Abstract:
A cellulose resin composition containing a cellulose resin (A) and a high refractive-index organic material (B), in which the cellulose resin (A) is a cellulose derivative obtained by substituting at least part of hydrogen atoms of hydroxy groups of a cellulose with an acyl group having 2 to 4 carbon atoms and a long-chain organic group having 7 or more carbon atoms, and the mass fraction (B/A) of the high refractive-index organic material (B) to the cellulose resin (A) falls within the range of 10/90 to 70/30.
Abstract:
A cellulose derivative having a long-chain organic group having 5 or more carbon atoms and a short-chain organic group having 4 or less carbon atoms which are introduced by use of hydroxy groups of a cellulose, and including a crystal structure derived from a cellulose derivative portion to which the short-chain organic group is linked, wherein an average number of hydroxy groups per glucose unit is of 1.0 or less.
Abstract:
A process for producing a cellulose derivative, comprising: a first step including reacting a cellulose and a first reactant comprising a long-chain reactant for reacting with a hydroxy group of the cellulose to introduce a long-chain organic group having 5 or more carbon atoms, in a solid-liquid heterogeneous system, to form a cellulose derivative in a swollen state, the cellulose derivative having the long-chain organic group having 5 or more carbon atoms introduced therein and having a part of hydroxy groups of the cellulose remained, and performing solid-liquid separation to obtain the cellulose derivative as an intermediate; and a second step including reacting the intermediate cellulose derivative and a second reactant comprising a short-chain reactant for reacting with a remaining hydroxy group of the intermediate cellulose derivative to introduce a short-chain organic group having 4 or less carbon atoms to form a final cellulose derivative having the short-chain organic group having 4 or less carbon atoms introduced therein.
Abstract:
A cellulose resin composition comprising a cellulose resin, a high refractive-index organic material and a carbon black, in which the cellulose resin is an acylated cellulose obtained by substituting at least part of hydrogen atoms of hydroxy groups of a cellulose with an acyl group having 2 to 4 carbon atoms, the carbon black is an acidic carbon black, the mass fraction (B/A) of the high refractive-index organic material (B) to the cellulose resin (A) falls within the range of 10/90 to 70/30, and the content of the carbon black (C) relative to the total of the cellulose resin composition falls within the range of 0.05 to 10% by mass.
Abstract:
A process for producing a cellulose derivative, comprising: a first step including reacting a cellulose and a first reactant comprising a long-chain reactant for reacting with a hydroxy group of the cellulose to introduce a long-chain organic group having 5 or more carbon atoms, in a solid-liquid heterogeneous system, to form a cellulose derivative in a swollen state, the cellulose derivative having the long-chain organic group having 5 or more carbon atoms introduced therein and having a part of hydroxy groups of the cellulose remained, and performing solid-liquid separation to obtain the cellulose derivative as an intermediate; and a second step including reacting the intermediate cellulose derivative and a second reactant comprising a short-chain reactant for reacting with a remaining hydroxy group of the intermediate cellulose derivative to introduce a short-chain organic group having 4 or less carbon atoms to form a final cellulose derivative having the short-chain organic group having 4 or less carbon atoms introduced therein.
Abstract:
A polylactic acid resin composition according to an embodiment of the invention includes a polylactic acid resin, an aliphatic polyester resin, a carbodiimide compound and a metal hydrate, in which the metal hydrate is surface-treated with a specific silane coupling agent; and the carbodiimide compound includes an aliphatic carbodiimide compound.
Abstract:
A composition containing a cellulose resin (X) obtained by binding an organic group to cellulose or a derivative thereof and a linear aliphatic polyester (Y), which is at least one of the following linear aliphatic polyesters (Y1) and (Y2) or a crosslinked product thereof: (Y1) a linear aliphatic polyester containing at least one of repeat units represented by the following formula (I) and formula (II) —(CO—R1—COO—R2—O)— formula (I) where R1 represents a bivalent aliphatic group having 1 to 12 carbon atoms and R2 represents a bivalent aliphatic group having 2 to 12 carbon atoms. —(CO—R3—O)— formula (II) where R3 represents a bivalent aliphatic group having 2 to 10 carbon atoms. (Y2) a linear aliphatic polyester comprising a ring-opening polymerization product of a cyclic ester.
Abstract:
Provided is a cellulose-based resin composition capable of forming a molded body excellent in flame retardancy and mechanical strength, and a molded body formed using the same. The present invention relates to a cellulose-based resin composition including: component (A): cellulose acetate, component (B): a predetermined phosphoric acid ester, component (C): an anti-dripping agent, and component (D): a metal hydroxide, wherein a content of the component (B) is 20% by mass or more and less than 30% by mass based on 100% by mass of a total content of the component (A) and the component (B), and a content of the component (D) is 10% by mass or more and 20% by mass or less based on 100% by mass of a total content of the components (A) to (D).
Abstract:
The present invention provides a cellulose resin composition capable of forming a molded body having high-quality appearance and scratch resistance. A cellulose resin composition including a cellulose derivative, a lubricant, a plasticizer, and a colorant, wherein the cellulose derivative is an acylated cellulose obtained by substituting at least a part of hydrogen atoms of hydroxy groups of a cellulose with an acyl group having 2 to 4 carbon atoms, the content of the lubricant is in a range of 0.1 to 10% by mass, the plasticizer is an aromatic plasticizer, the content of the plasticizer is in a range of 0.1 to 100 parts by mass per 100 parts by mass of the cellulose derivative, and the content of the colorant is in a range of 0.01 to 10% by mass.
Abstract:
A cellulose resin composition comprising a cellulose derivative (A) and a lubricant (B), wherein the cellulose derivative (A) is a cellulose derivative obtained by substituting at least a part of hydrogen atoms of hydroxyl groups of a cellulose with a short-chain organic group having 2 to 4 carbon atoms and a long-chain organic group having 8 to 30 carbon atoms with specific degrees of substitution; the lubricant (B) is at least one selected from the group consisting of a urea compound (B1) having a urea group (—NH—C(═O)—NH—) and an acyclic aliphatic group having 6 to 33 carbon atoms, an amide compound (B2) having an amide group (—C(═O)—NH—) and an acyclic aliphatic group having 6 to 33 carbon atoms, a fatty acid metal salt (B3), and a silicone-based lubricant (B4); and a content of the lubricant (B) is in a range of 0.1 to 10% by mass. A cellulose resin composition capable of forming a molded body having a high-quality appearance and scratch resistance is provided.