Copolymeric polyamide-acids,amideimides and copolyimides containing azo linkages and process for their preparation
    1.
    发明授权
    Copolymeric polyamide-acids,amideimides and copolyimides containing azo linkages and process for their preparation 失效
    含有AZO链接的共聚聚酰胺,酰亚胺和共聚物及其制备方法

    公开(公告)号:US3773725A

    公开(公告)日:1973-11-20

    申请号:US3773725D

    申请日:1970-08-03

    Inventor: PUSKAS I FIELDS E

    CPC classification number: C08G73/1096 C08G73/1042 C08G73/14

    Abstract: COPOLYMER COMPOSITIONS OF THE AMIDE-IMIDE VARIETY ARE MADE BY POLYMERIZING PRIMARY DIAMINES WITH AZOBENZENETETRACARBOXYLIC ACID DIANHYDRIDE AND AROMATIC POLYCARBOXYLIC ACID ANHYDRIDE COMONOMERS. THE POLYMERS ARE LINEAR, SHAPABLE, HIGHLY-SOLUBLE COMPOSITIONS WHICH AS FORMED CONTAIN AMIDE ACID GROUPS. THE POLYMERS IN DRY POWDER FORM ARE USEFUL FOR COMPRESSION MOLDING AND IN SOLUTION FORM ARE USEFUL FOR ADHESIVE COATINGS, POROUS MATERIAL IMPREGNATING, CASING FILMS, PREPARING FIBERS AND INSULATING COATINGS. THE POLYMERS ARE HEAT-MODIFIABLE CONVERTING TO THE IMIDE FORM AT ELEVATED TEMPERATURES PRODUCING COMPOSITIONS HAVING EXCELLENT SOLVENT RESISTANCE, THERMAL STABILITY AND ELECTRICAL PROPERTIES.

    Process for coupling organic molecules
    2.
    发明授权
    Process for coupling organic molecules 失效
    偶联有机分子的方法

    公开(公告)号:US3849274A

    公开(公告)日:1974-11-19

    申请号:US37533373

    申请日:1973-07-02

    Inventor: FIELDS E

    CPC classification number: C07C253/30 B01J19/123 Y02P20/582

    Abstract: A process for coupling organic molecules involving the step of irradiating an organic compound with ultraviolet light in the presence of hexachlorobenzene, hexabromobenzene or hexaiodobenzene under an inert gas. The process is useful for producing an intermolecular carbon-to-carbon bond by a hydrogen abstraction mechanism from such compounds as acetic acid, methyl acetate, diethyl ether, and phenyl acetonitrile.

    Process for preparing aromatic cyclic thiones
    3.
    发明授权
    Process for preparing aromatic cyclic thiones 失效
    制备芳香环的方法

    公开(公告)号:US3818041A

    公开(公告)日:1974-06-18

    申请号:US30018872

    申请日:1972-10-24

    Inventor: FIELDS E

    Abstract: Aromatic cyclic thiones are synthesized and a process for preparing them by the thermal conversion of aromatic carboxylic acid anhydride to its aryne form and reaction therewith of carbon disulfide is described. The products are useful as bactericides and as extreme-pressure additives in lubricating compositions.

    Abstract translation: 合成芳族环状硫杂子,并描述通过芳族羧酸酐热转化成其二炔形式并与二硫化碳反应来制备芳族环硫酸钠的方法。 该产品可用作杀菌剂和润滑组合物中的极压添加剂。

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