公开(公告)号：US3772184A

公开(公告)日：1973-11-13

申请号：US3772184D

申请日：1971-12-17

Applicant: STANDARD OIL CO

Inventor： BERTOLACINI R ,  KIM D

IPC: B01J23/36 ,  B01J23/656 ,  B01J27/128 ,  C09K8/64 ,  C10G35/06 ,  C10G35/09 ,  C10G59/02 ,  C10L7/02 ,  C10G35/08 ,  B01J11/08 ,  B01J11/78 ,  C10G39/00

CPC classification number: C10G35/09 ,  B01J23/6567 ,  C09K8/64 ,  C10G35/06 ,  C10G59/02 ,  C10L7/02

Abstract: The catalyst comprises a hydrogenation component, a small amount of rhenium, and a small amount of gallium on a solid catalytic support comprising a porous refractory inorganic oxide. The rhenium and the gallium may be present either in the elemental form or as compounds. The preferred hydrogenation component is a Group VIII noble metal and the preferred porous refractory inorganic oxide is a catalytically active alumina. The reforming process comprises contacting a petroleum hydrocarbon stream in a reforming zone under reforming conditions and in the presence of hydrogen with the above-described catalyst. In one embodiment, the process comprises contacting a partially-reformed hydrocarbon stream in a reforming zone under reforming conditions and in the presence of hydrogen with the above catalyst. In another embodiment, the process comprises contacting a naphtha in a reforming zone under reforming conditions and in the presence of hydrogen with the above catalyst. In a third embodiment, the process comprises contacting the petroleum hydrocarbon stream in a first reforming zone under reforming conditions and in the presence of hydrogen with a first reforming catalyst to produce a first reformate and subsequently contacting the first reformate in a second reforming zone under reforming conditions and in the presence of hydrogen with a second reforming catalyst, said second reforming catalyst being the catalyst described in the preceding paragraph.

Abstract translation: 催化剂包含氢化组分，少量的铼和少量的含有多孔耐火无机氧化物的固体催化载体上的镓。 铼和镓可以以元素形式存在或作为化合物存在。 优选的氢化组分是VIII族贵金属，优选的多孔耐火无机氧化物是催化活性氧化铝。

公开(公告)号：US3714032A

公开(公告)日：1973-01-30

申请号：US3714032D

申请日：1970-11-25

Applicant: STANDARD OIL CO

Inventor： BERTOLACINI R ,  RADFORD H

IPC: B01J23/28 ,  C10G49/02 ,  C10G49/04 ,  C10G49/08 ,  C10G23/12

CPC classification number: C10G49/08 ,  B01J23/28 ,  C10G49/02 ,  C10G49/04

Abstract: The process comprises contacting the high-boiling petroleum hydrocarbon feedstock under hydrocarbon conversion conditions and in the presence of hydrogen with a catalyst comprising a member selected from the group consisting of (1) uranium and a second hydrogenation metal, (2) their oxides, (3) their sulfides, and (4) mixtures thereof supported on a porous refractory inorganic oxide having an average pore diameter of about 100 Angstroms to about 300 Angstroms and a surface area in excess of 200 square meters per gram. The preferred second hydrogenation metal is molybdenum and the preferred porous refractory inorganic oxide is alumina.

Abstract translation: 该方法包括在烃转化条件下和氢存在下使高沸点石油烃原料与包含选自（1）铀和第二氢化金属的组分的催化剂接触，（2）其氧化物， 3）它们的硫化物，和（4）其负载在平均孔径为约100埃至约300埃的多孔耐火无机氧化物上并且其表面积超过200平方米每克的混合物。 优选的第二加氢金属是钼，优选的多孔耐火无机氧化物是氧化铝。

公开(公告)号：US3729521A

公开(公告)日：1973-04-24

申请号：US3729521D

申请日：1970-09-01

Applicant: STANDARD OIL CO

Inventor： GUTBERLET L ,  BERTOLACINI R ,  BRENNAN H

IPC: B01J29/08 ,  B01J29/16 ,  B01J29/70 ,  B01J29/90 ,  B01J37/20 ,  C07C6/00 ,  C07C6/12 ,  C07C15/00 ,  C07C3/00

CPC classification number: C07C6/123 ,  B01J29/084 ,  B01J29/166 ,  B01J29/70 ,  B01J29/90 ,  B01J37/20 ,  B01J2229/26 ,  B01J2229/42 ,  C07C6/00 ,  Y02P20/584

