公开(公告)号：US4507198A

公开(公告)日：1985-03-26

申请号：US451011

申请日：1982-12-20

Applicant: Kim N. Unger ,  Rory L. Tibbals ,  Dennis V. Smeltzer

Inventor： Kim N. Unger ,  Rory L. Tibbals ,  Dennis V. Smeltzer

IPC: B03D1/004 ,  B03D1/008 ,  B03D1/012 ,  B03D1/14

CPC classification number: B03D1/012 ,  B03D1/008 ,  B03D2201/02 ,  B03D2203/02 ,  B03D2203/04

Abstract: A collector for use in concentrating metal values in ores by flotation, said collector comprising a mixture of (A) an O-alkyl N-alkylthionocarbamate wherein each alkyl radicals has from 1 to 6 carbon atoms and (B) at least 30 percent by weight of (A) of a normally liquid tall oil fatty acid fraction.

Abstract translation: 一种用于通过浮选浓缩矿石中的金属值的收集器，所述收集器包含（A）O-烷基N-烷基硫代氨基甲酸酯的混合物，其中每个烷基具有1至6个碳原子，（B）至少30重量％ （A）的正常液体妥尔油脂肪酸馏分。

公开(公告)号：US4689142A

公开(公告)日：1987-08-25

申请号：US714832

申请日：1985-03-22

Applicant: Kim N. Unger

Inventor： Kim N. Unger

IPC: B03D1/012 ,  B03D1/14

CPC classification number: B03D1/012 ,  B03D2201/02 ,  B03D2203/02 ,  B03D2203/025

Abstract: A method and product for concentrating metal values from their ores employing alkyl mercaptans as collector additives in froth flotation, wherein there is provided a mixture of (I) a collector selected from the class consisting of at least one of (A) an alkyl xanthogen alkyl formate compound having the general formula: ##STR1## wherein R is a branched or straight chain alkyl substituent having 1 to 6 carbon atoms and R' is selected from the class consisting of one of ethyl and methyl; and (B) a dialkyl thionocarbamate compound having the formula: ##STR2## wherein Y is a branched or straight chain alkyl substituent having 1 to 6 carbon atoms and Y' is selected from the class consisting of one of ethyl and ethyl; and (II) an alkyl mercaptan having the formula:Z--SHwherein Z is a branched or straight chain alkyl substituent having 4 to 16 carbon atoms. Isobutyl xanthogen ethyl formate, N-methyl-O-ethyl thionocarbamate and dodecyl mercaptan are illustrative. The method is particularly satisfactory for collecting copper, lead, zinc, molybdenum sulfide and precious metals.

Abstract translation: 一种用于从其矿石中浓缩金属值的方法和产品，其使用烷基硫醇作为泡沫浮选中的收集剂添加剂，其中提供了（I）选自以下的收集剂的混合物：（A）烷基黄原酸烷基 具有以下通式的甲酸酯化合物：其中R是具有1至6个碳原子的支链或直链烷基取代基，R'选自乙基和甲基之一; 和（B）具有下式的二烷基硫代氨基甲酸酯化合物：其中Y是具有1至6个碳原子的支链或直链烷基取代基，Y'选自乙基和乙基之一; 和（II）具有下式的Z-SH的烷基硫醇，其中Z是具有4至16个碳原子的支链或直链烷基取代基。 异丁基黄原酸甲酯，N-甲基-O-乙基硫代氨基甲酸酯和十二烷基硫醇是说明性的。 该方法对于收集铜，铅，锌，硫化钼和贵金属尤其令人满意。

公开(公告)号：US4584095A

公开(公告)日：1986-04-22

申请号：US622474

申请日：1984-06-20

Applicant: Kim N. Unger

Inventor： Kim N. Unger

IPC: B03D1/004 ,  B03D1/014 ,  B03D1/02

CPC classification number: B03D1/014 ,  B03D2201/04 ,  B03D2203/02

Abstract: An ore dressing method for recovering metal values by froth flotation and from their ores, in which flotation of the ore is conducted in the presence of a frothing agent mixture comprising a minor amount of a phosphorodithioic compound as a synergistic adjuvant and a frother which may be an aliphatic alcohol or ketone; a terpenic oil or alcohol or phenol; or a polyalkylene or polyoxyalkylene glycol or ether.

Abstract translation: 一种用于通过泡沫浮选和其矿石回收金属值的选矿方法，其中矿石的浮选在包含少量作为协同助剂的二硫代磷酸化合物和起泡剂的起泡剂混合物存在下进行，所述起泡剂混合物可以是 脂肪醇或酮; 萜烯油或醇或苯酚; 或聚亚烷基或聚氧亚烷基二醇或醚。

公开(公告)号：US4387034A

公开(公告)日：1983-06-07

申请号：US314375

申请日：1981-10-23

Applicant: Kim N. Unger ,  Dennis V. Smeltzer

Inventor： Kim N. Unger ,  Dennis V. Smeltzer

IPC: B03D1/012 ,  B03D1/02

CPC classification number: B03D1/02 ,  B03D1/012 ,  B03D2201/02 ,  B03D2203/02 ,  B03D2203/04

Abstract: A collector for use in concentrating metal values in ores by flotation, said collector comprising a synergistic mixture of O-isopropyl N-ethylthionocarbamate and O-isobutyl N-methylthionocarbamate. Ore dressing flotation methods wherein said mixture serves as collector are also provided.

