公开(公告)号：US10688464B2

公开(公告)日：2020-06-23

申请号：US15613616

申请日：2017-06-05

Applicant: General Atomics

Inventor： Glenn Thomas Hong ,  Kevin William Downey

IPC: C02F1/02 ,  C02F1/72 ,  C02F11/08 ,  B01J3/00 ,  B01J19/02 ,  C10G1/00 ,  C23F11/18 ,  C23F11/08 ,  C02F5/02 ,  C02F5/08 ,  C02F5/10 ,  C02F5/06

Abstract: The disclosed technology relates to methods of inhibiting corrosion in reaction chambers configured for hydrothermal reaction of feeds containing a heteroatom. An embodiment of such a method comprises providing a feed stream comprising a phosphorus-containing material, an alkali metal compound, water, and a corrosion-inhibitor. The embodiment additionally includes introducing the feed stream and oxidant into a reactor chamber and oxidizing the phosphorus-containing material at an oxidation temperature greater than about 374° C. and an oxidation pressure exceeding about 25 bar, wherein the reactor chamber has inner surfaces comprising a material that corrodes when in contact with a phosphorus compound within the reactor. The embodiment additionally includes selectively reacting the corrosion-inhibitor with phosphorus within the reactor, thereby precipitating in the reactor chamber a phosphorus-containing solid inorganic compound. The embodiment further includes forming in the reactor chamber an alkali salt melt and carrying away from the reactor chamber a mixture comprising the solid phosphorus-containing inorganic compound and the alkali salt melt.

公开(公告)号：US20180345241A1

公开(公告)日：2018-12-06

申请号：US15613616

申请日：2017-06-05

Applicant: General Atomics

Inventor： Glenn Thomas Hong ,  Kevin William Downey

IPC: B01J19/02 ,  B01J3/00 ,  C02F1/02 ,  C10G1/00 ,  C02F1/72 ,  B01J3/04 ,  C02F11/08

CPC classification number: B01J19/02 ,  B01J3/008 ,  B01J2219/0236 ,  C02F1/025 ,  C02F5/02 ,  C02F5/06 ,  C02F5/08 ,  C02F5/083 ,  C02F5/10 ,  C02F11/086 ,  C02F2209/02 ,  C02F2209/03 ,  C02F2303/08 ,  C10G1/004 ,  C23F11/08 ,  C23F11/18

Abstract: The disclosed technology relates to methods of inhibiting corrosion in reaction chambers configured for hydrothermal reaction of feeds containing a heteroatom. An embodiment of such a method comprises providing a feed stream comprising a phosphorus-containing material, an alkali metal compound, water, and a corrosion-inhibitor. The embodiment additionally includes introducing the feed stream and oxidant into a reactor chamber and oxidizing the phosphorus-containing material at an oxidation temperature greater than about 374° C. and an oxidation pressure exceeding about 25 bar, wherein the reactor chamber has inner surfaces comprising a material that corrodes when in contact with a phosphorus compound within the reactor. The embodiment additionally includes selectively reacting the corrosion-inhibitor with phosphorus within the reactor, thereby precipitating in the reactor chamber a phosphorus-containing solid inorganic compound. The embodiment further includes forming in the reactor chamber an alkali salt melt and carrying away from the reactor chamber a mixture comprising the solid phosphorus-containing inorganic compound and the alkali salt melt.