公开(公告)号：US10053762B2

公开(公告)日：2018-08-21

申请号：US14770737

申请日：2014-02-20

Applicant: SHOWA CO., LTD. ,  MORI KOSAN CO., LTD.

Inventor： Teruki Takayasu ,  Shingo Mori ,  Kinji Onoda

IPC: C23C8/10 ,  C23C8/24 ,  C25D11/26 ,  C10M103/04 ,  C10M103/06 ,  C23C8/34 ,  C23C28/04 ,  B01J21/06 ,  B01J35/00 ,  C23F17/00 ,  C25D7/00 ,  H01G9/20

CPC classification number: C23C8/10 ,  B01J21/063 ,  B01J27/24 ,  B01J35/004 ,  B01J37/0207 ,  B01J37/08 ,  B01J37/12 ,  B01J37/16 ,  B01J37/348 ,  C10M103/04 ,  C10M103/06 ,  C10M2201/053 ,  C10M2201/0623 ,  C23C8/24 ,  C23C8/34 ,  C23C28/042 ,  C23F17/00 ,  C25D7/00 ,  C25D11/26 ,  H01G9/2031

Abstract: A material that is useful as a wear-resistant member, a highly functional photocatalytic material, a photoelectric conversion element material, etc., is produced without the need for complicated processes or complicated handling, which are problems of the prior art. Provided is a method for producing a surface-treated metallic titanium material or titanium alloy material, the method comprising the steps of (1) forming titanium nitride on the surface of a metallic titanium material, and (2) heating the metallic titanium material with titanium nitride formed on the surface thereof obtained in step (1) in an oxidizing atmosphere. Also provided is a method for producing a surface-treated metallic titanium material or titanium alloy material, the method comprising, between steps (1) and (2) above, the step of anodizing the metallic titanium material with titanium nitride formed on the surface thereof obtained in step (1) in an electrolyte solution that does not have an etching effect on titanium, thereby forming a titanium oxide film. Further provided is a surface-treated material.

公开(公告)号：US20160133393A1

公开(公告)日：2016-05-12

申请号：US14897067

申请日：2015-01-19

Applicant: SHOWA CO., LTD.

Inventor： Teruki Takayasu ,  Kinji Onoda ,  Ryosuke Matsuoka ,  Takanori Hattori

IPC: H01G9/20 ,  H01G9/00

CPC classification number: H01G9/2031 ,  H01G9/0029 ,  H01G9/2022 ,  Y02E10/52 ,  Y02E10/542

Abstract: An object of the present invention is to provide a dye-sensitized solar cell that can exhibit high electrical power corresponding to high photoelectric conversion efficiency.Provided is a dye-sensitized solar cell in which a photoelectrode and a counter electrode are disposed opposite to each other via an electrolyte layer; (1) the photoelectrode comprising a titanium material and a titanium oxide layer containing a dye sensitizing agent formed on the titanium material; (2) the counter electrode comprising a transparent conductive glass or transparent conductive film coated with an electrochemical-reduction catalyst layer; and (3) a light-concentrating device being disposed on the counter electrode side.

Abstract translation: 本发明的目的是提供一种可以表现出高光电转换效率高的电力的染料敏化太阳能电池。 提供了一种染料敏化太阳能电池，其中光电极和对电极经由电解质层彼此相对设置; （1）包含钛材料的光电极和在钛材料上形成的含有染料敏化剂的氧化钛层; （2）所述对电极包括涂覆有电化学还原催化剂层的透明导电玻璃或透明导电膜; 和（3）在对电极侧设置的聚光装置。

