公开(公告)号：US20160208025A1

公开(公告)日：2016-07-21

申请号：US14912631

申请日：2014-08-29

Applicant: SAUDI BASIC INDUSTRIES CORPORATION ,  SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Nedumbamana SANKARAN ,  Prashant Sukumar SHINGE ,  Sharankumar SHETTY ,  Girish CHANDRA ,  Haif AL-SHAMMARI ,  Abdulaziz Hamad AL-HUMYDI ,  Edward Joseph NESAKUMAR ,  Pradeep Jeevaji NADKARNI

IPC: C08F110/02 ,  C07F7/00

CPC classification number: C08F110/02 ,  C07F7/00 ,  C07F17/00 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65927 ,  C08F210/16 ,  C08F210/14 ,  C08F2500/03 ,  C08F2500/10

Abstract: The invention relates to a metallocene complex according to formula (1) wherein M is a metal selected from lanthanides or transition metals from group 3, 4, 5 or 6 of the Periodic System of the Elements, Q is an anionic ligand to M, k is the number of Q groups and equals the valence of M minus 2, Z1, Z2, Z3 and Z4 are identical or different and can be chosen from the group consisting of hydrogen and a hydrocarbon radical with 1-20 carbon atoms, and adjacent substituents Z can form a ring system together with the carbon atoms of the Cp ring to which they are bound.

Abstract translation: 本发明涉及根据式（1）的茂金属络合物，其中M是选自元素周期系统的第3,4,5或6族的镧系元素或过渡金属的金属，Q是M，k的阴离子配体 是Q基团的数量并且等于M的代价减去2，Z1，Z2，Z3和Z4是相同或不同的，并且可以选自氢和具有1-20个碳原子的烃基，以及相邻的取代基 Z可以与它们所结合的Cp环的碳原子一起形成环系。

公开(公告)号：US20160168280A1

公开(公告)日：2016-06-16

申请号：US14907923

申请日：2014-07-29

Applicant: SAUDI BASIC INDUSTRIES CORPORATION ,  SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Nedumbamana SANKARAN ,  Prashant Sukumar SHINGE ,  Sharankumar SHETTY ,  Girish CHANDRA ,  Haif AL-SHAMMARI ,  Abdulaziz Hamad AL-HUMYDI ,  Edward Joseph NESAKUMAR

IPC: C08F4/76 ,  C07C211/48 ,  C07F17/00

CPC classification number: C08F4/76 ,  C07C211/48 ,  C07C211/52 ,  C07C2602/08 ,  C07F5/02 ,  C07F5/025 ,  C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F10/02 ,  C08F2420/02

Abstract: A metallocene complex according to formula 1 wherein M is a metal selected from lanthanides or transition metals from group 3, 4, 5, or 6, Q is an anionic ligand to M, k is the number of Q groups and equals the valence of M minus 2, X is a cyclic bridging group that is bonded to a carbon atom of the cyclopentadienyl ligand and to nitrogen, Z1, and Z4 are hydrogen or a hydrocarbon radical with 1-20 carbon atoms; adjacent substituents Z2 and Z3 and are connected to form an indenyl or tetrahydroindenyl ring system and R is hydrogen or a hydrocarbon radical with 1-20 carbon atoms. Also described is a composition comprising the metallocene complex, a process for the preparation of the complex, and a process for the polymerization of olefin polymers in the presence of the metallocene complex.

Abstract translation: 根据式1的茂金属络合物，其中M是选自第3,4,5或6族的镧系元素或过渡金属的金属，Q是M的阴离子配体，k是Q基团的数量，并且等于M的化合价 负2，X是与环戊二烯基配位体的碳原子键合并与氮键合的环状桥连基，Z 1和Z 4是氢或具有1-20个碳原子的烃基; 相邻的取代基Z2和Z3连接形成茚基或四氢茚基环体系，R是氢或1-20个碳原子的烃基。 还描述了包含茂金属络合物的组合物，制备络合物的方法，以及在茂金属络合物存在下聚合烯烃聚合物的方法。

公开(公告)号：US20140275455A1

公开(公告)日：2014-09-18

申请号：US14205530

申请日：2014-03-12

Applicant: SAUDI BASIC INDUSTRIES CORPORATION

Inventor： Haif AL-SHAMMARI ,  Jason MORTON ,  Douglas STEPHAN

IPC: C08F4/76 ,  C08F210/14 ,  C08F110/02

CPC classification number: C08F210/16 ,  C07F17/00 ,  C08F4/00 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65927 ,  C08F10/00 ,  C08F210/14 ,  C08F2500/03 ,  C08F2500/09 ,  C08F2500/10

Abstract: The invention relates to a metallocene complex according to the following formula (1) wherein R1 and R2 are the same or different and are a substituted or unsubstituted, linear or branched, hydrocarbyl group comprising 1 to 30 carbon atoms; M is titanium, zirconium, or hafnium and X1 and X2 are the same and are halogen or a hydrocarbyl group comprising 1 to 20 carbon atoms.

Abstract translation: 本发明涉及根据下式（1）的茂金属络合物，其中R 1和R 2相同或不同，并且是含有1至30个碳原子的取代或未取代的直链或支链烃基; M是钛，锆或铪，X 1和X 2是相同的并且是卤素或包含1至20个碳原子的烃基。

公开(公告)号：US20180044450A1

公开(公告)日：2018-02-15

申请号：US15788140

申请日：2017-10-19

Applicant: SAUDI BASIC INDUSTRIES CORPORATION ,  SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Nedumbamana SANKARAN ,  Prashant SHINGE ,  Sharankumar SHETTY ,  Girish CHANDRA ,  Haif AL-SHAMMARI ,  Abdulaziz Hamad AL-HUMYDI ,  Edward Joseph NESAKUMAR ,  Pradeep Jeevaji NADKARNI

IPC: C08F110/02 ,  C08F4/6592 ,  C07F7/00

Abstract: The invention relates to a metallocene complex according to formula (1) wherein M is a metal selected from lanthanides or transition metals from group 3, 4, 5 or 6 of the Periodic System of the Elements, Q is an anionic ligand to M, k is the number of Q groups and equals the valence of M minus 2, Z1, Z2, Z3 and Z4 are identical or different and can be chosen from the group consisting of hydrogen and a hydrocarbon radical with 1-20 carbon atoms, and adjacent substituents Z can form a ring system together with the carbon atoms of the Cp ring to which they are bound.