PROCESS FOR PREPARING A COPOLYMER
    1.
    发明申请
    PROCESS FOR PREPARING A COPOLYMER 有权
    制备共聚物的方法

    公开(公告)号:US20150376330A1

    公开(公告)日:2015-12-31

    申请号:US14766254

    申请日:2014-03-17

    Abstract: A process for preparing a copolymer comprising subjecting a first cyclic ester having a ring size from 4 to 11 atoms and a second cyclic ester having a ring size from 12 to 40 atoms to ring-opening copolymerization using as catalyst a compound of formula I, wherein M is trivalent Al, Ti, V, Cr, Mn, Co, yttrium, Sc or lanthanides; X and X′ are both a heteroatom; Y and Y′ are O, N, S or P; Z is a substituent as described herein; L1 is an organic moiety linking X and Y; L2 is an organic moiety linking X′ and Y′; L3 is an organic moiety linking Y and Y′ and has a chain length between Y and Y′ of at least 2 atoms. The copolymer has a randomness of at least 0.5 and a number average molecular weight of at least 15000 g/mol.

    Abstract translation: 一种制备共聚物的方法,包括使环大小为4至11个原子的第一环酯和环状大小为12至40个原子的第二环酯用作式I化合物的催化剂进行开环共聚,其中 M是三价Al,Ti,V,Cr,Mn,Co,钇,Sc或镧系元素; X和X'都是杂原子; Y和Y'是O,N,S或P; Z是本文所述的取代基; L1是连接X和Y的有机部分; L2是连接X'和Y'的有机部分; L3是连接Y和Y'并且具有至少2个原子的Y和Y'之间的链长的有机部分。 共聚物的随机性为至少0.5,数均分子量为至少15000g / mol。

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