公开(公告)号：US20190169728A1

公开(公告)日：2019-06-06

申请号：US16272338

申请日：2019-02-11

Applicant: SHOWA CO., LTD. ,  MORI KOSAN CO., LTD

Inventor： Teruki Takayasu ,  Shingo Mori

IPC: C22F1/18 ,  C30B30/02 ,  C30B7/12 ,  C30B29/16 ,  C23C8/24 ,  C23C28/04 ,  C25D11/26 ,  C23C8/80 ,  A47J37/12

Abstract: An object of the present invention is to produce a member useful for preventing edible oil from degrading by performing simple, economical, and safe steps.A method for producing an edible oil degradation-preventing member, comprising the steps of: (1) forming titanium nitride on the surface of a metallic titanium material or titanium alloy material by one treatment method selected from the group consisting of a heat treatment under an ammonia gas atmosphere and a heat treatment under a nitrogen gas atmosphere, at a heating temperature of 750° C. or higher; (2) anodizing the metallic titanium material or titanium alloy material with the titanium nitride formed on the surface thereof obtained in step (1) by applying a voltage of 10 V or more in an electrolyte solution having no etching effect on titanium, thereby forming a titanium oxide film; and (3) heating the metallic titanium material or titanium alloy material with the titanium oxide film formed on the surface thereof obtained in step (2) at a temperature of 400° C. or higher in an atmosphere selected from an air atmosphere, a mixed atmosphere of oxygen gas and nitrogen gas, and an oxygen gas atmosphere.

公开(公告)号：US20160086738A1

公开(公告)日：2016-03-24

申请号：US14889579

申请日：2014-05-07

Applicant: SHOWA CO., LTD.

Inventor： Teruki Takayasu

IPC: H01G9/20 ,  H01G9/00

CPC classification number: H01G9/2031 ,  H01G9/0029 ,  H01G9/2022 ,  H01G9/209 ,  Y02E10/542 ,  Y02P70/521

Abstract: A dye-sensitized solar cell with high photoelectric conversion efficiency and excellent durability is provided.The dye-sensitized solar cell comprises a photoelectrode and a counter electrode that are disposed opposite to each other via an electrolyte layer; (1) the photoelectrode comprising a metal titanium material or titanium alloy material, and a semiconductor layer formed on the metal titanium material or titanium alloy material, the semiconductor layer containing a dye sensitizing agent; (2) the counter electrode comprising a metal titanium material or titanium alloy material coated with an electrochemical-reduction catalyst layer; (3) a light irradiation means being disposed between the photoelectrode and the counter electrode.

Abstract translation: 提供了具有高光电转换效率和优异耐久性的染料敏化太阳能电池。 染料敏化太阳能电池包括通过电解质层彼此相对设置的光电极和对电极; （1）包含金属钛材料或钛合金材料的光电极和形成在金属钛材料或钛合金材料上的半导体层，所述半导体层含有染料敏化剂; （2）所述对电极包括镀有电化学还原催化剂层的金属钛材料或钛合金材料; （3）设置在光电极与对电极之间的光照射装置。

公开(公告)号：US09822025B2

公开(公告)日：2017-11-21

申请号：US14892434

申请日：2013-06-28

Applicant: SHOWA CO., LTD.

Inventor： Teruki Takayasu ,  Teruo Arai ,  Kinji Onoda

IPC: C02F1/32 ,  C02F1/72 ,  C02F1/20 ,  B01D53/86 ,  B01D1/14 ,  B01D53/02 ,  B01D53/88 ,  C02F1/28 ,  B01J21/06 ,  B01J35/00 ,  B01J37/34 ,  B01D53/72 ,  C02F1/467 ,  C02F101/20 ,  C02F101/32 ,  C02F101/36 ,  C02F103/06

CPC classification number: C02F1/725 ,  B01D1/14 ,  B01D53/02 ,  B01D53/72 ,  B01D53/8662 ,  B01D53/8687 ,  B01D53/88 ,  B01D53/885 ,  B01D2253/102 ,  B01D2255/20707 ,  B01D2255/702 ,  B01D2255/802 ,  B01D2257/2064 ,  B01D2257/7027 ,  B01D2259/804 ,  B01J21/063 ,  B01J35/004 ,  B01J37/348 ,  C02F1/20 ,  C02F1/283 ,  C02F1/32 ,  C02F1/4678 ,  C02F2101/20 ,  C02F2101/322 ,  C02F2101/36 ,  C02F2103/06 ,  C02F2305/10 ,  Y02A50/235

