公开(公告)号：US20210339227A1

公开(公告)日：2021-11-04

申请号：US17273095

申请日：2019-09-03

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Biju M. DEVASSY ,  Naresh DHACHAPALLY ,  Nigit J. MELEPPURAM ,  Vinod S. NAIR

IPC: B01J23/22 ,  B01J21/04 ,  B01J35/10 ,  B01J37/02 ,  B01J37/08 ,  C07C5/333

Abstract: A catalyst for non-oxidative dehydrogenation of alkanes and a method for making and using the same is disclosed. The catalyst can include vanadium oxide derived from vanadyl oxalate. More particularly the catalyst is prepared by a method comprising the steps of: (a) contacting a transition alumina support with an aqueous solution comprising a vanadium carboxylate material solubilized therein; (b) heating the contacted alumina support to remove the water and produce a catalyst precursor material in solid form; and (c) heating the solid catalyst precursor material in the presence of an oxidizing source at a temperature of 500 to 800° C. to produce an alumina supported catalytic material comprising vanadium oxide. The catalyst can be further modified with an alkali metal oxide like potassium oxide, the precursor thereof being introduced with the impregnation solution.

公开(公告)号：US20230211324A1

公开(公告)日：2023-07-06

申请号：US18001145

申请日：2021-06-10

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Biju M. DEVASSY ,  Nigit J. MELEPPURAM ,  Naresh DHACHAPALLY ,  Vinod S. NAIR

IPC: B01J23/63 ,  B01J21/04 ,  B01J37/02 ,  B01J37/00 ,  B01J37/08 ,  C07C5/32

CPC classification number: B01J23/63 ,  B01J21/04 ,  B01J37/0221 ,  B01J37/0236 ,  B01J37/0009 ,  B01J37/088 ,  B01J37/0072 ,  C07C5/325 ,  C07C2523/63

Abstract: Disclosed are shaped dehydrogenation catalysts, methods for making the catalysts, and methods for dehydrogenating a hydrocarbon using the catalyst. A method for making the shaped dehydrogenation catalyst can include combining a group 13 metal precursor and a group 1 metal precursor with a catalyst support precursor to form a shapeable material, shaping the shapeable material to form a wet shaped material, drying the wet shaped material to form a dry shaped material, and calcining the dry shaped material to form the shaped dehydrogenation catalyst.

公开(公告)号：US20230211318A1

公开(公告)日：2023-07-06

申请号：US18001125

申请日：2021-06-10

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Naresh DHACHAPALLY ,  Nigit J. MELEPPURAM ,  Biju M. DEVASSY ,  Vinod S. NAIR

IPC: B01J23/22 ,  B01J21/12 ,  B01J35/10 ,  B01J37/02 ,  B01J37/08 ,  B01J37/00 ,  C07C5/333

CPC classification number: B01J23/22 ,  B01J21/12 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/0009 ,  B01J37/088 ,  B01J37/0207 ,  B01J37/0236 ,  C07C5/3332 ,  C07C2523/10 ,  C07C2523/22

Abstract: A supported non-oxidative alkane dehydrogenation catalyst and a method for making and using the same is disclosed. The supported non-oxidative alkane dehydrogenation catalyst can include a vanadium oxide, a rare earth metal oxide, an alkali metal oxide, and a support containing silica and alumina.