公开(公告)号：US20140288197A1

公开(公告)日：2014-09-25

申请号：US14297901

申请日：2014-06-06

Applicant: MOMENTIVE PERFORMANCE MATERIALS JAPAN LLC

Inventor： Masanari SHIMAKAWA

IPC: C08J9/00

CPC classification number: C08J9/0061 ,  C08G77/12 ,  C08G77/20 ,  C08J3/246 ,  C08J3/247 ,  C08J9/0052 ,  C08J9/0066 ,  C08J9/06 ,  C08J2201/026 ,  C08J2203/00 ,  C08J2383/05 ,  C08J2383/07 ,  C08J2483/05 ,  C08K3/36 ,  C08K5/00 ,  C08K5/14 ,  C08K5/235 ,  C08K5/56 ,  C08L83/00 ,  C08L83/04

Abstract: There are provided a composition for silicone rubber foam, a manufacturing method of a silicone rubber foam, and a silicone rubber foam in which it is possible to control the foaming states. The composition for silicone rubber foam contains: (A) 100 parts by mass of polyorganosiloxane having a degree of polymerization of 4,000 to 10,000 and having two or more alkenyl groups at a content of 0.001 mmol/g or more and less than 0.3 mmol/g; an amount of polyorganohydrogensiloxane having an average of two or more Si-atom-bonded hydrogen atoms so that a molar ratio of the hydrogen atoms to the alkenyl groups in the (A) component is 0.001 to 5; 0.1 to 10 parts by mass of an organic foaming agent with a decomposition temperature of 50 to 250° C.; 5 to 200 parts by mass of silica powder; and a catalyst amount of a platinum-based metal catalyst activated with ultraviolet rays.

Abstract translation: 提供了一种用于硅橡胶泡沫的组合物，硅橡胶泡沫的制造方法和可以控制发泡状态的硅橡胶泡沫。 用于硅橡胶泡沫的组合物包含：（A）100质量份聚合度为4,000至10,000的聚有机硅氧烷，并且具有含有0.001mmol / g以上且小于0.3mmol / g的两个或更多个链烯基 ; 一定量的具有两个以上Si原子键合的氢原子的聚有机氢硅氧烷，使得（A）成分中的氢原子与烯基的摩尔比为0.001〜5; 0.1〜10质量份的分解温度为50〜250℃的有机发泡剂。 5〜200质量份二氧化硅粉末; 和用紫外线活化的铂系金属催化剂的催化剂量。

公开(公告)号：US20140024730A1

公开(公告)日：2014-01-23

申请号：US14036793

申请日：2013-09-25

Applicant: MOMENTIVE PERFORMANCE MATERIALS JAPAN LLC

Inventor： Masanari SHIMAKAWA

IPC: C08L83/04 ,  C08J9/00

CPC classification number: C08J9/0061 ,  C08G77/12 ,  C08G77/20 ,  C08J3/246 ,  C08J3/247 ,  C08J9/0052 ,  C08J9/0066 ,  C08J9/06 ,  C08J2201/026 ,  C08J2203/00 ,  C08J2383/05 ,  C08J2383/07 ,  C08J2483/05 ,  C08K3/36 ,  C08K5/00 ,  C08K5/14 ,  C08K5/235 ,  C08K5/56 ,  C08L83/00 ,  C08L83/04

Abstract: There are provided a composition for silicone rubber foam, a manufacturing method of a silicone rubber foam, and a silicone rubber foam in which it is possible to control the foaming states. The composition for silicone rubber foam contains: (A) 100 parts by mass of polyorganosiloxane having a degree of polymerization of 4,000 to 10,000 and having two or more alkenyl groups at a content of 0.001 mmol/g or more and less than 0.3 mmol/g; an amount of polyorganohydrogensiloxane having an average of two or more Si-atom-bonded hydrogen atoms so that a molar ratio of the hydrogen atoms to the alkenyl groups in the (A) component is 0.001 to 5; 0.1 to 10 parts by mass of an organic foaming agent with a decomposition temperature of 50 to 250° C.; 5 to 200 parts by mass of silica powder; and a catalyst amount of a platinum-based metal catalyst activated with ultraviolet rays.

公开(公告)号：US20210147683A1

公开(公告)日：2021-05-20

申请号：US17158148

申请日：2021-01-26

Applicant: MOMENTIVE PERFORMANCE MATERIALS JAPAN LLC

Inventor： Masanari SHIMAKAWA

IPC: C08L83/04 ,  C08K3/36 ,  C08K3/08

Abstract: There is provided silicone rubber that achieves both a low modulus and high tear strength and a liquid silicone rubber composition that gives the silicone rubber. The liquid silicone rubber composition contains: (A) an alkenyl group-containing linear polyorganosiloxane; (B) a 0.1 to 39 parts by mass linear hydrogenorganopolysiloxane relative to 100 parts by mass of (A); (C) a polyorganosiloxane having alkenyl groups and Si—H whose total number in one molecule is three or more; (D) a hydrosilylation catalyst; and (E) a silica powder having a specific surface area of 100 to 420 m2/g, the content of the silica powder being 10 to 50 parts by mass relative to 100 parts by mass of (A). Relative to the total mass of (A), (B), and (C), the total molar amount of the alkenyl groups of (A) and Si—H of (B) is 0.03 to 0.19 mmol/g, and the total molar amount of the alkenyl groups and SiH of (C) is 0.01 to 0.05 mmol/g. An Si—H/alkenyl group ratio of the composition is 0.7 to 1.3.

