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1.发明申请公开(公告)号：US20160333181A1
公开(公告)日：2016-11-17
申请号：US15110477
申请日：2015-01-12
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： PAUL DEAN SYBERT , MARK ADRIANUS JOHANNES VAN DER MEE , ROLAND SEBASTIAN ASSINK , ROBERT DIRK VAN DE GRAMPEL , ADITYA NARAYANAN , FENG CAO , KAPIL CHANDRAKANT SHETH , HAO ZHOU , XIAOYU SUN , REMCO WIRTZ
CPC classification number: C08L69/00 , B32B27/08 , C08J5/00 , C08J2369/00 , C08J2469/00 , C08J2479/08 , C08K3/22 , C08K5/526 , C08K2003/2241 , C08L69/005 , C08L79/08 , C08L2201/08 , C08L2203/12 , C08L2203/14 , C08L2205/02 , C08L2205/025 , C08L2205/03 , C08L2205/035 , C08L2205/06 , C08L2207/04 , C25D11/02
Abstract: A thermoplastic composition comprises, based on the total weight of the thermoplastic composition, 10 to 45 wt. % of a poly(etherimide); 35 to 90 wt. % of a poly(carbonate-siloxane); 0.5 to 20 wt. % of compatibilizer polycarbonate component comprising a poly(carbonate-arylate ester); up to 15 wt. % of an ultraviolet light stabilizer; and 0 to 30 wt. % of TiO2; wherein a sample of the composition has a notched Izod impact energy of at least 200 J/m at 23° C. measured in accordance to ASTM D256; and an at least 50% higher notched Izod impact energy value compared to the composition without the compatibilizer component measured in accordance to ASTM D256.
Abstract translation: 基于热塑性组合物的总重量，热塑性组合物包含10至45wt。 ％的聚（醚酰亚胺）; 35〜90重量％ ％的聚（碳酸酯 - 硅氧烷）; 0.5〜20重量％ ％的包含聚（碳酸酯 - 芳基酯）的增容剂聚碳酸酯组分; 高达15wt。 ％的紫外光稳定剂; 和0〜30wt。 ％的TiO2; 其中所述组合物的样品在23℃下具有根据ASTM D256测量的至少200J / m的缺口伊佐德冲击能量; 并且与根据ASTM D256测量的不具有增容剂组分的组合物相比，具有至少50％以上的缺口伊佐德冲击能量值。
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公开(公告)号：US20190169368A1
公开(公告)日：2019-06-06
申请号：US16303393
申请日：2017-05-27
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： MARK ADRIANUS JOHANNES VAN DER MEE , NATHALIE GONZALEZ VIDAL , FABRIZIO MICCICHE , ROLAND SEBASTIAN ASSINK , KAZUHIKO MITSUI , JOHANNES DE BROUWER , SHAHRAM SHAFAEI , HENDRIKUS PETRUS CORNELIS VAN HEERBEEK , TAMARA MARIJKE EGGENHUISEN , ROBERT DIRK VAN DE GRAMPEL
Abstract: A lens comprising a copolycarbonate comprising bisphenol A carbonate units and second carbonate units of the formula (I) and 2 to 40 ppm of an organosulfonic stabilizer of the formula (II), wherein the second carbonate units are present in an amount of 20 to 49 mol %, preferably 30 to 40 mol % based on the sum of the moles of the copolycarbonate and the bisphenol A homopolycarbonate; and the polycarbonate composition has: a Vicat B120 of 160° C. or higher measured according to ISO 306; and a yellowness index of less than 12, measured according to ASTM D1925.
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公开(公告)号：US20190136048A1
公开(公告)日：2019-05-09
申请号：US16095153
申请日：2017-04-28
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： PAUL DEAN SYBERT , TONY FARRELL , ROB BOONMAN , ROBERT DIRK VAN DE GRAMPEL , MARK ADRIANUS JOHANNES VAN DER MEE
Abstract: A melt-blend composition is formed from, based on the total weight of the melt-blend composition, 0 to 5 wt. % of an additive; and 95 to 100 wt. % of a polymer composition, wherein the polymer composition comprises, based on the total weight of the polymer composition, 5 to 95 wt. % of a first copolycarbonate consisting of bisphenol A carbonate units and first additional second copolycarbonate consisting of bisphenol A carbonate units and second additional carbonate units (phthalimidine carbonate units); and 0.001 to 0.1 wt. % of a transesterification catalyst, wherein the melt-blended composition has a haze of less than 15% and a transmission greater than 75%, each measured using the color space CIE1931 (Illuminant C and a 2° observer) at a 3.2 mm thickness.
