公开(公告)号：US4579978A

公开(公告)日：1986-04-01

申请号：US670102

申请日：1984-11-13

Applicant: Jiang-Jen Lin ,  John R. Sanderson

Inventor： Jiang-Jen Lin ,  John R. Sanderson

IPC: C07C409/08 ,  C07D301/19 ,  C07C179/035

CPC classification number: C07D301/19 ,  C07C407/00 ,  C07C409/08

Abstract: Substantially quantitative yields of bibenzyl hydroperoxide and bibenzyl dihydroperoxide can be obtained when oxygen is reacted with bibenzyl (1,2-diphenylethane) in the presence of a minor amount of sodium bicarbonate at a temperature within the range of about 100.degree. to about 160.degree. C. to provide an oxidation product wherein the bibenzyl is substantially selectively converted to the bibenzyl hydroperoxides. The bibenzyl hydroperoxides can be used as raw materials for the production of propylene oxide by reacting the bibenzyl hydroperoxides with propylene.

Abstract translation: 在少量碳酸氢钠存在下，在约100至约160℃的温度范围内，当与二苄基（1,2-二苯基乙烷）反应时，可以获得过氧化二苄苯基和联苄基二氢过氧化物的基本定量产率 以提供氧化产物，其中联苄基本上选择性地转化为联苯氢过氧化物。 苄基氢过氧化物可以用作通过使苄基氢过氧化物与丙烯反应生产环氧丙烷的原料。

公开(公告)号：US4483998A

公开(公告)日：1984-11-20

申请号：US484058

申请日：1983-04-11

Applicant: John R. Sanderson ,  Edward T. Marquis ,  Jiang-Jen Lin

Inventor： John R. Sanderson ,  Edward T. Marquis ,  Jiang-Jen Lin

IPC: B01J23/89 ,  C07C51/235 ,  C07D301/06 ,  C07D303/04

CPC classification number: B01J23/8926 ,  C07C51/235 ,  C07D301/06 ,  C07D303/04

Abstract: A process for simultaneously producing an epoxide and a carboxylic acid from an olefin and an aldehyde, respectively, by co-oxidation over a catalyst in the presence of oxygen is described. The catalyst is made by precipitating silver oxide in the presence of copper(II) oxide, copper(II) borate or a mixture thereof. These novel heterogeneous catalysts provide higher selectivities to the epoxide than those obtainable with commercial catalysts.

Abstract translation: 描述了通过在氧气存在下通过催化剂共氧化同时由烯烃和醛生成环氧化物和羧酸的方法。 催化剂通过在氧化铜（II），硼酸铜（II）或其混合物的存在下沉淀氧化银来制备。 这些新型的非均相催化剂提供了比用商业催化剂获得的更高的选择性。

公开(公告)号：US4554364A

公开(公告)日：1985-11-19

申请号：US683547

申请日：1984-12-19

Applicant: John R. Sanderson ,  Ernest L. Yeakey ,  Jiang-Jen Lin

Inventor： John R. Sanderson ,  Ernest L. Yeakey ,  Jiang-Jen Lin

IPC: C07D317/20 ,  C07D317/00

CPC classification number: C07D317/20

Abstract: It has been surprisingly discovered in accordance with the present invention that when 1,3-dioxolane is reacted with formaldehyde in the presence of tert-butyl hydroperoxide and a cobalt initiator, the reaction preferentially involves an addition of the formaldehyde to the 2-methylene group of the 1,3-dioxolane with only minor reaction with the 4-methylene and 5-methylene groups of the 1,3-dioxolane whereby the reaction product that is formed contains significant quantities of 2-hydroxyalkyl-1,3-dioxolanes and only minimal amounts of the undesired methyl formate by-product. 2-Hydroxymethyl-1,3-dioxolane is hydrolyzed with comparative ease to ethylene glycol and the corresponding glycol aldehyde (CHO--CH.sub.2 --OH). The glycol aldehyde in turn can be catalytically hydrogenated to form additional quantities of ethylene glycol.

