公开(公告)号：US20190136048A1

公开(公告)日：2019-05-09

申请号：US16095153

申请日：2017-04-28

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： PAUL DEAN SYBERT ,  TONY FARRELL ,  ROB BOONMAN ,  ROBERT DIRK VAN DE GRAMPEL ,  MARK ADRIANUS JOHANNES VAN DER MEE

IPC: C08L69/00 ,  C08G64/06

Abstract: A melt-blend composition is formed from, based on the total weight of the melt-blend composition, 0 to 5 wt. % of an additive; and 95 to 100 wt. % of a polymer composition, wherein the polymer composition comprises, based on the total weight of the polymer composition, 5 to 95 wt. % of a first copolycarbonate consisting of bisphenol A carbonate units and first additional second copolycarbonate consisting of bisphenol A carbonate units and second additional carbonate units (phthalimidine carbonate units); and 0.001 to 0.1 wt. % of a transesterification catalyst, wherein the melt-blended composition has a haze of less than 15% and a transmission greater than 75%, each measured using the color space CIE1931 (Illuminant C and a 2° observer) at a 3.2 mm thickness.

公开(公告)号：US20200172665A1

公开(公告)日：2020-06-04

申请号：US16679807

申请日：2019-11-11

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： PAUL DEAN SYBERT ,  ROY RAY ODLE ,  JORDI CALVERAS ,  WEI ZHAO

IPC: C08G64/16 ,  C08G64/28 ,  C08K5/42 ,  G02B1/04

Abstract: A copolycarbonate includes 0.005-0.1 mole percent of sulfur-containing carbonate units derived from a sulfur-containing bisphenol monomer, 2-95 mole percent of high heat carbonate units derived from a high heat aromatic dihydroxy monomer, and 5-98 mole percent of a low heat carbonate units derived from a low heat aromatic monomer, each based on the sum of the moles of the carbonate units; and optionally, thioether carbonyl endcaps of the formula —C(═O)-L-S—R, wherein L is a C1-12 aliphatic or aromatic linking group and R is a C1-20 alkyl, C6-18 aryl, or C7-24 arylalkylene; wherein the sulfur content of the high heat copolycarbonate in the absence of the thioether endcaps is from 5-20 parts per million by weight.

公开(公告)号：US20190134919A1

公开(公告)日：2019-05-09

申请号：US16096010

申请日：2017-04-28

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： TONY FARRELL ,  PAUL DEAN SYBERT

IPC: B29C65/16 ,  B29C65/00 ,  C08K7/14 ,  C08L67/02 ,  C08L69/00 ,  G02B1/04

CPC classification number: B29C65/1616 ,  B29C65/1635 ,  B29C65/1677 ,  B29C66/71 ,  B29C66/712 ,  B29C66/7212 ,  B29C66/72143 ,  B29C66/73321 ,  B29K2105/0085 ,  C08K7/14 ,  C08L67/02 ,  C08L69/005 ,  G02B1/04 ,  B29K2067/006 ,  B29K2067/00 ,  B29K2067/003 ,  B29K2069/00 ,  B29K2309/08

Abstract: A laser weldable composition comprising a polyester component, 5 to 50 weight percent of a filler; and 10 to 30 wt. % of a poly(ester-carbonate) copolymer comprising carbonate units and ester units of the formula (I) wherein: T is a C2-20 alkylene, a C6-20 cycloalkylene, or a C6-20 arylene; R1 and J are each independently (a) a bisphenol A divalent group, and (b) a C16 or higher divalent group (b1), (b2), or (b1) and (b2), wherein (b1) is a phthalimidine divalent group, and (b2) is a third divalent group, wherein the C16 or higher divalent group (b1), (b2) or a combination of (b1) and (b2) is present in an amount of 40 mol % to 50 mol % based on the total moles of the bisphenol A divalent groups and the C16 or higher divalent group; and the composition, when molded into an article having a 2.0 mm thickness, provides a near infrared transmission at 960 nanometers of greater than 50% and a thermal resistance according to HDT 1.8 MPa flat (ISO 75/Af) is greater than 160° C.