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4.发明申请公开(公告)号：US20190218391A1
公开(公告)日：2019-07-18
申请号：US16302322
申请日：2017-05-27
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： MARK ADRIANUS JOHANNES VAN DER MEE , NATHALIE GONZALEZ VIDAL , FABRIZIO MICCICHE , ROLAND SEBASTIAN ASSINK , KAZUHIKO MITSUI , JOHANNES DE BROUWER , SHAHRAM SHAFAEI , HENDRIKUS PETRUS CORNELIS VAN HEERBEEK , TAMARA MARIJKE EGGENHUISEN , ROBERT DIRK VAN DE GRAMPEL
CPC classification number: C08G64/12 , C08K5/42 , C08L69/00 , C08L2201/08 , C08L2205/025 , C08L2205/03 , G02B1/04 , G02B1/041 , G02B1/11 , G02B1/14
Abstract: A thermoplastic composition comprises: a copolycarbonate comprising bisphenol A carbonate units and second carbonate units of the formula (I); and 2 to 40 ppm of an organosulfonic stabilizer of the formula (II); wherein the second carbonate units are present in an amount of 20 to 49 mol %, preferably 30 to 40 mol % based on the sum of the moles of the copolycarbonate and the bisphenol A homopolycarbonate, and optionally the copolycarbonate comprises less than 2 ppm by weight of each of an ion of lithium, sodium, potassium, calcium, magnesium, ammonium, chlorine, bromine, fluorine, nitrite, nitrate, phosphite, phosphate, sulfate, formate, acetate, citrate, oxalate, trimethylammonium, and triethylammonium, as measured by ion chromatography; and the thermoplastic composition has: a Vicat B120 of 160° C. or higher measured according to ISO 306; and a yellowness index of less than 12, measured according to ASTM D1925.
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5.发明申请INTERIOR TRAIN COMPONENTS HAVING LOW SMOKE AND LOW HEAT RELEASE, AND METHODS OF THEIR MANUFACTURE 审中-公开具有低烟和低热释放的内部火车部件及其制造方法公开(公告)号：US20160129923A1
公开(公告)日：2016-05-12
申请号：US14997729
申请日：2016-01-18
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： MARK ADRIANUS JOHANNES VAN DER MEE , ROLAND SEBASTIAN ASSINK , ROBERT DIRK VAN DE GRAMPEL , PAUL DEAN SYBERT
CPC classification number: B61D33/0007 , B61D1/04 , B61D37/00 , C08K3/04 , C08K5/523 , C08K5/526 , C08K9/04 , C08L69/005 , C08L83/04 , C08L83/10 , C08L83/06 , C08L69/00 , C08L67/03
Abstract: Seat components and claddings for railway molded or formed from a thermoplastic polymer composition comprising, based on the total weight of the composition, 50 to 93 wt. % of a specific polycarbonate; 4 to 30 wt. % of a poly(carbonate-siloxane) comprising bisphenol A carbonate units, and siloxane units; 3 to 20 wt. % of an organophosphorus compound in an amount effective to provide 0.1 to 2.0 wt. % of phosphorus, based on the total weight of the thermoplastic polymer composition; wherein an article having a thickness of 0.5 to 10 mm molded from the composition has a Ds-4 smoke density≦300 measured according to ISO 5659-2, and a MAHRE≦90 kW/m2 measured according to ISO 5660-1, a multiaxial impact energy≧100 J, and a ductility in multiaxial impact of 80 to 100% at +23° C. according to ISO 6603.