Abstract translation: 根据本发明令人惊奇地发现，当1,3-二氧戊环与甲醛在叔丁基过氧化氢和钴引发剂的存在下反应时，反应优先包括向2-亚甲基基团加入甲醛 的1,3-二氧戊环，与1,3-二氧戊环的4-亚甲基和5-亚甲基仅有很小的反应，由此形成的反应产物含有大量的2-羟基烷基-1,3-二氧戊环，仅含有 最少量的不需要的甲酸甲酯副产物。 相对于乙二醇和相应的二醇醛（CHO-CH2-OH），2-羟基甲基-1,3-二氧戊环水解。 二醇醛依次可以被催化氢化以形成额外量的乙二醇。

公开(公告)号：US4803305A

公开(公告)日：1989-02-07

申请号：US125965

申请日：1987-11-27

Applicant: John R. Sanderson ,  Edward T. Marquis ,  Jiang-Jen Lin

Inventor： John R. Sanderson ,  Edward T. Marquis ,  Jiang-Jen Lin

IPC: B01J31/04 ,  B01J31/22 ,  C07C29/50 ,  C07C45/33 ,  C07C409/04 ,  C07C179/025 ,  C07C31/12

CPC classification number: C07C409/04 ,  B01J31/2226 ,  C07C29/50 ,  C07C407/00 ,  C07C45/33 ,  B01J2231/70 ,  B01J2531/0216 ,  B01J2531/842 ,  Y02P20/52

Abstract: The oxidation of isobutane in the presence of a novel, soluble catalyst of the formula Fe.sub.3 O(Pivalate).sub.6 (MeOH).sub.3 Cl is disclosed. Tertiary-Butyl alcohol, tertiary-butyl hydroperoxide, and acetone are produced. A significant increase in isobutane conversion is obtained without a large decrease in selectivity to tertiary-butyl alcohol and tertiary-butyl hydroperoxide using a small amount of catalyst. Tertiary-butyl alcohol is useful as a gasoline additive and tertiary-butyl hydroperoxide is used for the production of propylene oxide. Acetone has a variety of uses as well.

Abstract translation: 公开了在式Fe 3 O（新戊酸酯）6（MeOH）3Cl）的新型可溶性催化剂存在下异丁烷的氧化。 制备叔丁醇，叔丁基过氧化氢和丙酮。 在使用少量催化剂的叔丁醇和叔丁基过氧化氢的选择性没有大的降低的情况下，异丁烷转化率显着增加。 叔丁醇可用作汽油添加剂，叔丁基过氧化氢用于生产环氧丙烷。 丙酮也有各种用途。

公开(公告)号：US4526992A

公开(公告)日：1985-07-02

申请号：US662316

申请日：1984-10-18

Applicant: Jiang-Jen Lin ,  John R. Sanderson

Inventor： Jiang-Jen Lin ,  John R. Sanderson

IPC: C07D215/30 ,  C07D317/12 ,  C07F11/00 ,  C07D317/00

CPC classification number: C07D215/30 ,  C07D317/12 ,  C07F11/005

Abstract: The synthesis of substituted dioxolanes by direct oxidation of olefins over a molybdenum 8-hydroxyquinoline catalyst in the presence of water is described. An organic solvent such as chlorobenzene may also be employed. Water is essential to the reaction to make the dioxolanes, otherwise olefin oxides are produced. Hence, 4-methyl-1,3-dioxolane and 2,4-dimethyl-1,3-dioxolane were prepared from propylene oxidation, and three isomers of 2,4,5-trimethyl-1,3-dioxolane were prepared from 2-butene oxidation.

