公开(公告)号：US3751365A

公开(公告)日：1973-08-07

申请号：US3751365D

申请日：1972-01-07

Applicant: STANDARD OIL CO

Inventor： PIASEK E ,  KARLL R

IPC: C07C275/14 ,  C07F5/02 ,  C07F5/04 ,  C08F8/32 ,  C08F8/42 ,  C10M159/16 ,  C10M1/54

CPC classification number: C10M159/16 ,  C07C275/14 ,  C07F5/022 ,  C07F5/04 ,  C08F8/32 ,  C08F8/42 ,  C10M2215/04 ,  C10M2215/062 ,  C10M2215/065 ,  C10M2215/102 ,  C10M2215/22 ,  C10M2215/221 ,  C10M2215/224 ,  C10M2215/225 ,  C10M2215/226 ,  C10M2215/26 ,  C10M2215/30 ,  C10M2217/046 ,  C10M2217/06 ,  C10M2219/044 ,  C10M2219/046 ,  C10M2219/064 ,  C10M2219/066 ,  C10M2221/00 ,  C10M2223/045 ,  C10M2227/06 ,  C10M2227/061 ,  C10N2210/02 ,  C10N2210/03 ,  C10N2230/12 ,  C10N2250/121 ,  C10N2270/02 ,  C08F110/00

Abstract: 1.0:0-0.7:0.1-10:1.0-10,

OIL SOLUTIONS OF BORON-CONTAINING DERIVATIVE OF PRODUCTS OF MANNICH REACTION BY CONDENSATION OF REACTANTS (1) A HIGH MOLECULAR WEIGHT ALKYL-SUBSTITUTED HYDROXYAROMATIC COMPOUND WHOSE ALKYL SUBSTITUENT HAS UPWARD FROM 40 TO 20,000 CARBON ATOMS, (2) A LOWER ALKYL-SUBSTITUTED PHENOL WHOSE ALKYL GROUP HAS 2 TO 20 CARBON ATOMS, (3) AN AMINE WHICH CONTAINS A HN WHEREIN THE BORON CONTENT OF SAID DERIVATIVE OF THE MANNICH REACTION EXPRESSED AS A BORON TO NITROGEN WEIGHT RATIO (B/N) IS IN THE RANGE OF 0.1-5.5:1.0 AND SAID BORON DERIVATIVE IS PRESENT IN WEIGHT CONCENTRATIONS OF 0.05 TO 70 PERCENT AS SOLUTE IN MINERAL OIL OF THE LUBRICATING OIL TYPES. SUCH OIL SOLUTIONS ARE USEFUL AS CRANKCASE LUBRICATING COMPOSITIONS, OR AS CONCENTRATES FOR FORTIFYING USED CRANKCASE LUBRICATING COMPOSITION AND FOR PREPARATION OF CRANKCASE LUBRICATING COMPOSITON. SUCH SOLUTIONS PROVIDE DETERGENCY, DISPERSANCY AND ANTIOXIDANT PROPERTIES NECESSARY FOR CRANKCASE OIL FUNCTION UNDER HIGH SEVERITY ENGINE OPERATION.

公开(公告)号：US3798247A

公开(公告)日：1974-03-19

申请号：US3798247D

申请日：1970-07-13

Applicant: STANDARD OIL CO

Inventor： PIASEK E ,  KARLL R

IPC: C07D239/16 ,  C07D239/22 ,  C08F8/32 ,  C10M135/10 ,  C10M137/10 ,  C10M159/16 ,  C10N30/04 ,  C10N30/10 ,  C09F7/00

