公开(公告)号：US09473459B2

公开(公告)日：2016-10-18

申请号：US13678595

申请日：2012-11-16

Applicant: Cytec Technology Corp.

Inventor： Yiqiang Zhao ,  Dalip Kumar Kohli ,  Kunal Gaurang Shah

IPC: C09J7/04 ,  B32B37/16 ,  H04L29/06 ,  H04W12/06 ,  H04W12/08 ,  H04W4/00 ,  G06F9/445 ,  G06F9/455 ,  G06F3/0482 ,  G06F3/0484 ,  H04M1/725 ,  H04W76/02 ,  H04L12/24 ,  H04W68/12

CPC classification number: H04L63/108 ,  B32B5/024 ,  B32B27/12 ,  B32B27/38 ,  B32B37/025 ,  B32B37/12 ,  B32B37/16 ,  B32B2037/1253 ,  C08J5/128 ,  C08J5/24 ,  C08J2363/04 ,  C08J2367/00 ,  C09J7/21 ,  C09J7/30 ,  C09J163/04 ,  C09J2463/00 ,  C09J2467/006 ,  G06F3/0482 ,  G06F3/04842 ,  G06F9/445 ,  G06F9/455 ,  G06F9/45529 ,  G06F9/45558 ,  G06F21/6245 ,  G06F21/629 ,  G06F2009/45587 ,  G06F2009/45595 ,  H04L41/0853 ,  H04L63/0272 ,  H04L63/102 ,  H04L63/105 ,  H04L63/20 ,  H04L67/34 ,  H04M1/72522 ,  H04M1/72583 ,  H04W4/50 ,  H04W4/60 ,  H04W8/22 ,  H04W12/06 ,  H04W12/08 ,  H04W68/12 ,  H04W76/10 ,  Y10T428/14

Abstract: A resin-rich peel ply that does not leave behind residual fibers after peeling and can work well with different resin-based composite substrates. The resin-rich peel ply is composed of a woven fabric impregnated with a resin matrix different from the resin matrix of the composite substrate. The peel ply is designed such that, upon manual removal of the peel ply from the composite substrate's surface, a thin film of the peel ply resin remains on the composite substrate's surface to create a bondable surface capable of bonding with another composite substrate, but no fibrous material from the woven fabric remains on the same surface.

Abstract translation: 富含树脂的剥离层，剥离后不留下残余纤维，可以与不同的树脂基复合基材一起使用。 富含树脂的剥离层由浸渍有与复合基材的树脂基体不同的树脂基体的机织织物组成。 剥离层被设计成使得当从复合基材的表面手工去除剥离层时，剥离树脂树脂的薄膜残留在复合基材的表面上以形成能够与另一复合基材结合的可结合表面，但没有 来自机织织物的纤维材料保留在相同的表面上。

公开(公告)号：US08974905B2

公开(公告)日：2015-03-10

申请号：US14512642

申请日：2014-10-13

Applicant: Cytec Technology Corp.

Inventor： Junjie Jeffrey Sang ,  Dalip Kumar Kohli ,  Kunal Gaurang Shah

IPC: B32B27/38 ,  B32B7/12 ,  B32B27/20 ,  B32B27/26 ,  C08G59/40 ,  C08G59/68 ,  C08K7/00 ,  C08K7/16 ,  C08K5/41 ,  C09J7/00 ,  C09J9/00 ,  C09J11/08 ,  C09J163/00 ,  B32B27/18 ,  B32B15/092

CPC classification number: C09J163/00 ,  B32B7/12 ,  B32B27/18 ,  B32B27/38 ,  B32B2250/03 ,  B32B2264/0207 ,  B32B2270/00 ,  B32B2405/00 ,  C08G59/4253 ,  C08G59/50 ,  C08G59/5026 ,  C08G59/5073 ,  C08K3/36 ,  C08L63/00 ,  C08L81/06 ,  Y10T428/24995 ,  Y10T428/249951 ,  Y10T428/249952 ,  Y10T428/254 ,  Y10T428/31515 ,  Y10T428/31522 ,  C08L51/04 ,  C08L101/00

Abstract: A structural adhesive composition that is suitable for high-strength bonding of metals and aerospace structural materials. In one embodiment, the structural adhesive composition based on a two-part system, which is curable at or below 200° F. (93° C.). The two-part system is composed of a resinous part (A) and a catalyst part (B), which may be stored separately at room temperature until they are ready to be used. The resinous part (A) includes at least two different multifunctional epoxy resins with different functionality selected from difunctional, trifunctional, and tetrafunctional epoxy resins, certain toughening components, and inorganic filler particles as a rheology/thixotrophy modifying component. The toughening components include core-shell rubber particles with different particle sizes and at least one of an elastomeric polymer and a polyethersulfone polymer. The catalyst part (B) includes an aliphatic or cyclic amine compound as a curing agent and inorganic filler as a rheology/thixotropy modifying component. The weight ratio of part (A) to part (B) is within the range of 3:2 to 10:2. In another embodiment, the structural adhesive composition is based on a one-part system which includes the components of the resinous part (A) in the two-part system mixed with a latent amine curing agent. The one-part system may further include an imidazole and/or an aliphatic amine. The one-part system is curable within the temperature range of 140-300° F. (60-150° C.). The paste adhesive disclosed herein has film-like properties and is particularly useful in rapid-assembly aerospace structure bonding applications.