公开(公告)号：US20160333181A1

公开(公告)日：2016-11-17

申请号：US15110477

申请日：2015-01-12

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： PAUL DEAN SYBERT ,  MARK ADRIANUS JOHANNES VAN DER MEE ,  ROLAND SEBASTIAN ASSINK ,  ROBERT DIRK VAN DE GRAMPEL ,  ADITYA NARAYANAN ,  FENG CAO ,  KAPIL CHANDRAKANT SHETH ,  HAO ZHOU ,  XIAOYU SUN ,  REMCO WIRTZ

IPC: C08L69/00 ,  C25D11/02 ,  C08J5/00

CPC classification number: C08L69/00 ,  B32B27/08 ,  C08J5/00 ,  C08J2369/00 ,  C08J2469/00 ,  C08J2479/08 ,  C08K3/22 ,  C08K5/526 ,  C08K2003/2241 ,  C08L69/005 ,  C08L79/08 ,  C08L2201/08 ,  C08L2203/12 ,  C08L2203/14 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2205/03 ,  C08L2205/035 ,  C08L2205/06 ,  C08L2207/04 ,  C25D11/02

Abstract: A thermoplastic composition comprises, based on the total weight of the thermoplastic composition, 10 to 45 wt. % of a poly(etherimide); 35 to 90 wt. % of a poly(carbonate-siloxane); 0.5 to 20 wt. % of compatibilizer polycarbonate component comprising a poly(carbonate-arylate ester); up to 15 wt. % of an ultraviolet light stabilizer; and 0 to 30 wt. % of TiO2; wherein a sample of the composition has a notched Izod impact energy of at least 200 J/m at 23° C. measured in accordance to ASTM D256; and an at least 50% higher notched Izod impact energy value compared to the composition without the compatibilizer component measured in accordance to ASTM D256.

Abstract translation: 基于热塑性组合物的总重量，热塑性组合物包含10至45wt。 ％的聚（醚酰亚胺）; 35〜90重量％ ％的聚（碳酸酯 - 硅氧烷）; 0.5〜20重量％ ％的包含聚（碳酸酯 - 芳基酯）的增容剂聚碳酸酯组分; 高达15wt。 ％的紫外光稳定剂; 和0〜30wt。 ％的TiO2; 其中所述组合物的样品在23℃下具有根据ASTM D256测量的至少200J / m的缺口伊佐德冲击能量; 并且与根据ASTM D256测量的不具有增容剂组分的组合物相比，具有至少50％以上的缺口伊佐德冲击能量值。

公开(公告)号：US20190112420A1

公开(公告)日：2019-04-18

申请号：US16096502

申请日：2017-04-28

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： TONY FARRELL ,  PAUL DEAN SYBERT ,  JAMES ALAN MAHOOD

IPC: C08G63/64 ,  C08K5/13

CPC classification number: C08G63/64 ,  C08K5/13

Abstract: A poly(ester-carbonate) copolymer comprises carbonate units of the formula (I); and ester units of the formula (II) wherein: T is a C2-20 alkylene, a C6-20 cycloalkylene, or a C6-20 arylene; and R1 and J are each independently (a) a bisphenol A divalent group and (b) a C16 or higher divalent group (b), wherein the C16 or higher divalent group is present in an amount of 40 to 50 mol %; the ester units are present in an amount of 40 to 60 mol %; the poly(ester-carbonate) copolymer has a weight average molecular weight of 18,000 to 24,000 Daltons; and a sample of the composition has a glass transition temperature of 210° C. to 235° C. as determined by differential scanning calorimetry (DSC) as per ASTM D3418 with a 20° C./min heating rate; and a melt viscosity of less than 1050 Pa-s at 644 sec-1 and 350° C., determined according to ISO 11443.

公开(公告)号：US20170173923A1

公开(公告)日：2017-06-22

申请号：US15300469

申请日：2015-03-30

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： MICHAEL J. DAVIS ,  PAUL DEAN SYBERT ,  PAUL DISCIULLO

IPC: B32B27/08 ,  B32B7/12 ,  B32B15/09 ,  B32B27/12 ,  B29C45/14 ,  B32B27/36 ,  B32B27/30 ,  B32B37/18 ,  B32B37/12 ,  B32B27/18 ,  B32B5/02 ,  B32B27/28