CPC classification number: C10M159/16 ,  C08F8/32 ,  C10M2203/06 ,  C10M2205/00 ,  C10M2205/02 ,  C10M2205/026 ,  C10M2205/028 ,  C10M2207/282 ,  C10M2207/34 ,  C10M2209/084 ,  C10M2209/103 ,  C10M2215/04 ,  C10M2215/062 ,  C10M2215/08 ,  C10M2215/082 ,  C10M2215/12 ,  C10M2215/22 ,  C10M2215/221 ,  C10M2215/224 ,  C10M2215/225 ,  C10M2215/226 ,  C10M2215/26 ,  C10M2215/28 ,  C10M2215/30 ,  C10M2217/028 ,  C10M2217/042 ,  C10M2217/043 ,  C10M2217/046 ,  C10M2217/06 ,  C10M2219/044 ,  C10M2223/045 ,  C10M2229/02 ,  C10M2229/05 ,  C10N2210/02 ,  C10N2230/12 ,  C10N2240/04 ,  C10N2240/042 ,  C10N2240/044 ,  C10N2240/046 ,  C10N2240/10 ,  C10N2240/101 ,  C10N2240/104 ,  C10N2240/106 ,  C08F110/00

Abstract: NOVEL ALIPHATIC ACID DERIVATIVES OF HIGH MOLECULAR WEIGHT MANNICH CONDENSATION PRODUCTS OF (1) HIGH MOLECULAR WEIGHT ALKYL-SULBSTITUTED HYDROXY AROMATIC COMPOUNDS WHOSE ALKYL-SUBSTITUENT HAS A NUMBER AVERAGE MOLECULAR WEIGHT ($N) FROM ABOUT 600-100,000, (2) A COMPOUND CONTAINING AT LEAST ONE HN

公开(公告)号：US3793202A

公开(公告)日：1974-02-19

申请号：US3793202D

申请日：1972-03-01

Applicant: STANDARD OIL CO

Inventor： PIASEK E ,  KARLL R

IPC: C08F8/00 ,  C10M159/16 ,  C10M1/32

CPC classification number: C10M159/16 ,  C08F8/00 ,  C10M2205/026 ,  C10M2209/084 ,  C10M2215/04 ,  C10M2215/062 ,  C10M2215/22 ,  C10M2215/221 ,  C10M2215/224 ,  C10M2215/225 ,  C10M2215/226 ,  C10M2215/26 ,  C10M2215/30 ,  C10M2217/046 ,  C10M2217/06 ,  C10M2219/046 ,  C10M2223/045 ,  C10N2210/02 ,  C10N2230/12 ,  C10N2270/02 ,  C08F10/00

Abstract: Protection against corrosion and deposition of sludge and varnish is provided by lubricating oils containing a minor amount of the ashless type addition agents which are prepared by reacting under conditions of the Mannich Reaction (1) a high molecular weight alkyl-substituted hydroxy aromatic compound, in which the alkyl-substituent has an average molecular weight of from about 600 to about 100,000, (2) an amine compound containing at least one HN

Abstract translation: 污泥和清漆的腐蚀和沉积防护由含少量无灰型添加剂的润滑油提供，该添加剂通过在Mannich反应（1）高分子量烷基取代的羟基芳族化合物的条件下反应而制备， 烷基取代基的平均分子量为约600至约100,000，（2）含有至少一个HN（3）脂族醛的胺化合物，和（4）含有至少6个碳原子的脂肪酸 原子，各自的反应物摩尔比为1：0.1-10：1-10：0.014-1.0，并进一步使这种改性缩合产物与每摩尔烷基取代的羟基芳族化合物约2至约6摩尔脂族醛反应 复合。

公开(公告)号：US3833618A

公开(公告)日：1974-09-03

申请号：US29364772

申请日：1972-09-29

Applicant: STANDARD OIL CO

Inventor： PIASEK E ,  PUSKAS I

IPC: C07D209/48 ,  C07D307/89 ,  C10M129/95 ,  C10M133/52 ,  C07C63/18 ,  C07C69/76

CPC classification number: C07D209/48 ,  C07D307/89 ,  C10M129/95 ,  C10M133/52

Abstract: TITLE COMPOUNDS ARE NOVEL OIL-SOLUBLE ANHYDRIDES AND THEIR ANALOGOUS DIACIDS. THE ANHYDRIDES ARE OBTAINED BY REACTION OF C30-214 ALKYL-SUBSTITUTED PHENOL WITH 4-ACID CHLORIDE OF TRIMELLITIC ANHYDRIDE WHICH CAN BE READILY HYDROLYZED WITH WATER TO THE ANALOGOUS DIACIDS. THE TITLE COMPOUNDS ARE USEFUL ANTI-RUST AND/OR ANTI-WEAR ADDITION AGENTS FOR LUBRICANTS AND AS INTERMEDIATE REACTANTS WITH ALCOHOLS AND AMINES FOR PREPARATION OF ESTER, AMIDE AND IMIDE DERIVATIVES ALSO USEFUL AS ADDITION AGENTS FOR LUBRICANTS, ESPECIALLY MINERAL OIL BASED LUBRICANTS.

