公开(公告)号：US20160250626A1

公开(公告)日：2016-09-01

申请号：US15027943

申请日：2014-10-08

Applicant: NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY

Inventor： Yuichiro HIMEDA ,  Wan-Hui WANG ,  Yuichi MANAKA ,  Yuki AMAMOTO

IPC: B01J31/22 ,  C07F15/00 ,  C01B3/22

CPC classification number: B01J31/2295 ,  B01J31/1815 ,  B01J31/183 ,  B01J31/22 ,  B01J2231/763 ,  B01J2531/822 ,  B01J2531/827 ,  B01J2531/96 ,  B01J2540/10 ,  C01B3/22 ,  C01B3/26 ,  C01B32/50 ,  C01B2203/0277 ,  C01B2203/066 ,  C01B2203/1064 ,  C07F15/0033 ,  C07F15/0073 ,  H01M8/0612 ,  H01M8/0618

Abstract: A catalyst including, as effective ingredient, complex represented by Formula (1) which contains bidentate ligand including aromatic heterocyclic 5-membered ring having 2 or more nitrogen atoms, or represented by Formula (2) which contains bidentate ligand including: aromatic heterocyclic 5-membered ring having 2 or more nitrogen atoms; and 6-membered ring having 1 or more nitrogen atoms, isomer or salt of the complex: where M1 and M2 denote transition metal such as iridium; X1 to X16 each independently denote nitrogen or carbon; R1 to R13 denote, for example, hydrogen atom, alkyl group, or hydroxy group, provided that when Xi (where i denotes 13 to 16) is nitrogen, R1 is absent at position corresponding to the nitrogen; L1 and L2 denote, for example, an aromatic anionic ligand; Z1 and Z2 denote any ligand or are absent; and m and n denote positive integer, 0, or negative integer.

Abstract translation: 一种催化剂，其包含作为有效成分的由式（1）表示的配合物，其含有二齿配体，包括具有2个或更多个氮原子的芳族杂环5元环，或由式（2）表示，其含有二齿配体，包括：芳族杂环5- 具有2个以上氮原子的多元环; 和具有1个或更多个氮原子的6元环，络合物的异构体或盐：其中M1和M2表示过渡金属如铱; X1至X16各自独立地表示氮或碳; R 1至R 13表示例如氢原子，烷基或羟基，条件是当Xi（其中i表示13至16）为氮时，R 1在与氮相当的位置处不存在; L1和L2表示例如芳族阴离子配体; Z1和Z2表示任何配体或不存在; m和n表示正整数，0或负整数。

公开(公告)号：US20240367967A1

公开(公告)日：2024-11-07

申请号：US18683936

申请日：2022-08-03

Applicant: NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY

Inventor： Hajime KAWANAMI ,  Yuichiro HIMEDA

IPC: C01B3/22 ,  F17C5/06

Abstract: A purpose of the present invention is to provide a pumpless high-pressure hydrogen supply system capable of supplying high-pressure hydrogen to a fuel cell vehicle, etc., when needed without using a compressor or the like, and a method for the system. The present invention relates to a high-pressure hydrogen supply system that obtains a mixed gas of hydrogen and carbon dioxide by dehydrogenation of formic acid using a complex catalyst, separates the hydrogen therefrom, and supplies the hydrogen at a pressure of 5 MPa or more. By obtaining the mixed gas at a pressure of 5 MPa or more by dehydrogenation and cooling the mixed gas by a separator while maintaining this pressure at 0.4 MPa or more, gas components other than hydrogen are phase separated as liquids or solids and removed. The separated hydrogen is raised in purity by pressure fluctuation adsorption, continuously sent to a pressure accumulator, and stored at a pressure of 70 MPa or more.