公开(公告)号：US20160250626A1

公开(公告)日：2016-09-01

申请号：US15027943

申请日：2014-10-08

Applicant: NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY

Inventor： Yuichiro HIMEDA ,  Wan-Hui WANG ,  Yuichi MANAKA ,  Yuki AMAMOTO

IPC: B01J31/22 ,  C07F15/00 ,  C01B3/22

CPC classification number: B01J31/2295 ,  B01J31/1815 ,  B01J31/183 ,  B01J31/22 ,  B01J2231/763 ,  B01J2531/822 ,  B01J2531/827 ,  B01J2531/96 ,  B01J2540/10 ,  C01B3/22 ,  C01B3/26 ,  C01B32/50 ,  C01B2203/0277 ,  C01B2203/066 ,  C01B2203/1064 ,  C07F15/0033 ,  C07F15/0073 ,  H01M8/0612 ,  H01M8/0618

Abstract: A catalyst including, as effective ingredient, complex represented by Formula (1) which contains bidentate ligand including aromatic heterocyclic 5-membered ring having 2 or more nitrogen atoms, or represented by Formula (2) which contains bidentate ligand including: aromatic heterocyclic 5-membered ring having 2 or more nitrogen atoms; and 6-membered ring having 1 or more nitrogen atoms, isomer or salt of the complex: where M1 and M2 denote transition metal such as iridium; X1 to X16 each independently denote nitrogen or carbon; R1 to R13 denote, for example, hydrogen atom, alkyl group, or hydroxy group, provided that when Xi (where i denotes 13 to 16) is nitrogen, R1 is absent at position corresponding to the nitrogen; L1 and L2 denote, for example, an aromatic anionic ligand; Z1 and Z2 denote any ligand or are absent; and m and n denote positive integer, 0, or negative integer.

Abstract translation: 一种催化剂，其包含作为有效成分的由式（1）表示的配合物，其含有二齿配体，包括具有2个或更多个氮原子的芳族杂环5元环，或由式（2）表示，其含有二齿配体，包括：芳族杂环5- 具有2个以上氮原子的多元环; 和具有1个或更多个氮原子的6元环，络合物的异构体或盐：其中M1和M2表示过渡金属如铱; X1至X16各自独立地表示氮或碳; R 1至R 13表示例如氢原子，烷基或羟基，条件是当Xi（其中i表示13至16）为氮时，R 1在与氮相当的位置处不存在; L1和L2表示例如芳族阴离子配体; Z1和Z2表示任何配体或不存在; m和n表示正整数，0或负整数。