公开(公告)号：US20170283614A1

公开(公告)日：2017-10-05

申请号：US15624087

申请日：2017-06-15

Applicant: MOMENTIVE PERFORMANCE MATERIALS JAPAN LLC

Inventor： Kikuo MOCHIZUKI ,  Hidefumi TAGAI ,  Masanari SHIMAKAWA ,  Kazuki SHINBO

IPC: C08L83/04 ,  F21V3/04 ,  G02B1/04 ,  B29C45/00 ,  B29C43/00

Abstract: A polyorganosiloxane composition for molding includes: (A) a straight-chain polyorganosiloxane having two or more alkenyl groups and having a viscosity (25° C.) of 10,000 to 500,000 mPa·s; (B) 30 to 80 mass % of a resinoid polyorganosiloxane including M, D, and Q units, at a molar ratio of a:b:c, on average (0.3≦a≦0.6, 0≦b≦0.1, 0.4≦c≦0.7, and a+b+c=1), and having two or more alkenyl groups; (C) an amount of a polyorganohydrogensiloxane having Si-bonded hydrogen atoms, an average degree of polymerization of 10 or more, a content of the Si-bonded hydrogen atoms of 5.0 mmol/g or more and 11.0 mmol/g or less, and a mass decrease rate up to 140° C. by TGA of 2.0 mass % or less so that an amount of the (Si-bonded hydrogen atoms/alkenyl groups) is 1.0 to 3.0 mol; and (D) a hydrosilylation reaction catalyst. A cured product excellent in mold release property is obtained and contamination of a metal mold is prevented.

公开(公告)号：US20180291160A1

公开(公告)日：2018-10-11

申请号：US16008255

申请日：2018-06-14

Applicant: MOMENTIVE PERFORMANCE MATERIALS JAPAN LLC

Inventor： Masanari SHIMAKAWA

IPC: C08J3/28 ,  C08L83/04 ,  C08K3/36

Abstract: There is provided a silicone rubber composition that has improved moldability, in particular, extrusion moldability, while ensuring that a cured product obtained therefrom has sufficient strength. The silicone rubber composition contains: (A) a 100 part by mass base polymer consisting of (A1) a polyorganosiloxane diol whose viscosity at 25° C. is 1 to 100 Pas and (A2) a polyorganosiloxane whose viscosity at 25° C. is 0.2 to 40000 Pas, with a ratio of (A1) being 20 to 100% by mass to the whole (A), the base polymer having a viscosity of 5 to 20000 Pas at 25° C. and having an alkenyl group content of 0.001 to 0.3 mmol/g; (B) a 10 to 50 part by mass silica powder whose specific surface area is 50 to 400 m2/g; (C) a 1 to 10 part by mass organosilazane; and (D) a catalytic amount of a curing agent.

公开(公告)号：US20150267021A1

公开(公告)日：2015-09-24

申请号：US14730776

申请日：2015-06-04

Applicant: MOMENTIVE PERFORMANCE MATERIALS JAPAN LLC

Inventor： Masanari SHIMAKAWA

IPC: C08J9/00

CPC classification number: C08J9/0061 ,  C08G77/12 ,  C08G77/20 ,  C08J3/246 ,  C08J3/247 ,  C08J9/0052 ,  C08J9/0066 ,  C08J9/06 ,  C08J2201/026 ,  C08J2203/00 ,  C08J2383/05 ,  C08J2383/07 ,  C08J2483/05 ,  C08K3/36 ,  C08K5/00 ,  C08K5/14 ,  C08K5/235 ,  C08K5/56 ,  C08L83/00 ,  C08L83/04

Abstract: There are provided a composition for silicone rubber foam, a manufacturing method of a silicone rubber foam, and a silicone rubber foam in which it is possible to control the foaming states. The composition for silicone rubber foam contains: (A) 100 parts by mass of polyorganosiloxane having a degree of polymerization of 4,000 to 10,000 and having two or more alkenyl groups at a content of 0.001 mmol/g or more and less than 0.3 mmol/g; an amount of polyorganohydrogensiloxane having an average of two or more Si-atom-bonded hydrogen atoms so that a molar ratio of the hydrogen atoms to the alkenyl groups in the (A) component is 0.001 to 5; 0.1 to 10 parts by mass of an organic foaming agent with a decomposition temperature of 50 to 250° C.; 5 to 200 parts by mass of silica powder; and a catalyst amount of a platinum-based metal catalyst activated with ultraviolet rays.

Abstract translation: 提供了一种用于硅橡胶泡沫的组合物，硅橡胶泡沫的制造方法和可以控制发泡状态的硅橡胶泡沫。 用于硅橡胶泡沫的组合物包含：（A）100质量份聚合度为4,000至10,000的聚有机硅氧烷，并且具有含有0.001mmol / g以上且小于0.3mmol / g的两个或更多个链烯基 ; 一定量的具有两个以上Si原子键合的氢原子的聚有机氢硅氧烷，使得（A）成分中的氢原子与烯基的摩尔比为0.001〜5; 0.1〜10质量份的分解温度为50〜250℃的有机发泡剂。 5〜200质量份二氧化硅粉末; 和用紫外线活化的铂系金属催化剂的催化剂量。