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公开(公告)号:US07423099B2
公开(公告)日:2008-09-09
申请号:US11539901
申请日:2006-10-10
Applicant: Hitoshi Kimoto , Ryouji Kanita , Yoichi Konno
Inventor: Hitoshi Kimoto , Ryouji Kanita , Yoichi Konno
IPC: C08F2/34 , C08F2/12 , C08F110/06
CPC classification number: C08F110/06 , Y10S526/901 , C08F2/34
Abstract: A process for producing a polyolefin comprising a combination of liquid phase polymerization of α-olefin conducted in one or more liquid phase polymerization reactors and gas phase polymerization of α-olefin conducted in one or more gas phase polymerization reactors after the liquid phase polymerization in a material flow.
Abstract translation: 一种制备聚烯烃的方法,包括在一个或多个液相聚合反应器中进行的α-烯烃的液相聚合和在一个或多个气相聚合反应器中进行的气相聚合中的α-烯烃的气相聚合之后, 物料流。
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公开(公告)号:US20100063224A1
公开(公告)日:2010-03-11
申请号:US12554701
申请日:2009-09-04
Applicant: Hitoshi Kimoto
Inventor: Hitoshi Kimoto
CPC classification number: C08F10/00 , B01J8/08 , B01J2219/00006 , B01J2219/0004 , C08F6/005 , C08L23/10 , C08F2/14 , C08F2/34 , C08F2/001
Abstract: [Object]An object of the present invention is to produce a polyolefin by efficiently reusing unreacted monomers at low costs.[Solution to Problem]A polymerization apparatus 1 of the present invention includes: a liquid-phase reactor 2 in which olefin monomers are subjected to liquid-phase polymerization; a vapor-phase reactor 3 in which olefin monomers are subjected to vapor-phase polymerization; a condenser 4 that condenses unreacted olefin monomers discharged from the vapor-phase reactor 3 so as to produce a liquid containing the olefin monomers; and a liquefied monomer transfer line 11 through which the liquid containing the olefin monomers is transferred from the condenser 4 into the liquid-phase reactor 2. Thus, collected unreacted monomers can be directly subjected to the liquid-phase polymerization without additionally requiring a process such as purification steps. Therefore, the unreacted olefin monomers can be reused efficiently and economically.
Abstract translation: 本发明的目的是通过以低成本有效地重新使用未反应的单体来生产聚烯烃。 问题的解决方案本发明的聚合装置1包括:其中使烯烃单体进行液相聚合的液相反应器2; 气相反应器3,其中烯烃单体进行气相聚合; 冷凝器4,冷凝从气相反应器3排出的未反应的烯烃单体以产生含有烯烃单体的液体; 以及液体单体输送管线11,含有烯烃单体的液体通过该液化单体输送管线11从冷凝器4转移到液相反应器2中。因此,收集的未反应单体可以直接进行液相聚合,而不需要这样的方法 作为纯化步骤。 因此,可以有效且经济地重新使用未反应的烯烃单体。
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公开(公告)号:US20070106037A1
公开(公告)日:2007-05-10
申请号:US11539901
申请日:2006-10-10
Applicant: Hitoshi Kimoto , Ryouji Kanita , Yoichi Konno
Inventor: Hitoshi Kimoto , Ryouji Kanita , Yoichi Konno
IPC: C08F2/00
CPC classification number: C08F110/06 , Y10S526/901 , C08F2/34
Abstract: A process for producing a polyolefin comprising a combination of liquid phase polymerization of α-olefin conducted in one or more liquid phase polymerization reactors and gas phase polymerization of α-olefin conducted in one or more gas phase polymerization reactors after the liquid phase polymerization in a material flow, the process comprising: step A of polymerizing liquid α-olefin in the presence of a catalyst in a first reactor for liquid phase polymerization to produce a slurry comprising unreacted liquid α-olefin and a polymer powder containing the catalyst, step B of causing gas comprising α-olefin to flow in a second reactor for gas phase polymerization while keeping the second reactor unfilled with a seed powder, step C of transferring the slurry produced in the first reactor into the second reactor unfilled with a seed powder in which the gas comprising α-olefin is caused to flow, step D of vaporizing the liquid α-olefin included in the slurry transferred from the first reactor, polymerizing the vaporized α-olefin and the α-olefin included in the gas blown into the second reactor, and forming a fluidized bed by fluidizing a polymer powder, this step being conducted in the second reactor in which the gas comprising the α-olefin is caused to flow, and step E of bringing the temperature and the pressure in the second reactor to a temperature and a pressure high enough to polymerize the α-olefin in the second reactor while allowing the gas comprising the α-olefin to flow.
Abstract translation: 一种制备聚烯烃的方法,包括在一个或多个液相聚合反应器中进行的α-烯烃的液相聚合和在一个或多个气相聚合反应器中进行的气相聚合中的α-烯烃的气相聚合之后, 该方法包括:在催化剂存在下在液相聚合的第一反应器中聚合液体α-烯烃的步骤A,以产生包含未反应的液体α-烯烃和含有催化剂的聚合物粉末的浆料,步骤B为 使包含α-烯烃的气体在第二反应器中流动以进行气相聚合,同时保持第二反应器未填充种子粉末;步骤C,将在第一反应器中产生的浆料转移到未填充有种子粉末的第二反应器中, 使包含α-烯烃的气体流动,使包含在浆料中的液体α-烯烃蒸发的步骤D 从第一反应器中提取,将气化的α-烯烃和包含在吹入第二反应器的气体中的α-烯烃聚合,并通过流化聚合物粉末形成流化床,该步骤在第二反应器中进行,其中气体 包括使α-烯烃流动,并且使第二反应器中的温度和压力达到足够高的温度和压力以使第二反应器中的α-烯烃聚合的步骤E,同时允许包含α-烯烃的气体, 烯烃流动。
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公开(公告)号:US20050277748A1
公开(公告)日:2005-12-15
申请号:US11131429
申请日:2005-05-18
Applicant: Hitoshi Kimoto , Kazuyuki Takemura , Kojiro Matsui
Inventor: Hitoshi Kimoto , Kazuyuki Takemura , Kojiro Matsui
CPC classification number: C08F10/00 , C08F210/06 , C08F2/02 , C08F2/14 , C08F210/08
Abstract: Disclosed is a method for producing an olefin polymer by liquid phase polymerization, the method including a step of polymerizing an olefinic monomer system in the presence of a catalyst and a liquid medium in a polymerization reactor, wherein the reactor has an inner wall having an arithmetic average surface roughness of 1.0 μm or less.
Abstract translation: 公开了通过液相聚合制备烯烃聚合物的方法,该方法包括在聚合反应器中在催化剂和液体介质存在下聚合烯烃单体体系的步骤,其中反应器具有内壁,其具有算术 平均表面粗糙度为1.0μm以下。
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