Abstract translation: 一种用于通过浮选浓缩矿石中的金属值的收集器，所述收集器包括N-异丙基N-乙基硫代氨基甲酸酯和O-异丁基N-甲基硫代氨基甲酸酯的协同混合物。 还提供了其中所述混合物用作收集器的矿石选矿浮选方法。

公开(公告)号：US4729843A

公开(公告)日：1988-03-08

申请号：US835982

申请日：1986-03-04

Applicant: Kim N. Unger

Inventor： Kim N. Unger

IPC: B03D1/012 ,  C09K3/00 ,  C07C155/02 ,  C07C161/00

CPC classification number: B03D1/012 ,  B03D2201/02 ,  B03D2203/02

Abstract: The present invention provides a new collector for use in the froth flotation of metal values from their ores. The collector comprises a synergistic mixture of alkyl xanthogen alkyl formates and dialkyl thionocarbamates, and yields metal recoveries superior to that achieved with either collector alone. According to the present invention the novel collector for use in froth flotation comprises a mixture of alkyl xanthogen alkyl formates having the general formula: ##STR1## wherein R is a branched or straight chain alkyl substituent having 1 to 6 carbon atoms, and R' is selected from the class consisting of ethyl and methyl; anddialkyl thionocarbamates having the general formula: ##STR2## wherein Y is a branched or straight chain alkyl substituent having 1 to 6 carbon atoms, and Y' is selected from the class consisting of ethyl and methyl.

Abstract translation: 本发明提供了一种用于泡沫浮选其矿石中的金属值的新收集器。 收集器包括烷基黄原烷基甲酸酯和硫代碳酸二烷基酯的协同混合物，并且产生的金属回收率优于单独使用收集器实现的。 根据本发明，用于泡沫浮选的新型收集器包括具有以下通式的烷基黄原烷基甲酸酯的混合物：其中R是具有1至6个碳原子的支链或直链烷基取代基，R'是 选自乙基和甲基类; 和具有以下通式的二烷基硫代碳酸氢盐：其中Y是具有1至6个碳原子的支链或直链烷基取代基，Y'选自乙基和甲基。

公开(公告)号：US4699712A

公开(公告)日：1987-10-13

申请号：US834144

申请日：1986-02-25

Applicant: Kim N. Unger

Inventor： Kim N. Unger

IPC: B03D1/012 ,  B03D1/014 ,  B03D1/14

CPC classification number: B03D1/012 ,  B03D1/014 ,  B03D2201/02 ,  B03D2203/02

Abstract: An ore dressing method for beneficiating copper from copper bearing ore by froth flotation employing the collector which comprises a mixture of an O,O-bis(alkylphenyl) phosphorodithioic compound, e.g., sodium O,O-bis(isopropylphenyl) phosphorodithioate, and a thiono compound which is an alkyl xanthogen formate, e.g., isobutyl xanthogen alkyl ethyl formate, and/or a thionocarbamate, e.g., N-ethyl O-isopropyl dialkyl thionocarbamate.

Abstract translation: 一种选矿方法，通过使用收集器进行泡沫浮选从含铜矿石中选择铜，该收集器包括O，O-双（烷基苯基）二硫代磷酸化合物，例如O，O-双（异丙基苯基）二硫代磷酸钠和硫醇 化合物，其为甲基黄原酸甲酯，例如异丁基黄原烷基甲酸乙酯和/或硫代氨基甲酸酯，例如N-乙基O-异丙基二硫代氨基甲酸异丙酯。

公开(公告)号：US4530758A

公开(公告)日：1985-07-23

申请号：US578990

申请日：1984-02-13

Applicant: Rory L. Tibbals ,  Kim N. Unger

Inventor： Rory L. Tibbals ,  Kim N. Unger

IPC: B03D1/014 ,  B03D1/14

CPC classification number: B03D1/014 ,  B03D1/012 ,  B03D2201/02 ,  B03D2203/02

Abstract: The method of recovering copper from a copper-bearing ore which comprises froth flotation of the ore in alkaline circuit and in the presence of a phosphorodithio compound of the formula ##STR1## wherein X is hydrogen, alkali metal, or the ammonium radical and R is alkyl-substituted phenyl of from 6 to 14 carbon atoms having from 1 to 3 alkyl substituents and from 1 to 6 carbon atoms in each alkyl substituent. Sodium O,O-bis(isopropylphenyl) phosphorodithioate and O,O-bis(isopropylphenyl) phosphorodithoic acid are illustrative. The method is particularly useful with sulfide minerals, especially with copper sulfides and molybdenum sulfides.

Abstract translation: 从含铜矿石中回收铜的方法，其中包括在碱性回路中矿石的浮沫和式“IMAGE”的二硫代化合物的存在下，其中X是氢，碱金属或铵基，R是 在每个烷基取代基中具有1至3个烷基取代基和1至6个碳原子的6至14个碳原子的烷基取代的苯基。 O，O-双（异丙基苯基）二硫代磷酸钠和O，O-双（异丙基苯基）磷酸二氢钠是说明性的。 该方法特别适用于硫化矿物，特别是与硫化铜和硫化钼。