公开(公告)号：US3756953A

公开(公告)日：1973-09-04

申请号：US3756953D

申请日：1972-01-07

Applicant: STANDARD OIL CO

Inventor： PIASEK E ,  KARLL R

IPC: C07C275/14 ,  C07F5/02 ,  C07F5/04 ,  C08F8/32 ,  C08F8/42 ,  C10M159/16 ,  C10M1/54

CPC classification number: C10M159/16 ,  C07C275/14 ,  C07F5/022 ,  C07F5/04 ,  C08F8/32 ,  C08F8/42 ,  C10M2215/04 ,  C10M2215/062 ,  C10M2215/065 ,  C10M2215/102 ,  C10M2215/22 ,  C10M2215/221 ,  C10M2215/224 ,  C10M2215/225 ,  C10M2215/226 ,  C10M2215/26 ,  C10M2215/30 ,  C10M2217/046 ,  C10M2217/06 ,  C10M2219/044 ,  C10M2219/046 ,  C10M2219/064 ,  C10M2219/066 ,  C10M2221/00 ,  C10M2223/045 ,  C10M2227/06 ,  C10M2227/061 ,  C10N2210/02 ,  C10N2210/03 ,  C10N2230/12 ,  C10N2250/121 ,  C10N2270/02 ,  C08F110/00

Abstract: OIL SOLUTIONS CONTAINING 0.1-70 WEIGHT PERCENT OF BORON-CONTAINING MANNICH REACTION CONDENSATION PRODUCTS OF (1) HIGH MOLECULAR WEIGHT ALKYL-SUBSTITUTED HYDROXYAROMATIC COMPOUNDS WHOSE ALKYL SUBSTITUENT HAS UPWARD FROM 40 TO 20,000 CARBON ATOMS, (2) AMINE WHICH CONTAINS AN HN

公开(公告)号：US3718663A

公开(公告)日：1973-02-27

申请号：US3718663D

申请日：1970-08-31

Applicant: STANDARD OIL CO

Inventor： LEE R ,  PIASEK E ,  KARLL R

IPC: C07C275/14 ,  C07F5/02 ,  C10M133/56 ,  C10M135/16 ,  C07D27/00

CPC classification number: C07C275/14 ,  C07F5/022 ,  C10M133/56 ,  C10M135/16 ,  C10M2215/04 ,  C10M2215/086 ,  C10M2215/10 ,  C10M2215/102 ,  C10M2215/26 ,  C10M2215/28 ,  C10M2217/046 ,  C10M2217/06 ,  C10M2219/044 ,  C10M2219/064 ,  C10M2223/045 ,  C10M2227/06 ,  C10M2227/061 ,  C10N2210/02 ,  C10N2210/03

Abstract: Complex substituted alkylene polyamines such as di(alkenylsuccinimide) of N1,N3 symmetrical bis(aminopolyazalkylene) ureas that react with boric acid in oil solution either with low boric acid utilization efficiency or react to form a hazy product whose haze cannot be removed by filtration are readily converted to the desired oil solution of boron and nitrogen containing products by first preparing an oil solution of super boron containing product of the complex substituted alkylene polyamine, combining the oil solution of super boron containing product with oil solution of the complex substituted alkylene polyamine and equilibrating the resulting mixture to a uniform boron to nitrogen content throughout.

