The first clad layer defines a first surface of the laminated glass substrate and comprises a first clad glass composition that is transparent and has a first clad refractive index nCL1 that is lower than the core refractive index nC. The light-transmitting structure further includes a plurality of interdiffusion regions that extend from the core layer and through the first clad layer to define a light-scattering surface interposed with the first surface. Each interdiffusion region comprises an interdiffusion composition that is transparent and has an interdiffusion refractive index nI that is higher than the first clad refractive index nCL1.
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公开(公告)号:US12084373B2
公开(公告)日:2024-09-10
申请号:US17435539
申请日:2020-02-24
Applicant: CORNING INCORPORATED
Inventor: Heather Debra Boek , Timothy Michael Gross , Jin Su Kim , Jesse Kohl , Hung Cheng Lu , Yu Xiao , Liying Zhang , Lu Zhang
CPC classification number: C03B17/02 , B32B17/06 , C03B17/064 , C03C3/091 , C03C3/093 , B32B2307/30
Abstract: Methods for manufacturing glass articles having a target effective coefficient of thermal expansion CTETeff averaged over a temperature range comprise selecting a glass core composition having an average core glass coefficient of thermal expansion CTEcore that is greater than the target effective CTETeff and a glass clad composition having an average clad glass coefficient of thermal expansion CTEclad that is less than the target effective CTETeff; and manufacturing a glass laminate comprising a glass core layer formed from the glass core composition and two or more glass cladding layers fused to the glass core layer, each of the two or more glass cladding layers formed from the glass clad composition such that a ratio of a thickness of the glass core layer to a total thickness of the two or more glass cladding layers is selected to produce the glass laminate having an effective coefficient of thermal expansion CTEeff that is within ±0.5 ppm/° C. of the target effective CTETeff.
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公开(公告)号:US11554984B2
公开(公告)日:2023-01-17
申请号:US16272305
申请日:2019-02-11
Applicant: Corning Incorporated
Inventor: Timothy Michael Gross , Yuhui Jin , Ruchirej Yongsunthon , Liying Zhang
Abstract: An article comprises a glass substrate. The glass substrate has a first surface having a plurality of vias therein, and a second surface parallel to the first surface. At least one of the first surface and the second surface is an etched surface having a surface roughness (Ra) of 0.75 nm or less. The glass substrate comprises, in mol percent on an oxide basis: 65 mol %≤SiO2≤75 mol %; 7 mol %≤Al2O3≤15 mol %; 26.25 mol %≤RO+Al2O3−B2O3; 0 mol %≤R2O≤2 mol %. RO=MgO+CaO+SrO+BaO+ZnO. R2O=Li2O+Na2O+K2O+Rb2O+Cs2O.
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公开(公告)号:US20170174559A1
公开(公告)日:2017-06-22
申请号:US15384687
申请日:2016-12-20
Applicant: CORNING INCORPORATED
CPC classification number: C03C8/02 , B32B17/06 , B32B2457/20 , C03C3/091 , C03C3/093 , C03C2207/00 , H05K5/0017 , H05K5/03
Abstract: According to one embodiment, a glass may include from about 50 mol. % to about 70 mol. % SiO2; from about 12 mol. % to about 35 mol. % B2O3; from about 4 mol. % to about 12 mol. % Al2O3; greater than 0 mol. % and less than or equal to 1 mol. % alkali metal oxide, wherein Li2O is greater than or equal to about 20% of the alkali metal oxide; from about 0.3 mol. % to about 0.7 mol. % of Na2O or Li2O; and greater than 0 mol. % and less than 12 mol. % of total divalent oxide, wherein the total divalent oxide includes at least one of CaO, MgO and SrO, and wherein a ratio of Li2O (mol. %) to (Li2O (mol. %) +(Na2O (mol. %)) is greater than or equal 0.4 and less than or equal to 0.6. The glass may have a relatively low high temperature resistivity and a relatively high low temperature resistivity.