Abstract translation: 描述了通过在水存在下在钼8-羟基喹啉催化剂上直接氧化烯烃的取代的二氧戊环的合成。 还可以使用有机溶剂如氯苯。 水是制备二氧戊环的反应所必需的，否则产生烯烃氧化物。 因此，由丙烯氧化制备4-甲基-1,3-二氧戊环和2,4-二甲基-1,3-二氧戊环，由2,5-二甲基-1,3-二氧戊环制备2,4,5-三甲基-1,3-二氧戊环的三种异构体 丁烯氧化。

公开(公告)号：US08952087B2

公开(公告)日：2015-02-10

申请号：US12258402

申请日：2008-10-25

Applicant: Jiang-Jen Lin ,  Yi-Lin Liao ,  Chien-Chia Chu ,  Chih-Wei Chiu

Inventor： Jiang-Jen Lin ,  Yi-Lin Liao ,  Chien-Chia Chu ,  Chih-Wei Chiu

IPC: C08K3/08 ,  B22F9/00 ,  B22F1/00 ,  B22F9/24 ,  B82Y30/00

CPC classification number: B22F9/24 ,  B22F1/0022 ,  B22F2999/00 ,  B82Y30/00 ,  B22F1/0059

Abstract: The present invention provides a method for reducing metal ions (for example, silver ions) and stably dispersing metal nanoparticles by nanosilicate platelets. An organic dispersant, nanosilicate platelets and a metal ionic solution are mixed to perform a reductive reaction, wherein the organic dispersant is tri-sodium citrate dihydrate (SCD), chitosan or polyvinyl pyrrolidone (PVP), to produce a mixture of stably dispersed metal nanoparticles.

Abstract translation: 本发明提供了还原金属离子（例如银离子）并通过纳米硅酸盐片稳定分散金属纳米粒子的方法。 将有机分散剂，纳米硅酸盐片和金属离子溶液混合以进行还原反应，其中有机分散剂是柠檬酸三钠二水合物（SCD），壳聚糖或聚乙烯吡咯烷酮（PVP）），以产生稳定分散的金属纳米颗粒 。

公开(公告)号：US20130172447A1

公开(公告)日：2013-07-04

申请号：US13561072

申请日：2012-07-29

Applicant: Jiang-Jen Lin ,  Ying-Nan Chan ,  Jau-Yu Chiou

Inventor： Jiang-Jen Lin ,  Ying-Nan Chan ,  Jau-Yu Chiou

IPC: C09K21/12 ,  C08K3/36 ,  C08L63/02 ,  B82Y30/00

CPC classification number: C08K5/5399 ,  B82Y30/00 ,  C07F9/65815 ,  C08K9/04 ,  C08L63/00 ,  C09K21/12

Abstract: A phosphorous flame retardant including nanosilicate platelets (NSP) is made by first reacting hexachlorotriphosphazene (HCP) with poly(oxyalkylene)amine, then mixing the HCP product with nano silicate platelets (NSP) to obtain the phosphorous flame retardant including NSP. The phosphorous flame retardant can be further applied to an epoxy resin as a curing agent.

Abstract translation: 通过首先使六氯三磷腈（HCP）与聚（氧化烯）胺反应，然后将HCP产物与纳米硅酸盐血小板（NSP）混合以获得包括NSP的磷阻燃剂，制备包括纳米硅酸盐血小板（NSP）的磷阻燃剂。 磷阻燃剂可以进一步用作环氧树脂作为固化剂。

公开(公告)号：US20130005918A1

公开(公告)日：2013-01-03

申请号：US13612052

申请日：2012-09-12

Applicant: Jiang-Jen Lin ,  Wei-Cheng Tsai ,  Yen-Chi Hsu ,  Wen-Hsin Chang

Inventor： Jiang-Jen Lin ,  Wei-Cheng Tsai ,  Yen-Chi Hsu ,  Wen-Hsin Chang

IPC: C07C231/02 ,  C08F8/32

CPC classification number: C08F26/00

Abstract: Polymeric polyamine is produced by polymerizing polyoxyalkylene-amine and a linker. The polyoxyalkylene-amine has a structural formula H2N—R—NH2, wherein R is selected from the group consisting of dianhydride, diacid, epoxy, diisocyanate and poly(styrene-co-maleic anhydride) copolymers (SMA). The linker can be anhydride, carboxylic acid, epoxy, isocyanate or poly(styrene-co-maleic anhydride) copolymers (SMA). The polymeric polyamine so produced can be used as a stabilizer or dispersant of the Ag nanoparticles.

