公开(公告)号：US09340733B2

公开(公告)日：2016-05-17

申请号：US14182698

申请日：2014-02-18

Applicant: IFP ENERGIES NOUVELLES ,  CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE

Inventor： Karin Marchand ,  Alexandra Chaumonnot ,  Audrey Bonduelle ,  Magalie Roy-Auberger ,  Veronique Dufaud ,  Frederic Lefebvre ,  Manuela Bader ,  Susana Lopes Silva

IPC: C10G45/04 ,  C10G45/08 ,  C10G45/06 ,  C10G69/04 ,  C10G45/00 ,  C10G45/02

CPC classification number: C10G45/08 ,  C10G45/04 ,  C10G45/06 ,  C10G69/04 ,  C10G2300/202

Abstract: The invention relates to a process of hydrodesulphuration of at least one gasoil cut implementing a catalyst containing, in its oxide form, at least one metal from group VIB and/or at least one metal from group VIII of the periodic table, present in the form of at least one polyoxometalate of the formula (HhXxMmOy)q−, said polyoxometalates being present within a mesostructured silicon oxide matrix having a pore size within the range 1.5 to 50 nm and having amorphous walls of thickness within the range 1 to 30 nm, the said catalyst being sulphured before being implemented in the said process.

Abstract translation: 本发明涉及一种加氢脱硫方法，该方法是实施一种催化剂的方法，该催化剂切割物以其氧化物形式含有至少一种来自元素周期表VIB的金属和/或至少一种元素周期表第VIII族的金属，其形式为 的至少一种式（HhXxMmOy）q-的多金属氧酸盐，所述多金属氧酸盐存在于孔径在1.5至50nm范围内且具有在1至30nm范围内的非晶壁的介孔结构氧化硅基质内， 所述催化剂在所述方法实施之前被硫化。

公开(公告)号：US09925533B2

公开(公告)日：2018-03-27

申请号：US14366292

申请日：2012-11-23

Applicant: IFP ENERGIES NOUVELLES

Inventor： Audrey Bonduelle ,  Emmanuelle Guillon ,  Magalie Roy-Auberger

IPC: B01J37/02 ,  B01J29/78 ,  B01J31/02 ,  B01J29/76 ,  C10G47/20 ,  B01J35/00 ,  C10G65/10 ,  C10G47/18

CPC classification number: B01J37/0236 ,  B01J29/76 ,  B01J29/78 ,  B01J31/0201 ,  B01J35/002 ,  B01J37/0201 ,  B01J2229/20 ,  B01J2229/42 ,  C10G47/18 ,  C10G47/20 ,  C10G65/10

Abstract: The invention relates to a method of preparing a catalyst comprising a) preparation of a support comprising 0.2 to 30 wt % of zeolite NU-86 and from 70 to 99.8 wt % of a porous mineral matrix, the percentages by weight being expressed relative to the total weight of said support, b) impregnation of the support prepared according to step a) with at least one solution containing at least one precursor of at least one metal selected from group VIII metals and group VIB metals, used alone or as a mixture, c) at least one ripening step, and d) at least one drying step carried out at a temperature below 150° C., without a subsequent calcining step. The present invention also relates to a process for hydrocracking hydrocarbon feeds using the catalyst prepared according to the method of preparation according to the invention.

公开(公告)号：US09718050B2

公开(公告)日：2017-08-01

申请号：US14367260

申请日：2012-11-23

Applicant: IFP ENERGIES NOUVELLES

Inventor： Audrey Bonduelle ,  Emmanuelle Guillon ,  Magalie Roy-Auberger

IPC: B01J29/80 ,  C10G47/20 ,  C10G65/12 ,  B01J29/16 ,  B01J29/076

CPC classification number: B01J29/80 ,  B01J29/076 ,  B01J29/14 ,  B01J29/146 ,  B01J29/166 ,  C10G47/20 ,  C10G65/12

Abstract: The invention relates to a catalyst comprising at least one metal selected from the group formed by metals of group VIB and of group VIII of the periodic table, used alone or as a mixture, and a support comprising at least one zeolite NU-86, at least one zeolite Y and at least one porous mineral matrix containing at least aluminum and/or at least silicon. The invention also relates to a process for hydrocracking of hydrocarbon feeds employing said catalyst.

公开(公告)号：US09683180B2

公开(公告)日：2017-06-20

申请号：US14554242

申请日：2014-11-26

Applicant: IFP ENERGIES NOUVELLES

Inventor： Magalie Roy-Auberger ,  Emmanuelle Guillon ,  Aline Grezaud

IPC: C10G65/02 ,  C10G65/04 ,  C10G45/08 ,  C10G65/12 ,  C10G69/04 ,  B01J37/02 ,  B01J27/19 ,  B01J35/00 ,  C10G65/00

CPC classification number: C10G65/04 ,  B01J27/19 ,  B01J35/002 ,  B01J37/0203 ,  B01J37/0207 ,  C10G45/08 ,  C10G65/12 ,  C10G69/04 ,  C10G2300/1074 ,  C10G2300/202

Abstract: A process for the hydrotreatment of a vacuum distillate type hydrocarbon feed containing nitrogen-containing compounds is described, comprising a first step in which the feed is brought into contact with a catalyst in its oxide form, then a second step in which the feed is brought into contact with a dried catalyst comprising at least one organic compound containing oxygen and/or nitrogen.

