公开(公告)号：US3756941A

公开(公告)日：1973-09-04

申请号：US3756941D

申请日：1971-06-21

Applicant: TEXACO INC

Inventor： CARTER N ,  ESTES J ,  KRAVITZ S

IPC: C07C5/387 ,  C10G35/06 ,  C10G35/08

CPC classification number: C07C5/387

Abstract: ALKYLCYCLOPENTANES AND GASOLINE OR NAPTHA FRACTIONS CONTAINING THE SAME ARE DEHYDROISOMERIZED TO AROMATIC COMPOUNDS BY CONTACTING WITH A FLUORIDED GROUP VII-B OR VIII METAL-ALUMINA CATALYST AND A CARBON OXIDE AS A CONVERSION REACTION MODERATOR. BY EMPLOYING A FLUORIDED METAL-ALUMINA CATALYST AND A CARBON OXIDE MODERATOR, SUCH AS CARBON MONOXIDE OR CARBON DIOXIDE, ALKYLCYCLOPENTANES ARE SELECTIVELY CONVERTED TO AROMATICS AND GASOLINE OR NAPTHA FRACTIONS CONTAINING THE SAME ARE UPGRADED.

公开(公告)号：US3711425A

公开(公告)日：1973-01-16

申请号：US3711425D

申请日：1970-06-25

Applicant: TEXACO INC

Inventor： SUGGITT R ,  ESTES J ,  KRAVITZ S

IPC: B01J21/02 ,  B01J21/04 ,  B01J23/40 ,  B01J23/42 ,  B01J27/00 ,  B01J37/10 ,  C07C5/27 ,  C10G35/085 ,  C10G49/02 ,  B01J11/74 ,  B01J11/78

CPC classification number: C10G49/02 ,  B01J21/02 ,  B01J21/04 ,  B01J23/40 ,  B01J23/42 ,  B01J27/00 ,  B01J37/10 ,  C07C5/2791 ,  C07C2521/04 ,  C07C2523/26 ,  C07C2523/28 ,  C07C2523/30 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/46 ,  C07C2523/75 ,  C07C2523/755 ,  C10G35/085 ,  C07C9/16

Abstract: A METHOD FOR PREPARING A HYDROCARBON CONVERSION CATALYST BY PROVIDING A COMPOSITE COMPOSED OF ALUMINA HAVING ASSOCIATED THEREWITH A GROUP VI-B OR VIII METAL OR COMPOUND AND CONTACTING THE COMPOSITE WITH AN ACTIVATOR SYSTEM COMPRISING OXYGEN AND AN ORGANIC FLUORIDE COMPOUND HAVING FROM 2 TO 16 CARBON ATOMS. THE CATALYST SO PREPARED IS USEFUL IN HYDROCARBON CONVERSION PROCESSES AS ISOMERIZATION, HYDROCRACKING, REFORMING, DEHYDROGENATION, DISPROPORTIONATION AND POLYMERIZATION.

公开(公告)号：US3843748A

公开(公告)日：1974-10-22

申请号：US22376472

申请日：1972-02-04

Applicant: TEXACO INC

Inventor： SUGGITT R ,  ESTER J ,  KRAVITZ S

IPC: B01J21/02 ,  B01J21/04 ,  B01J23/40 ,  B01J23/42 ,  B01J23/90 ,  B01J27/00 ,  B01J37/10 ,  B01J37/26 ,  C07C5/22 ,  C07C5/27 ,  C10G35/06 ,  C10G35/085 ,  C10G45/60 ,  C10G45/62 ,  C10G49/04 ,  C07C5/30

CPC classification number: C10G49/04 ,  B01J21/02 ,  B01J21/04 ,  B01J23/40 ,  B01J23/42 ,  B01J23/90 ,  B01J27/00 ,  B01J37/10 ,  B01J37/26 ,  C07C5/226 ,  C07C5/2724 ,  C07C2521/04 ,  C07C2523/26 ,  C07C2523/28 ,  C07C2523/30 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/46 ,  C07C2523/75 ,  C07C2523/755 ,  C10G35/06 ,  C10G35/085 ,  C10G45/60 ,  C10G45/62 ,  Y02P20/584

Abstract: A method for preparing a hydrocarbon conversion catalyst by providing a composite composed of alumina having associated therewith a Group VIB or VIII metal or compound and contacting the composite with an activator system comprising oxygen and an organic fluoride compound having from 2 to 16 carbon atoms. The catalyst so prepared is useful in hydrocarbon conversion processes as isomerization, hydrocracking, reforming, dehydrogenation, disproportionation and polymerization.