CPC classification number: B32B27/08 ,  B29C45/14336 ,  B29C45/14811 ,  B29K2667/003 ,  B29K2995/0016 ,  B32B5/024 ,  B32B7/12 ,  B32B15/082 ,  B32B15/09 ,  B32B27/12 ,  B32B27/18 ,  B32B27/28 ,  B32B27/283 ,  B32B27/304 ,  B32B27/36 ,  B32B27/365 ,  B32B37/12 ,  B32B37/182 ,  B32B2255/10 ,  B32B2255/26 ,  B32B2262/0238 ,  B32B2262/0253 ,  B32B2262/0261 ,  B32B2262/0269 ,  B32B2262/0276 ,  B32B2262/04 ,  B32B2262/062 ,  B32B2262/065 ,  B32B2262/08 ,  B32B2262/101 ,  B32B2262/103 ,  B32B2262/106 ,  B32B2270/00 ,  B32B2305/188 ,  B32B2307/30 ,  B32B2307/3065 ,  B32B2307/40 ,  B32B2307/71 ,  B32B2307/75 ,  B32B2327/12 ,  B32B2367/00 ,  B32B2369/00 ,  B32B2383/00 ,  B32B2419/00 ,  B32B2439/00 ,  B32B2457/20 ,  B32B2479/00 ,  B32B2509/10 ,  B32B2551/08 ,  B32B2571/00 ,  B32B2605/003

Abstract: A multilayer sheet including: a base layer including a polycarbonatesiloxane-arylate; and a cap layer disposed on a side of the base layer, wherein the cap layer includes poly(ethylene terephthalate), poly(vinyl fluoride), poly(vinylidene fluoride), a silicone hardcoat, or a combination comprising at least one of the foregoing.

公开(公告)号：US20160129923A1

公开(公告)日：2016-05-12

申请号：US14997729

申请日：2016-01-18

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： MARK ADRIANUS JOHANNES VAN DER MEE ,  ROLAND SEBASTIAN ASSINK ,  ROBERT DIRK VAN DE GRAMPEL ,  PAUL DEAN SYBERT

IPC: B61D33/00 ,  C08L69/00 ,  C08L67/03 ,  B61D37/00

CPC classification number: B61D33/0007 ,  B61D1/04 ,  B61D37/00 ,  C08K3/04 ,  C08K5/523 ,  C08K5/526 ,  C08K9/04 ,  C08L69/005 ,  C08L83/04 ,  C08L83/10 ,  C08L83/06 ,  C08L69/00 ,  C08L67/03

Abstract: Seat components and claddings for railway molded or formed from a thermoplastic polymer composition comprising, based on the total weight of the composition, 50 to 93 wt. % of a specific polycarbonate; 4 to 30 wt. % of a poly(carbonate-siloxane) comprising bisphenol A carbonate units, and siloxane units; 3 to 20 wt. % of an organophosphorus compound in an amount effective to provide 0.1 to 2.0 wt. % of phosphorus, based on the total weight of the thermoplastic polymer composition; wherein an article having a thickness of 0.5 to 10 mm molded from the composition has a Ds-4 smoke density≦300 measured according to ISO 5659-2, and a MAHRE≦90 kW/m2 measured according to ISO 5660-1, a multiaxial impact energy≧100 J, and a ductility in multiaxial impact of 80 to 100% at +23° C. according to ISO 6603.

Abstract translation: 用于由热塑性聚合物组合物模制或形成的铁路的座椅部件和包层，包括基于组合物的总重量为50至93wt。 ％的特定聚碳酸酯; 4〜30重量％ ％的含有双酚A碳酸酯单元的聚（碳酸酯 - 硅氧烷）和硅氧烷单元; 3〜20重量％ ％的有机磷化合物的量有效提供0.1至2.0wt。 基于热塑性聚合物组合物的总重量的磷的百分比; 其中由组合物模制的具有0.5至10mm厚度的制品具有根据ISO 5659-2测量的Ds-4烟密度和nlE; 300，根据ISO 5660-1测量的MAHRE＆NlE; 90kW / m 2，多轴 冲击能≥100J，根据ISO 6603，在+ 23℃下多轴冲击的延展性为80〜100％。

公开(公告)号：US20200308398A1

公开(公告)日：2020-10-01

申请号：US16812966

申请日：2020-03-09

Applicant: SABIC Global Technologies B.V.