Abstract translation: 适用于金属和航空航天结构材料的高强度粘合的结构粘合剂组合物。 在一个实施方案中，基于两部分系统的结构粘合剂组合物，其可在等于或低于200°F（93℃）下固化。 两部分系统由树脂部分（A）和催化剂部分（B）组成，可以在室温下分开储存，直到准备使用。 树脂部分（A）包括至少两种具有不同官能度的功能性多官能环氧树脂，其中二官能，三官能和四官能环氧树脂，某些增韧组分和无机填料颗粒作为流变学/触变性改良组分。 增韧组分包括具有不同粒度的核 - 壳橡胶颗粒和弹性体聚合物和聚醚砜聚合物中的至少一种。 催化剂部分（B）包括作为固化剂的脂族或环状胺化合物和作为流变/触变性改性成分的无机填料。 部分（A）与部分（B）的重量比在3:2至10:2的范围内。 在另一个实施方案中，结构粘合剂组合物基于一部分系统，其包括与潜伏胺固化剂混合的两部分体系中的树脂部分（A）的组分。 单组分体系可以进一步包括咪唑和/或脂族胺。 单组分体系可在140-300°F（60-150°C）的温度范围内固化。 本文公开的糊状粘合剂具有膜状特性，并且在快速组装航空航天结构粘合应用中特别有用。

公开(公告)号：US10093081B2

公开(公告)日：2018-10-09

申请号：US15263700

申请日：2016-09-13

Applicant: Cytec Technology Corp.

Inventor： Yiqiang Zhao ,  Dalip Kumar Kohli ,  Kunal Gaurang Shah

IPC: B32B27/12 ,  B32B5/02 ,  C08J5/24 ,  B32B27/38 ,  B32B37/12 ,  B32B37/00 ,  C09J7/04 ,  C08J5/12 ,  C09J163/04

Abstract: A resin-rich peel ply that does not leave behind residual fibers after peeling and can work well with different resin-based composite substrates. The resin-rich peel ply is composed of a woven fabric impregnated with a resin matrix different from the resin matrix of the composite substrate. The peel ply is designed such that, upon manual removal of the peel ply from the composite substrate's surface, a thin film of the peel ply resin remains on the composite substrate's surface to create a bondable surface capable of bonding with another composite substrate, but no fibrous material from the woven fabric remains on the same surface.

公开(公告)号：US20130129957A1

公开(公告)日：2013-05-23

申请号：US13678595

申请日：2012-11-16

Applicant: Cytec Technology Corp.

Inventor： Yiqiang Zhao ,  Dalip Kumar Kohli ,  Kunal Gaurang Shah

IPC: C09J7/04 ,  B32B37/16

CPC classification number: H04L63/108 ,  B32B5/024 ,  B32B27/12 ,  B32B27/38 ,  B32B37/025 ,  B32B37/12 ,  B32B37/16 ,  B32B2037/1253 ,  C08J5/128 ,  C08J5/24 ,  C08J2363/04 ,  C08J2367/00 ,  C09J7/21 ,  C09J7/30 ,  C09J163/04 ,  C09J2463/00 ,  C09J2467/006 ,  G06F3/0482 ,  G06F3/04842 ,  G06F9/445 ,  G06F9/455 ,  G06F9/45529 ,  G06F9/45558 ,  G06F21/6245 ,  G06F21/629 ,  G06F2009/45587 ,  G06F2009/45595 ,  H04L41/0853 ,  H04L63/0272 ,  H04L63/102 ,  H04L63/105 ,  H04L63/20 ,  H04L67/34 ,  H04M1/72522 ,  H04M1/72583 ,  H04W4/50 ,  H04W4/60 ,  H04W8/22 ,  H04W12/06 ,  H04W12/08 ,  H04W68/12 ,  H04W76/10 ,  Y10T428/14

Abstract: A resin-rich peel ply that does not leave behind residual fibers after peeling and can work well with different resin-based composite substrates. The resin-rich peel ply is composed of a woven fabric impregnated with a resin matrix different from the resin matrix of the composite substrate. The peel ply is designed such that, upon manual removal of the peel ply from the composite substrate's surface, a thin film of the peel ply resin remains on the composite substrate's surface to create a bondable surface capable of bonding with another composite substrate, but no fibrous material from the woven fabric remains on the same surface.