Abstract translation: 用于由热塑性聚合物组合物模制或形成的铁路的座椅部件和包层，包括基于组合物的总重量为50至93wt。 ％的特定聚碳酸酯; 4〜30重量％ ％的含有双酚A碳酸酯单元的聚（碳酸酯 - 硅氧烷）和硅氧烷单元; 3〜20重量％ ％的有机磷化合物的量有效提供0.1至2.0wt。 基于热塑性聚合物组合物的总重量的磷的百分比; 其中由组合物模制的具有0.5至10mm厚度的制品具有根据ISO 5659-2测量的Ds-4烟密度和nlE; 300，根据ISO 5660-1测量的MAHRE＆NlE; 90kW / m 2，多轴 冲击能≥100J，根据ISO 6603，在+ 23℃下多轴冲击的延展性为80〜100％。
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Patent Agency Ranking
6.发明申请公开(公告)号：US20190276665A1
公开(公告)日：2019-09-12
申请号：US16319387
申请日：2017-07-25
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： MARK ADRIANUS JOHANNES VAN DER MEE , NATHALIE GONZALEZ VIDAL , FABRIZIO MICCICHE , ROLAND SEBASTIAN ASSINK , KAZUHIKO MITSUI , JOHANNES DE BROUWER , SHAHRAM SHAFAEI , HENDRIKUS PETRUS CORNELIS VAN HEERBEEK , TAMARA MARIJKE EGGENHUISEN , ROBERT DIRK VAN DE GRAMPEL
Abstract: tic composition includes: a high heat polycarbonate comprising optional bisphenol A carbonate units and high heat carbonate units of the formula (1), (2), (3), or a combination thereof; optionally a bisphenol A homopolycarbonate; and 2 to 40 ppm of an organosulfonic stabilizer of the formula (a) wherein the high heat carbonate units are present in an amount of 20 to 49 mol %, preferably 30 to 40 mol % based on the sum of the moles of the high heat polycarbonate and the bisphenol A homopolycarbonate, and optionally the high heat polycarbonate comprises less than 2 ppm by weight of each of an ion of lithium, sodium, potassium, calcium, magnesium, ammonium, chlorine, bromine, fluorine, nitrite, nitrate, phosphite, phosphate, sulfate, formate, acetate, citrate, oxalate, trimethylammonium, and triethylammonium, as measured by ion chromatography; and the thermoplastic composition has: a Vicat B120 of 160° C. or higher measured according to ISO 306; and a yellowness index of less than 12, measured according to ASTM D1925.
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公开(公告)号：US20190169365A1
公开(公告)日：2019-06-06
申请号：US16095755
申请日：2017-04-28
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： PAUL DEAN SYBERT , TONY FARRELL , ROB BOONMAN , ROBERT DIRK VAN DE GRAMPEL , MARK ADRIANUS JOHANNES VAN DER MEE
Abstract: A poly(carbonate-ester) copolymer including carbonate units of the formula (I); and ester units of the formula (II) wherein: T is a C2-20 alkylene, a C6-20 cycloalkylene, or a C6-20 arylene; and R1 and J are each independently a bisphenol A divalent group, or a phthalimidine divalent group or a third divalent group of the formula (III), (IV), (V), (VI) or (VII) wherein Xa is a C6-12 polycyclic aryl, C3-18 mono- or polycycloalkylene, C3-18 mono- or polycycloalkylidene, -(Q1)x-G-(Q2)y- group wherein Q1 and Q2 are each independently a C1-3 alkylene, G is a C3-10 cycloalkylene, x is 0 or 1, and y is 1, provided that the at least one bisphenol A divalent group, at least one phthalimidine divalent group, and at least one third divalent group are present in the poly(carbonate-ester) copolymer.
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8.发明申请公开(公告)号：US20160326366A1
公开(公告)日：2016-11-10
申请号：US15110472
申请日：2015-01-12
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： PAUL DEAN SYBERT , MARK ADRIANUS JOHANNES VAN DER MEE , ROLAND SEBASTIAN ASSINK , ROBERT DIRK VAN DE GRAMPEL , ADITYA NARAYANAN , FENG CAO , KAPIL CHANDRAKANT SHETH , HAO ZHOU , XIAOYU SUN , REMCO WIRTZ
CPC classification number: C08L69/00 , B32B27/08 , C08J5/00 , C08J2369/00 , C08J2469/00 , C08J2479/08 , C08K3/22 , C08K5/526 , C08K2003/2241 , C08L69/005 , C08L79/08 , C08L2201/08 , C08L2203/12 , C08L2203/14 , C08L2205/02 , C08L2205/025 , C08L2205/03 , C08L2205/035 , C08L2205/06 , C08L2207/04 , C25D11/02
Abstract: A thermoplastic composition comprises, based on the total weight of the thermoplastic composition, 10 to 45 wt. % of a poly(etherimide); 35 to 90 wt. % of a polycarbonate component comprising a polycarbonate homopolymer, a poly(carbonate-siloxane), or a combination thereof; 0.5 to 20 wt. % of a compatibilizer polycarbonate component comprising a poly(carbonate-arylate ester), a phthalimidine copolycarbonate, or a combination thereof; up to 5 wt. % of an ultraviolet light stabilizer; and 0 to 20 wt. % of TiO2, wherein a sample of the composition has a 50% higher notched Izod impact energy value compared to the composition without the compatibilizer component.
