公开(公告)号：US4263218A

公开(公告)日：1981-04-21

申请号：US81919

申请日：1979-10-04

Applicant: Steve J. Dougherty

Inventor： Steve J. Dougherty

IPC: B01J31/20 ,  C07C29/158 ,  C07C29/86 ,  C07C27/06 ,  C07C27/26 ,  C07C27/34

CPC classification number: B01J31/28 ,  B01J31/0202 ,  B01J31/0237 ,  B01J31/0239 ,  B01J31/0255 ,  B01J31/0271 ,  B01J31/04 ,  B01J31/20 ,  B01J31/4046 ,  C07C29/158 ,  C07C29/86 ,  B01J2231/648 ,  B01J2531/0211 ,  B01J2531/822 ,  B01J31/2234 ,  Y02P20/52 ,  Y02P20/584

Abstract: There is described an improvement in the process of recovering alcohol products formed by the homogeneous liquid phase reaction between oxides of carbon and hydrogen in the presence of a rhodium carbonyl complex catalyst which process involves mixing water and an essentially water-immiscible solvent with the solution containing products of such reaction to cause the alcohol products to enter the water phase and the rhodium to enter into the water-immiscible solvent phase wherein the improvement comprises mixing the water, solvent and solution containing products in contact with CO gas.

Abstract translation: 描述了在羰基铑羰基络合物催化剂存在下回收由碳和氢的氧化物之间的均相液相反应形成的醇产物的方法的改进，该方法包括将水和基本上与水不溶混的溶剂与含有 这种反应的产物使醇产物进入水相和铑进入与水不混溶的溶剂相，其中改进包括混合含有与CO气体接触的产物的水，溶剂和溶液。