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公开(公告)号:US20240400434A1
公开(公告)日:2024-12-05
申请号:US18800607
申请日:2024-08-12
Applicant: CORNING INCORPORATED
Inventor: Heather Debra Boek , Timothy Michael Gross , Jin Su Kim , Jesse Kohl , HungCheng Lu , Yu Xiao , Liying Zhang , Lu Zhang
Abstract: Methods for manufacturing glass articles having a target effective coefficient of thermal expansion CTETeff averaged over a temperature range comprise selecting a glass core composition having an average core glass coefficient of thermal expansion CTEcore that is greater than the target effective CTETeff and a glass clad composition having an average clad glass coefficient of thermal expansion CTEclad that is less than the target effective CTETeff; and manufacturing a glass laminate comprising a glass core layer formed from the glass core composition and two or more glass cladding layers fused to the glass core layer, each of the two or more glass cladding layers formed from the glass clad composition such that a ratio of a thickness of the glass core layer to a total thickness of the two or more glass cladding layers is selected to produce the glass laminate having an effective coefficient of thermal expansion CTEeff that is within ±0.5 ppm/° C. of the target effective CTETeff.
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公开(公告)号:US20230265007A1
公开(公告)日:2023-08-24
申请号:US18111717
申请日:2023-02-20
Applicant: CORNING INCORPORATED
Inventor: Qiang Fu , Mitchell Bruce Haller , Martha Rose Jesuit , Adam Thomas Shearer , Liying Zhang
CPC classification number: C03C10/00 , C03B32/02 , C03C2204/00
Abstract: A silicate-based composition includes, in mol.%: 35-65% SiO2, 20-40% CaO, 10-30% Na2O, 0-15% TiO2, >0-15% Al2O3, 0-10% P2O5, 0-15% ZrO2, and 0-3% SnO2. A method of forming a silicate-based composition includes ceramming a silicate-based composition such that the ceramming is a cycle has a first portion and a second portion, with the first portion conducted at a first temperature for a first time and the second portion conducted at a second temperature for a second time.
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公开(公告)号:US10329186B2
公开(公告)日:2019-06-25
申请号:US15384687
申请日:2016-12-20
Applicant: CORNING INCORPORATED
Abstract: According to one embodiment, a glass may include from about 50 mol. % to about 70 mol. % SiO2; from about 12 mol. % to about 35 mol. % B2O3; from about 4 mol. % to about 12 mol. % Al2O3; greater than 0 mol. % and less than or equal to 1 mol. % alkali metal oxide, wherein Li2O is greater than or equal to about 20% of the alkali metal oxide; from about 0.3 mol. % to about 0.7 mol. % of Na2O or Li2O; and greater than 0 mol. % and less than 12 mol. % of total divalent oxide, wherein the total divalent oxide includes at least one of CaO, MgO and SrO, and wherein a ratio of Li2O (mol. %) to (Li2O (mol. %)+(Na2O (mol. %)) is greater than or equal 0.4 and less than or equal to 0.6. The glass may have a relatively low high temperature resistivity and a relatively high low temperature resistivity.
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公开(公告)号:US20210179482A1
公开(公告)日:2021-06-17
申请号:US17117465
申请日:2020-12-10
Applicant: CORNING INCORPORATED
Inventor: PETER JOSEPH LEZZI , Liying Zhang
Abstract: Ion-exchanged alkali aluminosilicate glass articles with a ratio of peak compressive stress value to Young's modulus value of 14 or more. The glass articles may include Al2O3 mol %+RO mol %≥18 mol %, where RO mol %=MgO mol %+CaO mol %, and be substantially free of ZnO, SrO, BaO, B2O3, P2O5, Li2O, and K2O. The glass articles may have a peak compressive stress value in a range of 850 MPa to 1400 MPa. The glass articles are suitable for various high-strength applications, including cover glass applications that experience significant bending stresses during use, for example, cover glasses for flexible displays.
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公开(公告)号:US20240391823A1
公开(公告)日:2024-11-28
申请号:US18665998
申请日:2024-05-16
Applicant: CORNING INCORPORATED
Inventor: Jonathan Thomas Beall , Nikolaus Jon Deems , Yuhui Jin , Xinghua Li , Ying Liu , Lei Yuan , Liying Zhang
Abstract: A light-transmitting structure is disclosed. The light-transmitting structure includes a glass-based substrate that has a first major surface and a second major surface opposite the first major surface. The glass-based substrate comprises a first composition that is transparent and has a first refractive index n1. The light-transmitting structure further includes a plurality of surface regions fused with the glass-based substrate to define a light-scattering surface interposed with the first major surface. Each surface region comprises a second composition that is transparent and has a second refractive index n2 that is different than the first refractive index n1. The first major surface and the light-scattering surface define an interface to an ambient environment.
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