Abstract translation: 基于热塑性组合物的总重量，热塑性组合物包含10至45wt。 ％的聚（醚酰亚胺）; 35〜90重量％ ％的包含聚碳酸酯均聚物，聚（碳酸酯 - 硅氧烷）或其组合的聚碳酸酯组分; 0.5〜20重量％ ％的包含聚（碳酸酯 - 芳基酯），苯二甲酰亚胺共聚碳酸酯或其组合的增容剂聚碳酸酯组分; 最多5重量 ％的紫外光稳定剂; 和0〜20wt。 ％的TiO 2，其中与没有相容剂组分的组合物相比，组合物的样品具有高50％的缺口伊佐德冲击能量值。
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公开(公告)号：US20190300701A1
公开(公告)日：2019-10-03
申请号：US16302827
申请日：2017-05-27
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： MARK ADRIANUS JOHANNES VAN DER MEE , NATHALIE GONZALEZ VIDAL , FABRIZIO MICCICHE , ROLAND SEBASTIAN ASSINK , KAZUHIKO MITSUI , JOHANNES DE BROUWER , SHAHRAM SHAFAEI , HENDRIKUS PETRUS CORNELIS VAN HEERBEEK , TAMARA MARIJKE EGGENHUISEN , ROBERT DIRK VAN DE GRAMPEL
Abstract: A thermoplastic composition comprises: a copolycarbonate comprising bisphenol A carbonate units and second carbonate units of the formula (I) and optionally, a bisphenol A homopolycarbonate; wherein the second carbonate units are present in an amount of 10 to 49 mol % based on the sum of the moles of the copolycarbonate and the bisphenol A homopolycarbonate, the copolycarbonate comprises less than 2 ppm by weight of each of an ion of lithium, sodium, potassium, calcium, magnesium, ammonium, chlorine, bromine, fluorine, nitrite, nitrate, phosphite, phosphate, sulfate, formate, acetate, citrate, oxalate, trimethylammonium, and triethylammonium, as measured by ion chromatography, and the thermoplastic composition has a bisphenol A purity of at least 99.6%, or at least 99.7% as determined by high performance liquid chromatography. The thermoplastic composition has a Vicat B120 of 155° C. or higher; and an increase in yellowness index of less than 10 during 1000 hours of heat aging at 155° C.
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公开(公告)号：US20190203043A1
公开(公告)日：2019-07-04
申请号：US16303229
申请日：2017-05-27
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： MARK ADRIANUS JOHANNES VAN DER MEE , NATHALIE GONZALEZ VIDAL , FABRIZIO MICCICHE , ROLAND SEBASTIAN ASSINK , KAZUHIKO MITSUI , JOHANNES DE BROUWER , SHAHRAM SHAFAEI , HENDRIKUS PETRUS CORNELIS VAN HEERBEEK , TAMARA MARIJKE EGGENHUISEN , ROBERT DIRK VAN DE GRAMPEL
CPC classification number: C08L69/00 , C08G64/12 , C08J7/04 , C08J2369/00 , C08J2469/00 , C08L2201/08 , C08L2201/10 , C08L2205/025 , C08L2205/03 , G02B1/04 , G02B1/041
Abstract: A copolycarbonate lens formed from a polycarbonate composition comprising: a copolycarbonate comprising bisphenol A carbonate units and of phthalimide carbonate and optionally, a bisphenol A homopolycarbonate; wherein the second carbonate units are present in an amount of 18 to 35 mol % based on the sum of the moles of the copolycarbonate and the bisphenol A homopolycarbonate, the copolycarbonate comprises less than 2 ppm by weight of each of an ion of lithium, sodium, potassium, calcium, magnesium, ammonium, chlorine, bromine, fluorine, nitrite, nitrate, phosphite, phosphate, sulfate, formate, acetate, citrate, oxalate, trimethylammonium, and triethylammonium, as measured by ion chromatography, and the polycarbonate composition has a bisphenol A purity of at least 99.7% as determined by high performance liquid chromatography. The polycarbonate composition has: a Vicat B120 of 155° C. or higher; and an increase in yellowness index of less than 10 during 1000 hours of heat aging at 155° C.
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