公开(公告)号：US3711566A

公开(公告)日：1973-01-16

申请号：US3711566D

申请日：1970-11-25

Applicant: TEXACO INC

Inventor： KRAVITZ S ,  ESTES J ,  HERBSTMAN S

IPC: C10G45/52 ,  C10G49/00 ,  C07C5/10

CPC classification number: C10G45/52 ,  C10G49/007 ,  Y10S585/952

Abstract: A process for the low pressure hydrogenation of aromatic hydrocarbons in the presence of sulfur employing a fluorided platinum-alumina catalyst and carbon monoxide as a conversion reaction moderator. By employing a fluorided platinum-alumina catalyst and the moderator carbon monoxide, aromatic hydrocarbon saturation is accomplished while simultaneously inhibiting concurrent hydrocracking reactions.

Abstract translation: 在使用氟化的铂 - 氧化铝催化剂和一氧化碳作为转化反应调节剂的硫的存在下，芳族烃的低压氢化的方法。 通过使用氟化铂 - 氧化铝催化剂和调节剂一氧化碳，完成芳烃饱和，同时抑制同时加氢裂化反应。

公开(公告)号：US3793396A

公开(公告)日：1974-02-19

申请号：US3793396D

申请日：1972-01-21

Applicant: TEXACO INC

Inventor： SUGGITT R ,  ESTES J ,  KRAVITZ S

IPC: B01J23/40 ,  C07C5/22 ,  C10G35/06 ,  C10G45/60 ,  C10G45/62 ,  C07C5/30

CPC classification number: C10G45/62 ,  B01J23/40 ,  C07C5/226 ,  C07C2521/04 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/46 ,  C10G35/06 ,  C10G45/60 ,  C10G2400/02

Abstract: A METHOD FOR PREPARING A HYDROCARBON CONVERSION CATALYST COMPOSED OF ALUMINA AND CHLORINE OR BROMINE BY CONTACTING ALUMINA WITH AN ACTIVATOR SYSTEM COMPRISING CHLORINE OR BROMINE AND AN INORGANIC SULFUR COMPOUND SELECTED FROM THE GROUP HYDROGEN SULFIDE AND COMPOUNDS CORRESPONDING TO THE FORMULA SMX2. THE CATALYST MAY ADDITIONALLY INCLUDE A METAL SUCH AS PLATINUM, PALLADIUM, RUTHENIUM OR RHODIUM. THE CATALYSTS SO PREPARED ARE USEFUL IN SUCH HYDROCARBON CONVERSION PROCESSES AS ISOMERIZATION, CRACKING, HYDROCRACKING, REFORMING, ALKYLATION, DEHYDROGENATION, DISPROPORTIONATION AND POLYMERIZATION.

公开(公告)号：US3709817A

公开(公告)日：1973-01-09

申请号：US3709817D

申请日：1971-05-18

Applicant: TEXACO INC

Inventor： SUGGITT R ,  ESTES J ,  KRAVITZ S

IPC: B01J23/36 ,  B01J23/40 ,  B01J37/26 ,  C07C5/27 ,  C10G45/58 ,  C10G35/08

CPC classification number: B01J37/26 ,  B01J23/36 ,  B01J23/40 ,  C07C5/2791 ,  C10G2400/02 ,  Y02P20/52 ,  C07C9/16

Abstract: PARAFFIN HYDROCARBONS ARE SELECTIVELY HYDROCRACKED AND ISOMERIZED UNDER CONTROLLED CONVERSION CONDITIONS BY CONTACTING THE HYDROCARBON WITH HYDROGEN, A FLUORIDED GROUP VII-B OR VIII METAL-ALUMINA CATALYST AND WATER OR WATER PRECURSORS AS A CONVERSION REACTION MODERATOR. BY EMPLOYING A FLUORIDED METAL-ALUMINA CATALYST AND WATER OR WATER PRECURSOR MODERATOR, PARAFFIN HYDROCARBONS ARE SELECTIVELY HYDROCRACKED AND ISOMERIZED IN A MANNER SUCH THAT THE SELECTIVELY, ACTIVITY AND PRODUCT DISTRIBUTION IS CONTROLLED OVER THE COURSE OF THE CONVERION REACTION.

公开(公告)号：US3850846A

公开(公告)日：1974-11-26

申请号：US35280273

申请日：1973-04-19

Applicant: TEXACO INC

Inventor： COLE E ,  KRAVITZ S ,  COONE J

IPC: B01J23/42 ,  B01J37/20 ,  B01J11/74

CPC classification number: B01J37/20 ,  B01J23/42

Abstract: 1. A PROCESS FOR THE IN SITU SULFIDING OF A CATALYST WHICH COMPRISES CHARGING A MIXTURE OF A PARTICULATE CATALYST COMPRISING A GROUP VIII METAL OXIDE ON A SUPPORT COMPRISING A REFRACTORY INORGANIC OXIDE AND ENCAPSULATED HYDROLYZABLE SOLID SULFUR-CONTAINING COMPOUND TO A REACTION ZONE TO FORM A CATALYST BED THEREIN, HEATING THE MIXTURE TO REMOVE THE ENCAPSULATING MATERIAL FROM SAID COMPOUND, HYDROLYZING SAID COMPOUND TO PRODUCE H2S WITHIN SAID CATALYST BED THEREBY EFFECTING IN SITU SULFIDING OF SAID CATALYST.