Inventor： MARK ADRIANUS JOHANNES VAN DER MEE ,  VAIDYANATH RAMAKRISHNAN ,  PAUL DEAN SYBERT ,  MANOJKUMAR CHELLAMUTHU

IPC: C08L69/00 ,  C08G64/12 ,  C08G64/42 ,  C08K5/092 ,  C08K5/42 ,  B29C45/00 ,  G02C7/02

Abstract: A branched polycarbonate comprising: high heat aromatic carbonate units derived from a high heat aromatic dihydroxy monomer units; optionally, low heat carbonate units derived from low heat monomer units; and 0.05-1.5 mole percent, preferably 0.05-1.0 mole percent, of a branching agent based on the total number of moles in the branched polycarbonate; wherein the branched polycarbonate has a tensile stress at break of 10-70 megaPascals measured according to ISO 527, and a glass transition temperature of 170-260° C. measured by differential scanning calorimetry according to ASTM D3418 with a 20° C./min heating rate.

公开(公告)号：US20180273751A1

公开(公告)日：2018-09-27

申请号：US15989572

申请日：2018-05-25

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： MARK ADRIANUS JOHANNES VAN DER MEE ,  ROBERT DIRK VAN DE GRAMPEL ,  ROLAND SEBASTIAN ASSINK ,  PAUL DEAN SYBERT

IPC: C08L69/00 ,  C09K21/14 ,  B32B27/36 ,  C08K5/49 ,  C08L83/10 ,  C08L79/08 ,  C08L79/04 ,  B32B5/00 ,  C08G77/448 ,  C08G73/10

CPC classification number: C08L69/005 ,  B32B5/00 ,  B32B27/365 ,  C08G73/1046 ,  C08G77/448 ,  C08K5/49 ,  C08L69/00 ,  C08L79/04 ,  C08L79/08 ,  C08L83/10 ,  C08L2201/02 ,  C09K21/14

Abstract: A low smoke density thermoplastic composition comprising, based on the total weight of the thermoplastic composition, 70 to 95 wt % of a polycarbonate copolymer comprising first repeating units and second repeating units, wherein the first repeating units are not the same as the second repeating units, and wherein the first repeating units are bisphenol carbonate units of the formula wherein Ra and Rb are each independently C1-12 alkyl, C1-12 alkenyl, C3-8 cycloalkyl, or C1-12 alkoxy, p and q are each independently 0 to 4, and Xa is a single bond, —O—, —S—, —S(O)—, —S(O)2—, —C(O)—, a C1-11 alkylidene of formula —C(Rc)(Rd)— wherein Rc and Rd are each independently hydrogen or C1-10 alkyl, or a group of the formula —C(═Re)— wherein Re is a divalent C1-10 hydrocarbon group; and the second repeating units comprise bisphenol carbonate units that are not the same as the first repeating bisphenol carbonate units, siloxane units, arylate ester units, or a combination of arylate ester units and siloxane units; and 5 to 30 wt % of a polyetherimide based on the weight of the composition, wherein an article molded from the composition has a smoke density (Ds-4) value of equal to or less than 300 as measured by ISO 5659-2 on a 3 mm thick plaque.

公开(公告)号：US20170283612A1

公开(公告)日：2017-10-05

申请号：US15504038

申请日：2015-08-20

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： PAUL DEAN SYBERT ,  JIAN ZHOU ,  LAURA MELY RAMÍREZ ,  YUANQING HE ,  JINFENG ZHUGE ,  HAO ZHOU

IPC: C08L69/00

CPC classification number: C08L69/005 ,  C08G77/448 ,  C08K5/0066 ,  C08K5/49 ,  C08K5/523 ,  C08L51/04 ,  C08L79/08 ,  C08L83/10 ,  C08L2201/02 ,  C08L2205/03 ,  C08L2205/06 ,  C08L2207/53 ,  C08L69/00

Abstract: A thermoplastic composition comprises, based on the total weight of the polymers in the thermoplastic composition, a polycarbonatesiloxane-arylate; 2 to 15 wt % or 2 to 8 wt % or 1 to 4 wt % of a core-shell impact modifier; a flame retardant comprising a bromine-containing polymer or oligomer effective to provide 1.5 wt % to 5 wt % of bromine; an aromatic organophosphorus compound, effective to provide 0.1 to 1 wt % of phosphorus, or a combination comprising at least one of the foregoing; and optionally 0 to 80 wt % or 0 to 60 wt % of a polyetherimide.