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公开(公告)号：US3791961A
公开(公告)日：1974-02-12
申请号：US3791961D
申请日：1971-12-07
Applicant: EXXON RESEARCH ENGINEERING CO
Inventor： SINFELT J
CPC classification number: C10G59/02 , B01J23/468 , B01J37/22 , C10G35/09
Abstract: A CONVENTIONAL NAPHTHENE DEHYDROGENATION CATALYST, SUCH AS A PLATINUM-HALOGEN-ALUMINA CATALYST, IS USED IN THE INITIAL ZONE OR REACTORS IN A CATALYTIC REFORMING PROCESS; THE TAIL ZONE OR REACTORS CONTAINS A SUPPORTED GROUP VIII POLYMETALLIC CATALYST WITH PLATINUM AS ONE OF THE METALLIC COMPONENTS. IN A PREFERRED EMBODIMENT, THE TAIL ZONE CONTAINS A PLATINUM-IRIDIUM CATALYST ONE A POROUS SUPPORT SUCH AS ALUMINA. IN THE TAIL REACTORS, CONVERSION OF PARAFFINS IS OF PRIMARY IMPORTANCE, ALONG WITH DEALKYLATION OF ALKYLBENEZENES; IN THE INITIAL REACTORS, THE PREDOMINANT REACTION IS THE CONVERSION OF NAPHTTHENES TO AROMATICS. THE COMBINATION PROCESS RESULTS IN THE FORMATION OF A SIGNIFICANTLY GREATER OCTANE NUMBER PRODUCT THAN IS OBTAINED IN A CONVENTIONAL REOFMING PROCESS IN WHICH PLATINUM-ALUMINA CATALYST IS USED THROUGHOUT.
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公开(公告)号：US3789020A
公开(公告)日：1974-01-29
申请号：US3789020D
申请日：1971-02-01
Applicant: EXXON RESEARCH ENGINEERING CO
IPC: B01J23/656 , B01J23/89 , C10G35/09 , C10G35/095 , B01J11/08 , B01J11/22
CPC classification number: C10G35/09 , B01J23/656 , B01J23/89 , C10G35/095
Abstract: A METHOD OF THE PREPARATION OF A CATALYST COMPRISING THE SEQUESTRATION OF MICRONUTRIENT METAL IONS IN LIQUID TWO OR MORE METALS IN LOW CONCENTRATION OND ONE OR MORE PHOSPHATIC FERTILIZER SOLUTIONS IS FACILITATED BY INCORPORATING I NONMETALLIC REFRACTORY MATERIALS IN HIGH CONCENTRATIONS N WHICH COMPRISES SUPPORTING THE METALS ON A FRACTION OF THE SOLUTIONS A SYNERGISTIC COMBINATION OF CITRATE AND THE NONMETALLIC REFRACTORY MATERIAL, AND MIXING SAID FRACPOLYPHOSPHATE SALTS. TION WITH THE REMAINING NONMETALLIC REFRACTORY MATERIAL, WHEREBY THE OVERALL CATALYST AT REACTION CONDUCTIONS CONSISTS OF A PHYSICAL MIXTURE OF THE SUPPORTED METALLIC COMPONENT AND THE REMAINING NONOMETALLIC REFRACTORY MATERIAL. MORE PARTICULARLY, THE SUPPORTED METALLIC COMPONENT IS TREATED UNDER REDUCING CONDITIONS TO FORM AN ALLOY OF THE MATALS ON SAID FRACTION ON THE NONMETALLIC REFRACTORY MATERIAL. IN PREFFERED EMBODIMENTS THE SUPPORTED METALLIC COMPONENT OF THE CATALYST COMPRISES TWO METALS, ONE FROM GROUP VIII AND ONE FROM GROUP I-B. OR BOTH FROM GROUP VIII.
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Patent Agency Ranking
公开(公告)号：US3839194A
公开(公告)日：1974-10-01
申请号：US35040373
申请日：1973-04-12
Applicant: EXXON RESEARCH ENGINEERING CO
CPC classification number: B01J35/10 , B01J23/40 , B01J23/468 , B01J35/1019 , B01J37/24 , C10G35/09
Abstract: Naphtha feed stocks are converted to high octane products in a long cycle semi-regenerative operation utilizing a catalyst comprising alumina in association with 0.15 to 0.75 weight percent platinum, 0.15 to 0.45 weight percent iridium and 0.3 to 2.0 weight percent chlorine, each based on total catalyst, the surface area of the platinum and iridium on the alumina being at least about 200 square meters per gram of platinum and iridium as determined by carbon monoxide chemisorption techniques. The catalyst should contain less than about two atoms of sulfur per atom of platinum and iridium and be substantially free of alkali and alkaline earth metal constituents.