Abstract: THE PROCESS COMPRISES CONTACTING IN A REACTION ZONE A PETROLEUM HYDROCARBON FRACTION WITH A CATALYTIC COMPOSITION UNDER SUITABLE DISPROPORTIONATION CONDITIONS, SAID CATALYTIC COMPOSITION COMPRISING A MEMBER SELECTED FROM THE GROUP CONSISTING OF (1) A METAL OF GROUP VI-B OF THE PERIODIC TABLE OF ELEMENTS, 2() A METAL OF GROUP VIII OF THE PERIODIC TABLE, (3) THE OXIDE OF A METAL OF GROUP VI-B, (4) THE SULFIDE OF A METAL OF GROUP VI-B, (5) THE OXIDE OF A METAL OF GROUP VIII, (6) THE SULFIDE OF A METAL OF GROUP VIII, AND (7) MIXTURES THEREOF DEPOSITIONED UPON A SOLID ACIDIC CRACKING SUPPORT, WHICH SUP/ PORT COMPRISES AN ULTRASTABLE, LARGE-PORE CRYSTALLINE ALUMINOSILICATE MATERIAL AND A REFACTORY INORGANIC OXIDE. THE PREFERRED METAL OF GROUP VI-B IS MOLYBDENUM AND THE PREFERRED METAL OF GROUP VIII IS COBALT. THE CATALYST IS SUBJECTED TO A SULFUR-PROVIDING COMPOUND TO INHIBIT DEMETHANATION.

公开(公告)号：US3835031A

公开(公告)日：1974-09-10

申请号：US36308273

申请日：1973-05-23

Applicant: STANDARD OIL CO

Inventor： BERTOLACINI R ,  LEHMANN G ,  WOLLASTON E

IPC: B01D53/86 ,  B01J8/26 ,  B01J20/18 ,  B01J27/00 ,  B01J29/00 ,  B01J29/06 ,  B01J29/90 ,  B01J38/12 ,  C10G11/00 ,  C10G11/04 ,  C10G11/05 ,  C10G11/18 ,  B01J11/68 ,  C01B17/56

CPC classification number: C10G11/05 ,  B01J8/26 ,  B01J20/186 ,  B01J29/06 ,  B01J2229/20 ,  Y10S502/517

Abstract: A CYCLIC FLUIDIZED CATALYTIC CRACKING PROCESS IS OPERATED WITH A CATALYST COMPRISING MOLECULAR SIEVE IN A SILICAALUMINA MATRIX, IMPREGNATED WITH ONE OR MORE GROUP IIA METAL OXIDES, TO PROVIDE FROM ABOUT 0.25 TO ABOUT 5.0 WT. PERCENT OF GROUP IIA METAL OR METALS. THE EMISSION OF SULFUR OXIDES IN THE REGENERATOR STACK GASES IS DECREASED BY AT LEAST ABOUT 50%.

公开(公告)号：US3841995A

公开(公告)日：1974-10-15

申请号：US36920973

申请日：1973-06-12

Applicant: STANDARD OIL CO

Inventor： BERTOLACINI R ,  HOPKINS P ,  MENZL R

IPC: B01J23/40 ,  C10G45/10 ,  C10G65/04 ,  C10G23/04

CPC classification number: C10G45/10 ,  B01J23/40 ,  C10G2400/10

Abstract: 1. A PROCESS FOR THE PRODUCTION OF A COLORLESS MINERAL OIL, WHICH PROCESS COMPRISES CONTACTING A DEWAXED MINERAL LUBRICATING OIL DISTILLATE OR A DEWAXED AND SOLVENTEXTRACTED MINERAL LUBRICATING OIL DISTILLATE OF REDUCED AROMATIC HYDROCARBON CONTENT IN A FIRST REACTION ZONE WITH A SULFACTIVE HYDROGENATION CATALYST IN THE PRESENCE OF HYDROGEN AND UNDER HYDROGENATION AN DESULFURIZATION CONDITIONS TO PRODUCE A HYDROGENATED AND DESULFURIZED PRODUCT; CONTACTING SAID HYDROGENATED AND DESULFURIZED PRODUCT IN A SECOND REACTION ZONE WITH A SECOND CATALYST COMPRISING A GROUP VIII NOBLE METAL EPOSITED UPON A LARGE-PORE-DIAMETER ALUMINA HAVING A SURFACE AREA OF ABOUT 150 SQUARE METERS PER GRAM TO ABOUT 500 SQUARE METERS PER GRAM AND AN AVERAGE PORE DIAMTER OF ABOUT 100 A. TO BOUT 200 A. IN THE PRESENCE OF HYROGEN AND AT A TEMPERATURE OF AT LEAST 450*F. A LHSV OF ABOUT 0.25 TO ABOUT 1 VOLUME OF HYDROCARBON PER HOUR PER VOLUME OF CATALYST, A HYDROGEN ADDITION RATE OF ABOUT 1,500 SCFB TO ABIUT 7,00 SCFB, AND A HYDROGEN PARTIAL PRESSURE OF AT LEAST 500 P.S.I.G. SAID TEMPERATURE IN SAID SECOND REACTION ZONE HAVING A MAXIMUM VALUE OF 500*F. AND RECOVERING SAID COLORLESS MINERAL OIL FROM THE EFFLUENT FROM SAID SECOND REACTION ZONE.

