公开(公告)号：US3692652A

公开(公告)日：1972-09-19

申请号：US3692652D

申请日：1970-10-19

Applicant: MASSACHUSETTS INST TECHNOLOGY

Inventor： SEYFERTH DIETMAR ,  SPOHN RALPH J

IPC: C07C45/49 ,  B01J1/10

CPC classification number: C07C45/49

Abstract: DIARYLMERCURY COMPOUNDS IN THF SOLUTIONS REACT WITH CARBON MONOXIDE IN THE PRESENCE OF DICOBALT OCTACARBONYL AND ULTRAVIOLET LIGHT TO PRODUCE DIARYL KETONES.

公开(公告)号：US3658861A

公开(公告)日：1972-04-25

申请号：US3658861D

申请日：1969-09-08

Applicant: MASSACHUSETTS INST TECHNOLOGY

Inventor： SEYFERTH DIETMAR ,  LAMBERT ROBERT L JR

IPC: C07F3/12

CPC classification number: C07F3/12

Abstract: AN ARYL (HALOMETHYL) MERCURY COMPOUND OF THE FORMULA:

R-HGC(H)N-1(X)4-N

WHEREIN R IS SUBSTITUTED OR UNSUBSTITUTED ARYL, X IS HALOGEN AND N IS 1 OR 2 IS OBTAINED BY REACTING AN ARYL MERCURIC HALIDE, AN ALKALI METAL ALKOXIDE AND EITHER DIHALOMETHANE OR A TRIHALOMETHANE AT A TEMPERATURE BETWEEN -80*C. AND 0*C. THE REACTION IS CARRIED OUT IN A HIGHLY POLAR ETHEREAL SOLVENT FOR THE ARYL MERCURIC HALIDE REACTANT. THE ARYL (HALOMETHYL) MERCURY COMPOUNDS FORM DIHALOCARBENES IN SITU TO REACT WITH BASE-SENSITIVE OR WEAKLY NUCLEOPHILIC OLEFINS TO FORM THE RESPECTIVE GEM-DIHALOCYCLOPROPANES.

公开(公告)号：US3694477A

公开(公告)日：1972-09-26

申请号：US3694477D

申请日：1970-11-03

Applicant: MASSACHUSETTS INST TECHNOLOGY

Inventor： SEYFERTH DIETMAR ,  HOPPER STEVEN P ,  DARRAGH KIRK V

IPC: C07F3/10 ,  C07F3/12

CPC classification number: C07F3/10

Abstract: Organo(fluorohalomethyl) mercury compounds are prepared by fluorinating with an organomercuric fluoride, a compound of the formula:

Abstract translation: 有机氟（氟卤代甲基）汞化合物是通过氟化有机化合物氟化物，下式化合物：RHgCX3，其中R是有机基，X是氯或溴，X可以相同或不同。 反应在至少0℃的温度下进行，但在低于该温度的情况下，基本上形成二卤代碳。 有机（氟卤甲基） - 汞产物可用作氟卤代碳原子供体，并用于制备偕二氟环丙烷和偕 - 氟卤代环丙烷。

公开(公告)号：US3899523A

公开(公告)日：1975-08-12

申请号：US41950273

申请日：1973-11-28

Applicant: MASSACHUSETTS INST TECHNOLOGY

Inventor： SEYFERTH DIETMAR ,  LAMBERT JR ROBERT L

IPC: C07F7/08 ,  C07F7/18

CPC classification number: C07F7/1844 ,  C07F7/0807 ,  C07F7/0896

Abstract: Silacyclopropanes having the following formula are provided:

wherein R and R1 can be the same or different and can be hydrogen, alkyl, aryl, substituted alkyl or substituted aryl; n is an integer from 0 to 10; W, X, Y and Z can be hydrogen, alkyl, aryl, substituted alkyl, substituted aryl or W and X or Y and Z on the same ring constituent can be -(CH2)m- wherein m is an integer from 1 to 10. The silacyclopropanes are formed by reacting a bromolithiated compound of the formula:

with a dihalosilane of the formula:

wherein A and A1 are halo and debrominating the resulting product with zinc or magnesium in tetrahydrofuran.

Abstract translation: 提供具有下式的硅环丙烷：WXYZ角度角C - （CH 2）n -C C角度RC |角度角| | R1C角C - （CH 2）n -C角度WXYZ（IV）其中R和 R1可以相同或不同，可以是氢，烷基，芳基，取代的烷基或取代的芳基; n是0至10的整数; W，X，Y和Z可以是氢，烷基，芳基，取代的烷基，取代的芳基或W，同一环成分上的X或Y和Z可以是 - （CH 2）m - ，其中m是1至10的整数 通过使下式的溴化锂化合物：WX ANGLE BrC | ANGLE C ANGLE（CH 2）n | LiC ANGLE YZ与下式的二卤代硅烷反应形成硅环丙烷：其中A和A 1为卤素，并使 得到的产物与锌或镁在四氢呋喃中。