Abstract translation: 石油醚原料在长循环半再生操作中转化为高辛烷值产物，利用包含氧化铝的催化剂与0.15至0.75重量％的铂，0.15至0.45重量百分比的铱和0.3至2.0重量百分比的氯，基于总计 催化剂中，铂和铱在氧化铝上的表面积为至少约200平方米/克铂和铱，通过一氧化碳化学吸附技术测定。 催化剂应含有少于约两个原子的硫原子的铂和铱，并且基本上不含碱金属和碱土金属成分。
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公开(公告)号：US3850747A
公开(公告)日：1974-11-26
申请号：US19446171
申请日：1971-11-01
Applicant: EXXON RESEARCH ENGINEERING CO
Abstract: Hydrocarbon materials are converted to useful products by contacting the same at elevated temperatures with a catalyst comprising a refractory support in association with greater than 0.1 wt. % iridium, and 0.1 - 1.0 wt. % of at least one additional metal. The iridium and additional catalyst metal, preferably platinum, are present on the surface of the support in the form of highly dispersed polymetallic clusters with metal surface areas of at least 200 square meters per gram of metal. The catalyst is particularly effective for promoting naphtha reforming operations.
Abstract translation: 碳氢化合物材料通过在升高的温度下与含有大于0.1重量％的耐火载体的催化剂接触而转化为有用的产物。 ％铱，和0.1〜1.0wt。 至少一种额外金属的％。 铱和另外的催化剂金属（优选铂）以高度分散的多金属簇的形式存在于载体的表面上，金属表面积为至少200平方米/克金属。 催化剂对于促进石脑油重整操作特别有效。
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公开(公告)号：US3835034A
公开(公告)日：1974-09-10
申请号：US35038673
申请日：1973-04-12
Applicant: EXXON RESEARCH ENGINEERING CO
CPC classification number: C10G35/09 , B01J23/40 , B01J23/468 , B01J35/10 , B01J35/1019 , B01J37/24
Abstract: NAPTHA FEED STOCKS ARE CONVERTED TO HIGH OCTANE PRODUCTS AT HIGH SEVERITY CONDITIONS UTILIZING A CATALYST COMPRISNG ALUMINA IN ASSOCIATION WITH 0.15 TO 0.75 WEIGHT PERCENT PLATINUM, 0.15 TO 0.45 WEIGHT PERCENT IRIDIUM AND 0.3 TO 2.0 WEIGHT PERCENT CHLORINE, EACH BASED ON TOTAL CATALYST, THE SURFACE AREA OF THE PLATINUM AND IRIDIUM ON THE ALUMINA BEING AT LEAST ABOUT 200 SQUARE METERS PER GRAM OF PLATINUM AND IRIDIUM AS DETERMINED BY CARBON MONOXIDE C CHEMISORPTION TECHNIQUES. THE CATALYST SHOULD CONTAIN LESS THAN ABOUT TWO ATOMS OF SULFUR PER ATOM OF PLATINUM AND IRIDIUM AND BE SUBSTANTIALLY FREE OF ALKALI AND ALKALINE EARTH METAL CONSTITUENTS.
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公开(公告)号：US3769201A
公开(公告)日：1973-10-30
申请号：US3769201D
申请日：1971-05-27
Applicant: EXXON RESEARCH ENGINEERING CO
Abstract: A CATALYTIC REFORMING PROCESS WHEREIN NAPHTHA FEED STREAMS, BOILING FROM ABOUT 80 TO 450*F., AND COMPRISING NAPHTHENES, PARAFFINS AND AROMATICS, ARE CONTACTED, IN AN INITIAL REACTION ZONE, WITH A HYDROGEN CONTAINING GAS, IN THE PRESENCE OF A CATALYST COMPRISING PD, OR PD AND A GROUP I-B METAL SUPPORTED ON A REFRACTORY OXIDE, AND PASSED INTO A TAIL ZONE WHEREIN THE FEED STREAM IS AGAIN CONTACTED WITH A CATALYST AND THEREBY FURTHER REACTED TO PRODUCE A HIGH OCTANE NUMBER PRODUCT. IN A PREFERRED EMBODIMENT THE GROUP I-B METAL IS AU.
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公开(公告)号：US3729408A
公开(公告)日：1973-04-24
申请号：US3729408D
申请日：1970-12-28
Applicant: EXXON RESEARCH ENGINEERING CO
Abstract: A catalytic reforming process wherein naphtha feed streams, boiling from about 80* to 450* F, and comprising naphthenes, paraffins and aromatics, are contacted, in an initial reaction zone, with a hydrogen containing gas, in the presence of a catalyst comprising Pt and a group IB metal supported on a refractory oxide; passed into a tail zone wherein the feed stream is again contacted with a catalyst and thereby further reacted; and a high octane product is recovered. In a preferred embodiment the Group IB metal is Cu.
Abstract translation: 在催化重整过程中，在初始反应区中，在含有Pt的催化剂存在下，将沸点为约80-450°F的石脑油进料流，包含环烷烃，链烷烃和芳族化合物与含氢气体接触， 和负载在难熔氧化物上的IB族金属; 进入尾区，其中进料流再次与催化剂接触，从而进一步反应; 并回收高辛烷值的产品。 在优选实施方案中，IB族金属是Cu。
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