Abstract translation: 该方法包括在氢气和脱硫条件下使第一反应区中的矿物润滑油馏出物与磺化氢化催化剂接触，以在氢化和脱硫条件下使第二反应区中的脱硫产物与催化剂组合物接触， 本发明在氢气存在下和在选择的条件下。

公开(公告)号：US3798154A

公开(公告)日：1974-03-19

申请号：US3798154D

申请日：1972-03-01

Applicant: STANDARD OIL CO

Inventor： BERTOLACINI R ,  BRENNAN H

IPC: C10G35/095 ,  C10G35/08 ,  C10G35/06 ,  C10G39/00

CPC classification number: C10G35/095

Abstract: THE CATALYST COMPRISES A HYDROGENATION COMPONENT COMPRISING A MEMBER SELECTED FROM THE GROUP CONSISTING OF A METAL OF GROUP VI-A, COMPOUNDS OF A METAL OF GROUP VI-A, AND MIXTURES THEREOF SUPPORTED ON A CO-CATALYTIC SOLID SUPPORT COMPRISING MORDENITE AND A POROUS REFRACTORY INORGANIC OXIDE. THE HYDROGENATION COMPONENT MAY BE CHARACTERIZED FURTHER BY A MEMBER SELECTED FROM THE GROUP CONSISTING OF RHENIUM, COMPOUNDS OF RHENIUM, A NON-NOBLE METAL OF GROUP VIII, COMPOUNDS OF A NON-NOBLE METAL OF GROUP VIII, AND MIXTURES THEREOF. THE PREFERRED GROUP VI-A METAL IS MOLYBDENUM. A REFORMING PROCESS COMPRISES CONTACTING A PETROLEUM HYDROCARBON STREAM IN A REFORMING ZONE UNDER REFORMING CONDITIONS AND IN THE PRESENCE OF HYDROGEN WITH THE ABOVE CATALYST. IN ONE EMBODIMENT. THE PROCESS COMPRISES CONTACTING A PARTIALLY-REFORMED HYDROCARBON STREAM IN A REFORMING ZONE UNDER REFORMING CONDITIONS AND IN THE PRESENCE OF HYDROGEN WITH THE ABOVE CATALYST. IN ANOTHER EMBODIEMENT, THE PROCESS COMPRISES CONTACTING THE PETROLEUM HYDROCARBON STREAM IN A FIRST REFORMING ZONE UNDER REFORMING CONDITIONS AND IN THE PRESENCE OF HYDROGEN WITH A CATALYST COMPRISING A PLATINUM GROUP METAL AND A HALIDE ON ALUMINA TO PRODCE A FIRST REFORMATE AND SUBSEQUENTLY CONTACTING THE FIRST REFORMATE IN A SECOND REFORMING ZONE UNDER REFORMING CONDITIONS AND IN THE PRESENCE OF HYDROGEN WITH THE AVOVE CATALYST.

公开(公告)号：US3772183A

公开(公告)日：1973-11-13

申请号：US3772183D

申请日：1971-12-17

Applicant: STANDARD OIL CO

Inventor： BERTOLACINI R ,  KIM D

IPC: B01J23/00 ,  B01J23/62 ,  B01J27/00 ,  C10G35/09 ,  C10G59/02 ,  C10G39/00

CPC classification number: C10G59/02 ,  B01J23/62 ,  C10G35/09

Abstract: There is provided a process for reforming a petroleum hydrocarbon stream, which process comprises contacting said hydrocarbon stream in a first reforming zone under reforming conditions and in the presence of hydrogen with a first reforming catalyst to produce a first reformate and subsequently contacting said first reformate in a second reforming zone under reforming conditions and in the presence of hydrogen with a second catalyst comprising a hydrogenation component and a small amount of gallium on a solid catalytic support comprising a porous refractory inorganic oxide. The first reforming catalyst may be any suitable reforming catalyst in the art.

Abstract translation: 提供了一种重整石油烃流的方法，该方法包括在重整条件下和在氢的存在下在第一重整区中与第一重整催化剂接触所述烃流以产生第一重整产物，随后使所述第一重整产物 在重整条件下和在氢的存在下，在包含多孔难熔性无机氧化物的固体催化载体上含有氢化组分和少量镓的第二催化剂的第二重整区。 第一重整催化剂可以是本领域任何合适的重整催化剂。