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公开(公告)号:US12187893B2
公开(公告)日:2025-01-07
申请号:US17614014
申请日:2020-05-29
Applicant: SHPP Global Technologies B.V.
Inventor: Laura Mely Ramirez , Tony Farrell , Paul Dean Sybert , Remco Wirtz
IPC: C08L83/10 , B33Y70/00 , C09D183/10
Abstract: A thermoplastic composition includes: 40 to 75 wt % of a poly(carbonate-siloxane-arylate); 5 to 45 wt % of a poly(carbonate-siloxane) present in an amount effective to provide 0.75 to 7 wt % of siloxane units; 10 to 40 wt % of a polycarbonate homopolymer; 5 to 15 wt % of an organophosphorus compound in an amount effective to provide 0.1 to 1 wt % of phosphorus; and optionally, 0.1 to 10 wt % of an additive composition. The thermoplastic composition has a melt volume flow rate of greater than 6 cm3/10 min. An article molded from the thermoplastic composition has a 2-minute integrated heat release rate of less than or equal to 65 kW-min/m2 and a peak heat release rate of less than 65 kW/m2 and a notched Izod impact resistance of greater than 30 kJ/m2 or greater than 700 J/m2.
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公开(公告)号:US20240150573A1
公开(公告)日:2024-05-09
申请号:US18277329
申请日:2022-02-24
Applicant: SHPP Global Technologies B.V.
Inventor: Yuntao Li , Hao Zhou , Franklin Ehrensbeck , Laura Mely Ramirez , Peter Vollenberg , Sarah E. Grieshaber
CPC classification number: C08L69/00 , B29C39/003 , B29C48/022 , C08K9/12 , B29K2069/00 , C08K2201/003 , C08L2205/025
Abstract: An composition comprising: a homopolycarbonate; a poly(carbonate-siloxane) having a siloxane content of 30-70 wt %, preferably 35-65 wt %, based on the total weight of the poly(carbonate-siloxane) present in an amount effective to provide 2-10 wt % total siloxane, based on the total weight of the composition; an antimicrobial agent, wherein the antimicrobial agent is a silver zinc zeolite powder, wherein the antimicrobial agent is present in amount effective to provide up to 1000 parts per million of elemental silver based on the total weight of the composition and optionally, an additive composition.
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公开(公告)号:US20230062944A1
公开(公告)日:2023-03-02
申请号:US17796783
申请日:2021-02-10
Applicant: SHPP GLOBAL TECHNOLOGIES B.V.
Inventor: Peter Vollenberg , Christopher Luke Hein , Laura Mely Ramirez
Abstract: A poly(carbonate-siloxane) composition comprising: a poly(carbonate-siloxane) copolymer comprising carbonate units and siloxane units, wherein a siloxane content is greater than 25 wt % to less than 70 wt %, based on the total weight of the poly (carbonate-siloxane) copolymer and wherein the weight average molecular weight of the poly (carbonate-siloxane) copolymer is greater than 30,000 g/mol, as measured by gel permeation chromatography using a crosslinked styrene-divinyl benzene column, using polystyrene standards and calibrated for polycarbonate; a homopolycarbonate comprising a bisphenol A homopolycarbonate; a colorant composition comprising an organic colorant, an inorganic pigment, or a combination thereof, wherein the colorant composition optionally comprises titanium dioxide in an amount of 0.8 wt % or less; optionally, a flame retardant; optionally, an anti-drip agent; optionally, an additive composition, wherein an average siloxane domain size is less than 100 nanometers as determined by scanning electron microscopy, nd a molded sample of the poly(carbonate-siloxane) composition is substantially free of pearlescence.
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公开(公告)号:US20250163265A1
公开(公告)日:2025-05-22
申请号:US18842956
申请日:2023-02-28
Applicant: SHPP GLOBAL TECHNOLOGIES B.V.
Inventor: Wei Zhao , Laura Mely Ramirez , Hao Zhou , Peter Hendrikus Theodorus Vollenberg
Abstract: A polycarbonate composition comprises: a copolycarbonate comprising repeating units derived from a cyclohexylidene-bridged bisphenol; and an auxiliary polycarbonate comprising a branched homopolycarbonate; a poly(1,4-cyclohexanedimethylene terephthalate), a copolycarbonate derived from an isophorylidene-bridged bisphenol, and optionally a poly(alkylene cyclohexanedicarboxylate), poly(carbonate siloxane) having a siloxane content of less than 20 wt % based on the total weight of the poly(carbonatesiloxane), poly(aliphatic ester-carbonate) comprising bisphenol A carbonate units and C6-12 dicarboxy ester units; or a combination thereof. The polycarbonate compositions have one or more of a transparency of 89% or greater on 2.5 mm plaques according to ASTM-D1003-00; and a heat deformation temperature of at least 111° C., or at least 127° C. at 0.45 MPa or at least 98° C., or at least 110° C. at 1.82 MPa as determined on 3.18 mm bars per ASTM D648.
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公开(公告)号:US20220389223A1
公开(公告)日:2022-12-08
申请号:US17834471
申请日:2022-06-07
Applicant: SHPP Global Technologies B.V.
Inventor: Yunfei He , Yun Zheng , Wei Shan , Rui Gao , Yuntao Li , Hao Zhou , Franklin J. Ehrensbeck , Laura Mely Ramirez , Peter Vollenberg , Sarah E. Grieshaber
Abstract: A thermoplastic composition comprising: a homopolycarbonate; a poly(carbonate siloxane) component present in an amount effective to provide 0.5-20 wt % total siloxane content; an antimicrobial agent comprising silver zirconium phosphate, silver phosphate glass, or a combination thereof; optionally, an additive composition; each based on the total weight of the composition which totals to 100 wt %.
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