Abstract translation: 复合取代的亚烷基多胺如N1，N3对称双（氨基多亚氮烷基）脲的二（烯基 - 琥珀酰亚胺）对称双（氨基多亚氮烷基）脲，其与硼酸在油溶液中反应，具有低硼酸利用效率或反应，形成其雾度不能通过 通过首先制备复合取代的亚烷基多胺的含超级含硼产物的油溶液，将含超硼含量产物的油溶液与络合物取代的亚烷基的油溶液结合，过滤容易地转化为所需的含硼和氮的产物油溶液 并将所得混合物平衡至一致的硼至氮含量。

公开(公告)号：US3803039A

公开(公告)日：1974-04-09

申请号：US23103072

申请日：1972-03-01

Applicant: STANDARD OIL CO

Inventor： PIASEK E ,  KARLL R

IPC: C08F8/32 ,  C10M169/00 ,  C10M1/32

CPC classification number: C10M1/08 ,  C08F8/32 ,  C10M2203/06 ,  C10M2205/00 ,  C10M2205/02 ,  C10M2205/026 ,  C10M2205/028 ,  C10M2207/282 ,  C10M2207/34 ,  C10M2209/084 ,  C10M2209/103 ,  C10M2215/04 ,  C10M2215/062 ,  C10M2215/08 ,  C10M2215/082 ,  C10M2215/12 ,  C10M2215/22 ,  C10M2215/221 ,  C10M2215/224 ,  C10M2215/225 ,  C10M2215/226 ,  C10M2215/26 ,  C10M2215/28 ,  C10M2215/30 ,  C10M2217/028 ,  C10M2217/042 ,  C10M2217/043 ,  C10M2217/046 ,  C10M2217/06 ,  C10M2219/044 ,  C10M2223/045 ,  C10M2229/02 ,  C10M2229/05 ,  C10N2210/02 ,  C10N2240/04 ,  C10N2240/042 ,  C10N2240/044 ,  C10N2240/046 ,  C08F110/00

Abstract: Protection against corrosion and deposition of sludge and varnish is provided by lubricating oils containing a minor amount of the ashless addition agents which are aliphatic acid derivatives of high molecular weight Mannich condensation products of (1) high molecular weight alkyl-substituted hydroxy aromatic compounds whose alkyl-substituent has a number average molecular weight (Mn) from about 600-100,000, (2) a compound containing at least one

GROUP, (3) AN ALDEHYDE IN THE RESPECTIVE MOLAR REACTANT RATIO OF 1:0.1-10:1.0-10, AND (4) 0.1-10.0 WEIGHT PERCENT OF AN ALIPHATIC ACID HAVING AT LEAST 6 CARBON ATOMS.

公开(公告)号：US3798165A

公开(公告)日：1974-03-19

申请号：US3798165D

申请日：1969-02-10

Applicant: STANDARD OIL CO

Inventor： PIASEK E ,  KARLL R

IPC: C07C275/14 ,  C07F5/02 ,  C07F5/04 ,  C08F8/32 ,  C08F8/42 ,  C10M159/16 ,  C10M1/20 ,  C10M1/32

CPC classification number: C10M159/16 ,  C07C275/14 ,  C07F5/022 ,  C07F5/04 ,  C08F8/32 ,  C08F8/42 ,  C10M2215/04 ,  C10M2215/062 ,  C10M2215/065 ,  C10M2215/102 ,  C10M2215/22 ,  C10M2215/221 ,  C10M2215/224 ,  C10M2215/225 ,  C10M2215/226 ,  C10M2215/26 ,  C10M2215/30 ,  C10M2217/046 ,  C10M2217/06 ,  C10M2219/044 ,  C10M2219/046 ,  C10M2219/064 ,  C10M2219/066 ,  C10M2221/00 ,  C10M2223/045 ,  C10M2227/06 ,  C10M2227/061 ,  C10N2210/02 ,  C10N2210/03 ,  C10N2230/12 ,  C10N2250/121 ,  C10N2270/02 ,  C08F110/00