Abstract translation: 富含树脂的剥离层，剥离后不留下残余纤维，可以与不同的树脂基复合基材一起使用。 富含树脂的剥离层由浸渍有与复合基材的树脂基体不同的树脂基体的机织织物组成。 剥离层被设计成使得当从复合基材的表面手工去除剥离层时，剥离树脂树脂的薄膜残留在复合基材的表面上以形成能够与另一复合基材结合的可结合表面，但没有 来自机织织物的纤维材料保留在相同的表面上。

公开(公告)号：US20150030844A1

公开(公告)日：2015-01-29

申请号：US14512642

申请日：2014-10-13

Applicant: CYTEC TECHNOLOGY CORP.

Inventor： Junjie Jeffrey Sang ,  Dalip Kumar Kohli ,  Kunal Gaurang Shah

IPC: C09J163/00 ,  B32B27/38 ,  B32B27/18 ,  B32B7/12

CPC classification number: C09J163/00 ,  B32B7/12 ,  B32B27/18 ,  B32B27/38 ,  B32B2250/03 ,  B32B2264/0207 ,  B32B2270/00 ,  B32B2405/00 ,  C08G59/4253 ,  C08G59/50 ,  C08G59/5026 ,  C08G59/5073 ,  C08K3/36 ,  C08L63/00 ,  C08L81/06 ,  Y10T428/24995 ,  Y10T428/249951 ,  Y10T428/249952 ,  Y10T428/254 ,  Y10T428/31515 ,  Y10T428/31522 ,  C08L51/04 ,  C08L101/00

Abstract: A structural adhesive composition that is suitable for high-strength bonding of metals and aerospace structural materials. In one embodiment, the structural adhesive composition based on a two-part system, which is curable at or below 200° F. (93° C.). The two-part system is composed of a resinous part (A) and a catalyst part (B), which may be stored separately at room temperature until they are ready to be used. The resinous part (A) includes at least two different multifunctional epoxy resins with different functionality selected from difunctional, trifunctional, and tetrafunctional epoxy resins, certain toughening components, and inorganic filler particles as a rheology/thixotrophy modifying component. The toughening components include core-shell rubber particles with different particle sizes and at least one of an elastomeric polymer and a polyethersulfone polymer. The catalyst part (B) includes an aliphatic or cyclic amine compound as a curing agent and inorganic filler as a rheology/thixotropy modifying component. The weight ratio of part (A) to part (B) is within the range of 3:2 to 10:2. In another embodiment, the structural adhesive composition is based on a one-part system which includes the components of the resinous part (A) in the two-part system mixed with a latent amine curing agent. The one-part system may further include an imidazole and/or an aliphatic amine. The one-part system is curable within the temperature range of 140-300° F. (60-150° C.). The paste adhesive disclosed herein has film-like properties and is particularly useful in rapid-assembly aerospace structure bonding applications.

Abstract translation: 适用于金属和航空航天结构材料的高强度粘合的结构粘合剂组合物。 在一个实施方案中，基于两部分系统的结构粘合剂组合物，其可在等于或低于200°F（93℃）下固化。 两部分系统由树脂部分（A）和催化剂部分（B）组成，可以在室温下分开储存，直到准备使用。 树脂部分（A）包括至少两种具有不同官能度的功能性多官能环氧树脂，其中二官能，三官能和四官能环氧树脂，某些增韧组分和无机填料颗粒作为流变学/触变性改良组分。 增韧组分包括具有不同粒度的核 - 壳橡胶颗粒和弹性体聚合物和聚醚砜聚合物中的至少一种。 催化剂部分（B）包括作为固化剂的脂族或环状胺化合物和作为流变/触变性改性成分的无机填料。 部分（A）与部分（B）的重量比在3:2至10:2的范围内。 在另一个实施方案中，结构粘合剂组合物基于一部分系统，其包括与潜伏胺固化剂混合的两部分体系中的树脂部分（A）的组分。 单组分体系可以进一步包括咪唑和/或脂族胺。 单组分体系可在140-300°F（60-150°C）的温度范围内固化。 本文公开的糊状粘合剂具有膜状特性，并且在快速组装航空航天结构粘合应用中特别有用。

公开(公告)号：US08895148B2

公开(公告)日：2014-11-25

申请号：US13652724

申请日：2012-10-16

Applicant: Cytec Technology Corp.