Abstract translation: 聚合多胺通过聚合聚氧亚烷基 - 胺和接头来制备。 聚氧化烯胺具有结构式H2N-R-NH2，其中R选自二酐，二酸，环氧，二异氰酸酯和聚（苯乙烯 - 共 - 马来酸酐）共聚物（SMA）。 接头可以是酐，羧酸，环氧，异氰酸酯或聚（苯乙烯 - 共 - 马来酸酐）共聚物（SMA）。 如此生产的聚合多胺可用作Ag纳米颗粒的稳定剂或分散剂。

公开(公告)号：US20120279352A1

公开(公告)日：2012-11-08

申请号：US13549417

申请日：2012-07-14

Applicant: Jiang-Jen Lin ,  Wei-Cheng Tsai ,  Chao-Po Hsu ,  Wei-Li Lin ,  Yueh-Hsien Wu

Inventor： Jiang-Jen Lin ,  Wei-Cheng Tsai ,  Chao-Po Hsu ,  Wei-Li Lin ,  Yueh-Hsien Wu

IPC: B22F9/16 ,  B82Y40/00

CPC classification number: B22F9/24 ,  B22F1/0018 ,  B82Y30/00 ,  Y10S977/896

Abstract: The present invention provides a method for producing silver nanoparticles by employing ethanolamine. The method of this invention can be easily operated and no organic solvent is required. Ethanolamine first reacts with copolymers of poly(styrene-co-maleic anhydride) (abbreviated as SMA) to generate polymeric polymers. The polymeric polymers then reduce silver ions to silver atoms which are dispersed in the form of silver nanoparticles. Functional groups of the polymeric polymers can chelate with silver ions and be stably compatible with water or organic solvents, whereby the silver nanoparticles can be stably dispersed without aggregation and the produced silver nanoparticles.

Abstract translation: 本发明提供使用乙醇胺制造银纳米粒子的方法。 本发明的方法可以容易地操作，不需要有机溶剂。 乙醇胺首先与聚（苯乙烯 - 共 - 马来酸酐）（缩写为SMA）的共聚物反应生成聚合物聚合物。 聚合物聚合物然后将银离子还原成以银纳米颗粒形式分散的银原子。 聚合物聚合物的官能团可以与银离子螯合并与水或有机溶剂稳定地相容，由此可以稳定地分散银纳米颗粒而不会聚集，并且所制备的银纳米颗粒。

公开(公告)号：US20120031846A1

公开(公告)日：2012-02-09

申请号：US13039335

申请日：2011-03-03

Applicant: Jiang-Jen Lin ,  Ru-Siou Hsu

Inventor： Jiang-Jen Lin ,  Ru-Siou Hsu

IPC: B01D59/30

CPC classification number: C02F1/281 ,  B01D17/0202 ,  B01J20/10 ,  B01J20/12 ,  B01J20/3204 ,  B01J20/3272 ,  C02F1/285 ,  C02F1/288 ,  C02F1/681 ,  C02F2001/425 ,  C02F2101/32 ,  C10G25/003 ,  C10G33/04

Abstract: The present invention provides a method for collecting oil with a modified clay. By mixing the modified clay and oil, the oil can be adsorbed to the clay. The modified clay is obtained by intercalating a hydrophobic polymer such as acidified poly(oxyalkylene)-amine into layered silicate clay, mica or talc to enlarge the interlayer space. The modified clay thus becomes hydrophobic and adsorption to the oil is promoted.

Abstract translation: 本发明提供一种用改性粘土收集油的方法。 通过混合改性粘土和油，油可以吸附到粘土上。 改性粘土是通过将层状硅酸盐粘土，云母或滑石中的疏水性聚合物如酸化的聚（氧化烯） - 胺嵌入而获得的，以扩大层间空间。 因此，改性粘土变得疏水，促进了对油的吸附。