公开(公告)号：US10076746B2

公开(公告)日：2018-09-18

申请号：US15103583

申请日：2014-12-08

Applicant: IFP Energies nouvelles

Inventor： Magalie Roy-Auberger ,  Ali Jahel

IPC: B01J27/19 ,  B01J37/20 ,  B01J23/882 ,  B01J31/02 ,  B01J31/04 ,  B01J37/02 ,  C10G45/08 ,  B01J37/28 ,  B01J35/10 ,  B01J37/08 ,  C10G45/50 ,  B01J23/883

CPC classification number: B01J27/19 ,  B01J23/882 ,  B01J23/883 ,  B01J31/0202 ,  B01J31/0237 ,  B01J31/0271 ,  B01J31/04 ,  B01J35/1019 ,  B01J37/0203 ,  B01J37/0207 ,  B01J37/0236 ,  B01J37/08 ,  B01J37/20 ,  B01J37/28 ,  C10G45/08 ,  C10G45/50 ,  C10G2300/703

Abstract: The invention concerns a process for the preparation of a catalyst starting from a pre-catalyst comprising at least one catalytic metal and a support, said pre-catalyst having undergone a heat treatment at at least 60° C. without calcining, in which process said pre-catalyst is impregnated with a basic solution having a pH of more than 7.5 and containing at least one molecule in the zwitterionic form, and the impregnated pre-catalyst is dried at a temperature of at most 240° C. without subsequent calcining.The molecule in the zeolite form is selected from the group formed by amino-alcohol acids containing secondary or tertiary amine groups and containing at least one carboxylic acid function (and preferably only one) and at least one alcohol function. It is bicine or tricine, for example.The invention also concerns the catalyst prepared using this process, and its use in hydrotreatment and/or hydroconversion.

公开(公告)号：US20150231615A1

公开(公告)日：2015-08-20

申请号：US14367260

申请日：2012-11-23

Applicant: IFP ENERGIES NOUVELLES

Inventor： Audrey Bonduelle ,  Emmanuelle Guillon ,  Magalie Roy-Auberger

IPC: B01J29/80 ,  C10G65/12 ,  C10G47/20

CPC classification number: B01J29/80 ,  B01J29/076 ,  B01J29/14 ,  B01J29/146 ,  B01J29/166 ,  C10G47/20 ,  C10G65/12

Abstract: The invention relates to a catalyst comprising at least one metal selected from the group formed by metals of group VIB and of group VIII of the periodic table, used alone or as a mixture, and a support comprising at least one zeolite NU-86, at least one zeolite Y and at least one porous mineral matrix containing at least aluminium and/or at least silicon. The invention also relates to a process for hydrocracking of hydrocarbon feeds employing said catalyst.

Abstract translation: 本发明涉及包含至少一种金属的催化剂，所述金属选自由VIB族金属和元素周期表中的VIII族金属单独使用或作为混合物形成的基团，以及包含至少一种沸石NU-86的载体， 至少一种沸石Y和至少含有至少铝和/或至少硅的多孔矿物基质。 本发明还涉及使用所述催化剂加氢裂解烃进料的方法。

公开(公告)号：US20140326641A1

公开(公告)日：2014-11-06

申请号：US14366292

申请日：2012-11-23

Applicant: IFP ENERGIES NOUVELLES

Inventor： Audrey Bonduelle ,  Emmanuelle Guillon ,  Magalie Roy-Auberger

IPC: B01J29/78 ,  C10G47/18 ,  C10G47/20

CPC classification number: B01J37/0236 ,  B01J29/76 ,  B01J29/78 ,  B01J31/0201 ,  B01J35/002 ,  B01J37/0201 ,  B01J2229/20 ,  B01J2229/42 ,  C10G47/18 ,  C10G47/20 ,  C10G65/10

Abstract: The invention relates to a method of preparing a catalyst comprising a) preparation of a support comprising 0.2 to 30 wt % of zeolite NU-86 and from 70 to 99.8 wt % of a porous mineral matrix, the percentages by weight being expressed relative to the total weight of said support, b) impregnation of the support prepared according to step a) with at least one solution containing at least one precursor of at least one metal selected from group VIII metals and group VIB metals, used alone or as a mixture, c) at least one ripening step, and d) at least one drying step carried out at a temperature below 150° C., without a subsequent calcining step. The present invention also relates to a process for hydrocracking hydrocarbon feeds using the catalyst prepared according to the method of preparation according to the invention.

Abstract translation: 本发明涉及一种制备催化剂的方法，其包括：a）制备包含0.2至30重量％的沸石NU-86和70至99.8重量％的多孔矿物基质的载体，所述重量百分比相对于 所述载体的总重量，b）根据步骤a）制备的载体浸渍至少一种含有至少一种选自Ⅷ族金属和ⅥB族金属的金属的前体的溶液，其单独使用或作为混合物使用， c）至少一个熟化步骤，和d）在低于150℃的温度下进行至少一个干燥步骤，而不用随后的煅烧步骤。 本发明还涉及使用根据本发明的制备方法制备的催化剂加氢裂化烃进料的方法。