Inventor： Junjie Jeffrey Sang ,  Dalip Kumar Kohli ,  Kunal Gaurang Shah

IPC: B32B7/12 ,  B32B15/092 ,  B32B27/20 ,  B32B27/26 ,  B32B27/38 ,  C09J9/00 ,  C09J163/00 ,  C08K3/36 ,  C08K5/41 ,  C08K7/00 ,  C08G59/38 ,  C08G59/50 ,  C08L81/06

CPC classification number: C09J163/00 ,  B32B7/12 ,  B32B27/18 ,  B32B27/38 ,  B32B2250/03 ,  B32B2264/0207 ,  B32B2270/00 ,  B32B2405/00 ,  C08G59/4253 ,  C08G59/50 ,  C08G59/5026 ,  C08G59/5073 ,  C08K3/36 ,  C08L63/00 ,  C08L81/06 ,  Y10T428/24995 ,  Y10T428/249951 ,  Y10T428/249952 ,  Y10T428/254 ,  Y10T428/31515 ,  Y10T428/31522 ,  C08L51/04 ,  C08L101/00

Abstract: A structural adhesive composition that is suitable for high-strength bonding of metals and aerospace structural materials. In one embodiment, the structural adhesive composition based on a two-part system, which is curable at or below 200° F. (93° C.). The two-part system is composed of a resinous part (A) and a catalyst part (B), which may be stored separately at room temperature until they are ready to be used. The resinous part (A) includes at least two different multifunctional epoxy resins, toughening components, and inorganic filler particles. The catalyst part (B) includes an aliphatic or cyclic amine compound as a curing agent and inorganic filler. In another embodiment, the structural adhesive composition is based on a one-part system, which includes the components of the resinous part (A) mixed with a latent amine curing agent. The one-part system may further include an imidazole and/or an aliphatic amine.

Abstract translation: 适用于金属和航空航天结构材料的高强度粘合的结构粘合剂组合物。 在一个实施方案中，基于两部分系统的结构粘合剂组合物，其可在等于或低于200°F（93℃）下固化。 两部分系统由树脂部分（A）和催化剂部分（B）组成，可以在室温下分开储存，直到准备使用。 树脂部分（A）包括至少两种不同的多官能环氧树脂，增韧组分和无机填料颗粒。 催化剂部分（B）包括脂族或环状胺化合物作为固化剂和无机填料。 在另一个实施方案中，结构粘合剂组合物基于一部分系统，其包括与潜胺胺固化剂混合的树脂部分（A）的组分。 单组分体系可以进一步包括咪唑和/或脂族胺。

公开(公告)号：US20130115442A1

公开(公告)日：2013-05-09

申请号：US13652724

申请日：2012-10-16

Applicant: Cytec Technology Corp

Inventor： Junjie Jeffrey Sang ,  Dalip Kumar Kohli ,  Kunal Gaurang Shah

IPC: C09J163/00 ,  C08K3/36 ,  B32B7/12 ,  B82Y30/00

CPC classification number: C09J163/00 ,  B32B7/12 ,  B32B27/18 ,  B32B27/38 ,  B32B2250/03 ,  B32B2264/0207 ,  B32B2270/00 ,  B32B2405/00 ,  C08G59/4253 ,  C08G59/50 ,  C08G59/5026 ,  C08G59/5073 ,  C08K3/36 ,  C08L63/00 ,  C08L81/06 ,  Y10T428/24995 ,  Y10T428/249951 ,  Y10T428/249952 ,  Y10T428/254 ,  Y10T428/31515 ,  Y10T428/31522 ,  C08L51/04 ,  C08L101/00

Abstract: A structural adhesive composition that is suitable for high-strength bonding of metals and aerospace structural materials. In one embodiment, the structural adhesive composition based on a two-part system, which is curable at or below 200° F. (93° C.). The two-part system is composed of a resinous part (A) and a catalyst part (B), which may be stored separately at room temperature until they are ready to be used. The resinous part (A) includes at least two different multifunctional epoxy resins, toughening components, and inorganic filler particles. The catalyst part (B) includes an aliphatic or cyclic amine compound as a curing agent and inorganic filler. In another embodiment, the structural adhesive composition is based on a one-part system, which includes the components of the resinous part (A) mixed with a latent amine curing agent. The one-part system may further include an imidazole and/or an aliphatic amine.

Abstract translation: 适用于金属和航空航天结构材料的高强度粘合的结构粘合剂组合物。 在一个实施方案中，基于两部分系统的结构粘合剂组合物，其可在等于或低于200°F（93℃）下固化。 两部分系统由树脂部分（A）和催化剂部分（B）组成，可以在室温下分开储存，直到准备使用。 树脂部分（A）包括至少两种不同的多官能环氧树脂，增韧组分和无机填料颗粒。 催化剂部分（B）包括脂族或环状胺化合物作为固化剂和无机填料。 在另一个实施方案中，结构粘合剂组合物基于一部分系统，其包括与潜胺胺固化剂混合的树脂部分（A）的组分。 单组分体系可以进一步包括咪唑和/或脂族胺。