Abstract: The present invention provides a novel method for treating soil-contaminated water, the method using a photocatalytic material capable of efficiently removing, by light irradiation alone, volatile organic compounds and heavy metals that give rise to soil contamination. The present invention provides a method for treating soil-contaminated water that detoxifies volatile organic compounds contained in soil-contaminated water using a photocatalytic material, the method being characterized by including the steps of (1) subjecting the soil-contaminated water to a gas-liquid separation to obtain a gas phase, and (2) decomposing the volatile organic compounds contained in the gas phase obtained in step (1) using the photocatalytic material. The present invention further provides a method for treating soil-contaminated water using a photocatalytic material to remove heavy metals contained in the soil-contaminated water, the method being characterized, by including the steps of (1) subjecting the soil-contaminated water to a gas-liquid separation to obtain a liquid phase, and (2) removing the heavy metals contained in the liquid phase obtained in step (1) using the photocatalytic material.

公开(公告)号：US20160257585A1

公开(公告)日：2016-09-08

申请号：US14892434

申请日：2013-06-28

Applicant: SHOWA CO., LTD.

Inventor： Teruki Takayasu ,  Teruo Arai ,  Kinji Onoda

IPC: C02F1/72 ,  C02F1/20 ,  B01D53/02 ,  B01D53/88 ,  C02F1/28 ,  C02F1/32 ,  B01D53/86

CPC classification number: C02F1/725 ,  B01D1/14 ,  B01D53/02 ,  B01D53/72 ,  B01D53/8662 ,  B01D53/8687 ,  B01D53/88 ,  B01D53/885 ,  B01D2253/102 ,  B01D2255/20707 ,  B01D2255/702 ,  B01D2255/802 ,  B01D2257/2064 ,  B01D2257/7027 ,  B01D2259/804 ,  B01J21/063 ,  B01J35/004 ,  B01J37/348 ,  C02F1/20 ,  C02F1/283 ,  C02F1/32 ,  C02F1/4678 ,  C02F2101/20 ,  C02F2101/322 ,  C02F2101/36 ,  C02F2103/06 ,  C02F2305/10 ,  Y02A50/235

Abstract: The present invention provides a novel method for treating soil-contaminated water, the method using a photocatalytic material capable of efficiently removing, by light irradiation alone, volatile organic compounds and heavy metals that give rise to soil contamination. The present invention provides a method for treating soil-contaminated water that detoxifies volatile organic compounds contained in soil-contaminated, water using a photocatalytic material, the method being characterized by including the steps of (1) subjecting the soil-contaminated water to a gas-liquid separation to obtain a gas phase, and (2) decomposing the volatile organic compounds contained in the gas phase obtained in step (1) using the photocatalytic material. The present invention further provides a method for treating soil-contaminated water using a photocatalytic material to remove heavy metals contained in the soil-contaminated water, the method being characterized, by including the steps of (1) subjecting the soil-contaminated water to a gas-liquid separation to obtain a liquid phase, and (2) removing the heavy metals contained in the liquid phase obtained in step (1) using the photocatalytic material.

Abstract translation: 本发明提供了一种处理土壤污染水的新方法，该方法使用能够通过单独的光照射有效除去引起土壤污染的挥发性有机化合物和重金属的光催化材料。 本发明提供一种处理土壤污染的水的方法，该方法使用光催化材料对污染污染的水中的挥发性有机化合物进行解毒，其特征在于包括以下步骤：（1）将受污染的污水进行气体处理 - 液体分离以获得气相，和（2）使用光催化材料分解步骤（1）中获得的气相中包含的挥发性有机化合物。 本发明还提供了一种使用光催化材料处理土壤污染的水的方法，以去除污染土壤污染的水中的重金属，该方法的特征在于包括以下步骤：（1）将受污染的污水 气液分离以获得液相，和（2）使用光催化材料除去步骤（1）中获得的液相中所含的重金属。