Abstract: OIL SOLUBLE HIGH MOLECULAR WEIGHT MANNICH CONDENSATION PRODUCTS FORMED BY REACTING (1) HIGH MOLECULAR WEIGHT ALKYL-SUBSTITUTED HYDROXY AROMATIC COMPOUNDS WHOSE ALKYL-SUBSTITUENT HAS A NUMBER AVERAGE MOLECULAR WEIGHT (MN) FROM ABOUT 600-1000,000, (2) A COMPOUND CONTAINING AT LEAST HN

公开(公告)号：US3787458A

公开(公告)日：1974-01-22

申请号：US3787458D

申请日：1970-08-31

Applicant: STANDARD OIL CO

Inventor： PIASEK E ,  KARLL R

IPC: C08G14/04 ,  C08F8/00 ,  C08G14/12 ,  C10M159/16 ,  C10N30/10 ,  C10N60/00 ,  C09F7/00

CPC classification number: C10M159/16 ,  C08F8/00 ,  C08G14/12 ,  C10M2205/00 ,  C10M2207/282 ,  C10M2207/34 ,  C10M2209/103 ,  C10M2215/04 ,  C10M2215/062 ,  C10M2215/22 ,  C10M2215/221 ,  C10M2215/224 ,  C10M2215/225 ,  C10M2215/226 ,  C10M2215/26 ,  C10M2215/30 ,  C10M2217/042 ,  C10M2217/043 ,  C10M2217/046 ,  C10M2217/06 ,  C10M2219/046 ,  C10M2223/045 ,  C10N2210/02 ,  C10N2240/04 ,  C10N2240/042 ,  C10N2240/044 ,  C10N2240/046 ,  C08F10/00

Abstract: THE THERMAL OXIDATION STABILITY OF ALIPHATIC ACID-MODIFIED HIGH MOLECULAR WEIGHT MANNICH CONDENSATION PRODUCTS, WHICH ARE PREPARED BY REACTING (1) A HIGH MOLECULAR WEIGHT ALKYL-SUBSTITUTED HYDROXY AROMATIC COMPOUND, IN WHICH THE ALKYL-SUBSTITUENT HAS AN AVERAGE MOLECULAR WEIGHT OF FROM ABOUT 600 TO ABOUT 100,000, (2) AN AINE COMPOUND CONTAINING AT LEAST ONE HN

公开(公告)号：US3737465A

公开(公告)日：1973-06-05

申请号：US3737465D

申请日：1969-12-16

Applicant: STANDARD OIL CO

Inventor： KARLL R ,  PIASEK E

IPC: C07C37/20 ,  C07C39/12 ,  C08G63/193 ,  C08G63/547 ,  C08G69/44 ,  C08G73/02 ,  C10M129/91 ,  C10M149/14 ,  C07C39/16

CPC classification number: C08G69/44 ,  C07C37/20 ,  C07C39/12 ,  C08G63/193 ,  C08G63/547 ,  C08G73/02 ,  C10M129/91 ,  C10M149/14 ,  C10M2209/101 ,  C10M2209/102 ,  C10M2215/04 ,  C10M2215/26 ,  C10M2217/042 ,  C10M2217/043 ,  C10M2217/046 ,  C10M2217/06 ,  C10M2219/044 ,  C10M2223/045 ,  C10N2210/02

Abstract: NOVEL COMPOUNDS HAVING TWO TERMINAL HYDROXYMETHYL5-ALKYLBENZYL SUBSTITUENTS AND HAVING ALL ALKYL-SUBSTITENTS OF MOLECULAR WEIGHT UPWARD FROM ABOUT 400 ARE OBTAINED BY A STRONG ALKALI PROMOTED CONDENSATION OF 4-ALKYLPHENOL WITH FORMALDEHYDE. BECAUSE OF THE PRESENCE OF TWO HYDROXYMETHYL (METHYLOL) SUBSTITUTED ALKYLHYDROXYBENZYL GROUPS, THESE COMPOUNDS CAN BE CONSIDERED AS BIS-METHYLOLS SINCE THEY ARE MORE REACTIVE AS DIOLS THAN POLYPHENOLS. THESE COMPOUNDS THROUGH THEIR METHYLOL SUBSTITUENTS REACT WITH A COMPOUND HAVING AT LEAST ONE HN