Abstract:
The invention describes a hydrocracking catalyst which is selective towards the naphtha cut and the hydrocracking process using said catalyst, said catalyst comprising at least one hydrogenating-dehydrogenating element chosen from the group formed by the elements of group VIB and the non-noble elements of group VIII of the Periodic Table, taken alone or as a mixture, and a support comprising at least one porous mineral matrix, a zeolite Y having an initial lattice parameter a0 of the unit cell of strictly greater than 24.50 Å, and a zeolite beta, in which the weight ratio of said zeolite Y to said zeolite beta in the catalyst is between 5 and 12.
Abstract:
The invention describes a hydrocracking catalyst that is selective towards the naphtha cut and the hydrocracking process using said catalyst, said catalyst comprising at least one hydrogenating-dehydrogenating element chosen from the group formed by the elements of group VIB and the non-noble elements of group VIII of the periodic table, taken alone or as a mixture, and a support comprising at least one porous mineral matrix, a zeolite Y having an initial lattice parameter a0 of the unit cell of greater than 24.42 Å, and a zeolite beta, in which the weight ratio of said zeolite Y to said zeolite beta in the catalyst is strictly greater than 12.
Abstract:
The invention describes a hydrocracking catalyst which is selective towards the naphtha cut and the hydrocracking process using said catalyst, said catalyst comprising at least one hydrogenating-dehydrogenating element chosen from the group formed by the elements of group VIB and the non-noble elements of group VIII of the Periodic Table, taken alone or as a mixture, and a support comprising at least one porous mineral matrix, a zeolite Y having an initial lattice parameter a0 of the unit cell of greater than 24.42 Å, and a zeolite beta, in which the weight ratio of said zeolite Y to said zeolite beta in the catalyst is strictly greater than 12.
Abstract:
A subject matter of the invention is a process for the hydrotreating of a hydrocarbon feedstock having a distillation range of between 150° C. and 600° C., so as to obtain a hydrotreated effluent, said process comprising the following stages:
a) said hydrocarbon feedstock is brought into contact, in the presence of hydrogen, with at least one first catalyst occupying a volume V1 and comprising a support based on alumina or silica or silica-alumina and an active phase consisting of nickel and molybdenum, b) the effluent obtained in stage a) is brought into contact, in the presence of hydrogen, with at least one second catalyst occupying a volume V2 and comprising a support based on alumina or silica or silica-alumina and an active phase consisting of nickel, molybdenum and tungsten, and phosphorus,
the distribution of the volumes V1/V2 being of between 50% vol/50% vol and 90% vol/10% vol respectively.
Abstract:
The present invention is based on the use of a two-step hydrocracking process for the production of naphtha, comprising a step of hydrogenation placed upstream of the second hydrocracking step, the hydrogenation step treating the unconverted liquid fraction separated in the distillation step in the presence of a specific hydrogenation catalyst. Furthermore, the hydrogenation step and a second hydrocracking step are carried out under specific operating conditions and in particular under temperature conditions that are very specific with respect to one another.
Abstract:
The present invention concerns a hydrotreatment catalyst comprising an alumina-based support, at least one metal from group VIB, at least one metal from group VIII and phosphorus, in which: the specific surface area of the catalyst is in the range 20 to 150 m2/g; the density of the metal from group VIB, expressed as the number of atoms of metal from group VIB per unit surface area of catalyst, is in the range 7 to 30 atoms of metal from group VIB per nm2 of catalyst; the catalyst being prepared by impregnation of the metals from group VIB, group VIII and phosphorus onto the support in order to obtain an impregnated catalyst precursor, then drying said impregnated catalyst precursor at a temperature of less than 200° C. and without subsequent calcining.
Abstract:
A catalytic adsorbent, comprising at least cobalt and molybdenum deposited on a porous substrate in which the content of cobalt, expressed in terms of CoO oxide, is between 11 and 30% by weight relative to the total weight of said adsorbent and the content of molybdenum, expressed in terms of MoO3 oxide, is between 3 and 30% by weight relative to the total weight of said adsorbent, is described. This invention also relates to a process for hydrotreatment using said catalytic adsorbent.
Abstract:
The present application relates to a process for the selective hydrogenation of a gasoline which contains polyunsaturated compounds and sulphurous light compounds, the process allowing conjointly the hydrogenation of polyunsaturated compounds into mono-unsaturated compounds, increasing weight of the sulphurous light compounds by reaction with the unsaturated compounds, and maximisation of the isomerisation of the monounsaturated compounds comprising an external C═C double bond into their internal C═C double bond isomer, said process implementing a catalyst containing at least one group VIb metal and at least one group VIII metal deposited on a porous support.
Abstract:
The present invention is based on the use of a two-step hydrocracking process for the production of naphtha, comprising a step of hydrogenation placed downstream of the second hydrocracking step, the hydrogenation step treating the effluent resulting from the second hydrocracking step in the presence of a specific hydrogenation catalyst. Furthermore, the hydrogenation step and the second hydrocracking step are performed under specific operating conditions and in particular under quite specific temperature conditions.
Abstract:
The present invention describes a process for hydrocracking at least one hydrocarbon feed in which at least 50% by weight of the compounds have an initial boiling point of more than 300° C. and a final boiling point of less than 540° C. using at least one catalyst comprising at least one metal from group VIB and/or at least one metal from group VIII of the periodic classification of the elements and a support comprising at least one zeolite containing at least one series of channels the opening of which is defined by a ring containing 12 oxygen atoms (12MR), and at least one binder, said support being prepared from a highly dispersible alumina gel, said hydrocracking process being operated at a temperature in the range 200° C. to 480° C., at a total pressure in the range 1 MPa to 25 MPa, with a ratio of the volume of hydrogen to the volume of hydrocarbon feed in the range 80 to 5000 litres per litre and with an hourly space velocity (HSV), defined as the ratio of the volume flow rate of liquid hydrocarbon feed to the volume of catalyst charged into the reactor, in the range 0.1 to 50 h−1.