公开(公告)号：US09988467B2

公开(公告)日：2018-06-05

申请号：US14780236

申请日：2014-03-27

Applicant: Saudi Basic Industries Corporation

Inventor： Vugar Aliyev ,  Ian Blackmore

IPC: C08F4/69 ,  C08F110/02 ,  C08J5/00

CPC classification number: C08F110/02 ,  C08F4/69 ,  C08J5/00 ,  C08J2323/06 ,  C08F4/24 ,  C08F2500/01 ,  C08F2500/07 ,  C08F2500/12 ,  C08F2500/18 ,  C08F4/22

Abstract: The invention relates to a polymerization process for the production of high density polyethylene by polymerization of ethylene in the presence of a catalyst composition comprising a chromium compound, a support material wherein the alcohol is a primary alcohol having the formula (I) wherein R, R′ and R″ are the same or different and respectively represent a linear or branched alkyl, cycloalkyl, phenyl or phenyl containing radicals comprising from 5 to 15 carbon atoms and wherein only one of R, R′ or R″ can be a hydrogen radical and/or wherein the alcohol is a secondary alcohol and/or a secondary cyclic alcohol. The catalyst composition may also comprise a titanium compound. The high density polyethylene may be applied in the production of blow molded articles.

公开(公告)号：US20160145360A1

公开(公告)日：2016-05-26

申请号：US14900622

申请日：2014-06-17

Applicant: SAUDI BASIC INDUSTRIES CORPORATION ,  SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Orass Hamed ,  Vugar Aliyev ,  Ian Blackmore ,  Nayef Al-Enazi

IPC: C08F110/02 ,  B65D1/02

CPC classification number: C08F110/02 ,  B65D1/0207 ,  C08F210/02 ,  C08F210/16 ,  C08F10/02 ,  C08F4/24 ,  C08F4/69 ,  C08F2500/12 ,  C08F2500/07 ,  C08F2500/13 ,  C08F210/14 ,  C08F2500/04 ,  C08F2500/18 ,  C08F2500/24 ,  C08F4/025 ,  C08F4/76 ,  C08F4/78

Abstract: The present invention is directed to a polymerization process for the production of polyethylene by polymerization of ethylene in the presence of a catalyst composition comprising a porous silicon oxide support material carrying a chromium compound and a transition metal containing compound or metal halide transition metal compound. The silicon oxide support material has an average particle size between 20 um and 40 um, a pore volume between 1.8 and 2.2 ml/g and a surface area between 400 and 600 m2/g.

Abstract translation: 本发明涉及聚乙烯的聚合方法，该聚合方法是在催化剂组合物存在下，通过聚合乙烯来制备聚乙烯，所述催化剂组合物包含载有铬化合物的多孔氧化硅载体材料和含过渡金属的化合物或金属卤化物过渡金属化合物。 氧化硅载体材料的平均粒度为20μm至40μm，孔体积为1.8-2.2ml / g，表面积为400至600m2 / g。