公开(公告)号：US3843746A

公开(公告)日：1974-10-22

申请号：US22102572

申请日：1972-01-26

Applicant: TEXACO INC

Inventor： KRAVITZ S ,  ESTES J ,  SUGGITT R

IPC: B01J23/40 ,  B01J23/64 ,  B01J23/96 ,  B01J37/26 ,  C07C5/22 ,  C07C5/27 ,  C07C5/30

CPC classification number: C07C5/226 ,  B01J23/40 ,  B01J23/64 ,  B01J23/96 ,  B01J37/26 ,  C07C5/2724 ,  C07C2521/04 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/46 ,  Y02P20/584 ,  C07C9/00

Abstract: A method for preparing a hydrocarbon conversion catalyst by providing a composite composed of alumina having associated therewith a Group VIB, VIIB or VIII metal or compound and contacting the composite with an activator system comprising hydrogen and sulfuryl fluoride or thionyl fluoride. The catalysts so prepared are useful in such hydrocarbon conversion processes as isomerization, hydrocracking, reforming, alkylation, disproportionation, polymerization and hydrogenation.

公开(公告)号：US3852372A

公开(公告)日：1974-12-03

申请号：US22303072

申请日：1972-02-02

Applicant: TEXACO INC

Inventor： SUGGITT R ,  ESTES J ,  KRAVITZ S

IPC: B01J21/02 ,  B01J21/04 ,  B01J23/40 ,  B01J23/42 ,  B01J23/85 ,  B01J27/00 ,  B01J37/10 ,  B01J37/26 ,  C07C5/22 ,  C10G45/62 ,  B01J11/16 ,  C01B33/28 ,  C07C5/24

CPC classification number: B01J21/04 ,  B01J21/02 ,  B01J23/40 ,  B01J23/42 ,  B01J23/85 ,  B01J27/00 ,  B01J37/10 ,  B01J37/26 ,  C07C5/226 ,  C07C2521/04 ,  C07C2521/12 ,  C07C2523/26 ,  C07C2523/28 ,  C07C2523/30 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/46 ,  C07C2523/75 ,  C07C2523/755 ,  C10G45/62

Abstract: A method for preparing a hydrocarbon conversion catalyst by providing a composite composed of alumina having associated therewith a Group VIB or VIII metal or compound and contacting the composite with an activator system comprising hydrogen and an organic fluoride compound having from 2 to 16 carbon atoms. The catalysts so prepared are useful in such hydrocarbon conversion processes as isomerization, hydrocracking, reforming, alkylation, disproportionation, polymerization and hydrogenation.

Abstract translation: 通过提供由具有VIB或VIII族金属或化合物的氧化铝组成的复合材料制备烃转化催化剂的方法，并使该复合物与包含氢和具有2至16个碳原子的有机氟化物的活化剂体系接触。 如此制备的催化剂可用于如异构化，加氢裂化，重整，烷基化，歧化，聚合和氢化等烃转化过程。

公开(公告)号：US3843747A

公开(公告)日：1974-10-22

申请号：US22303172

申请日：1972-02-02

Applicant: TEXACO INC

Inventor： KRAVITZ S ,  ESTES J ,  SUGGITT R

IPC: B01J21/04 ,  B01J23/42 ,  B01J23/64 ,  B01J23/656 ,  B01J23/96 ,  B01J37/20 ,  B01J37/26 ,  C07C5/22 ,  C07C5/30

CPC classification number: B01J21/04 ,  B01J23/42 ,  B01J23/64 ,  B01J23/6567 ,  B01J23/96 ,  B01J37/20 ,  B01J37/26 ,  C07C5/2213 ,  C07C5/2226 ,  C07C5/2233 ,  C07C5/226 ,  C07C2521/04 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/46 ,  C07C2527/04 ,  Y02P20/584

Abstract: A method for preparing a hydrocarbon conversion catalyst by providing a composite composed of alumina having associated therewith a Group VIB, VIIB or VIII metal or compound and contacting the composite with an activator system comprising carbon monoxide and sulfuryl fluoride or thionyl fluoride. The catalysts so prepared are useful in such hydrocarbon conversion processes as isomerization, hydrocracking, reforming, alkylation, disproportionation, polymerization and hydrogenation.