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公开(公告)号：US09850380B2
公开(公告)日：2017-12-26
申请号：US15302635
申请日：2015-10-26
Applicant: Toray Industries, Inc.
Inventor： Daisuke Sato , Shinichiro Ochiai , Sadayuki Kobayashi
CPC classification number: C08L77/02 , B32B27/34 , B32B2439/00 , C08J5/00 , C08J2377/02 , C08J2477/06 , C08L23/26 , C08L77/06 , C08L2205/025 , F17C1/16 , F17C13/04 , F17C2203/0604 , F17C2203/066 , F17C2203/0675 , F17C2205/0323 , F17C2221/012 , F17C2270/0184 , C08L23/0815
Abstract: A polyamide resin composition for a molded article exposed to high-pressure hydrogen contains a polyamide 6 resin (A) and a polyamide resin (B) having a melting point, as determined by DSC, that is not higher than a melting point of the polyamide 6 resin (A) +20° C. and a cooling crystallization temperature, as determined by DSC, that is higher than a cooling crystallization temperature of the polyamide 6 resin (A), the polyamide resin (B) present in an amount of 0.01 to 5 parts by weight based on 100 parts by weight of the polyamide 6 resin (A). The polyamide resin composition can provide a molded article having excellent weld properties and is less likely to suffer failure points despite repeated charging and discharging of high-pressure hydrogen.
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公开(公告)号：US20200172726A1
公开(公告)日：2020-06-04
申请号：US16781768
申请日：2020-02-04
Applicant: Toray Industries, Inc.
Inventor： Yusuke Tojo , Kentaro Togawa , Daisuke Sato , Sadanori Kumazawa
Abstract: A thermoplastic polyester resin composition has an excellent retention stability and is capable of producing a molded article excellent in mechanical properties and heat resistance as well as in long-term hydrolysis resistance; and the molded article. The thermoplastic polyester resin includes 100 parts by weight of a thermoplastic polyester resin (A) and 0.1 to 10 parts by weight of a biphenyl aralkyl-type epoxy resin or cyclopentadiene-type epoxy resin (B) of a specific type.
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公开(公告)号：US20220153991A1
公开(公告)日：2022-05-19
申请号：US17598235
申请日：2020-03-23
Applicant: Toray Industries, Inc.
Inventor： Takashi Ueda , Masanori Kobayashi , Daisuke Sato
IPC: C08L69/00
Abstract: A thermoplastic resin composition includes: a polycarbonate resin (I); a specific graft copolymer (II); a vinyl copolymer (III); an inorganic filler (IV); and a phosphate ester compound (V). The vinyl-based copolymer (III) has a weight average molecular weight of 110,000 or less. A ratio of a melt flow rate of the vinyl-based copolymer (III) to a melt flow rate of the polycarbonate resin (I) is 7 or more and 12 or less. A blending amount of the phosphoric acid ester-based compound (V) is 1 to 10 parts by weight with respect to 100 parts by weight of a total amount of (I) to (IV).
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公开(公告)号：US11319436B2
公开(公告)日：2022-05-03
申请号：US15035303
申请日：2014-09-04
Applicant: Toray Industries, Inc.
Inventor： Yusuke Tojo , Kentaro Togawa , Daisuke Sato , Sadanori Kumazawa
Abstract: A thermoplastic polyester resin composition has an excellent retention stability and is capable of producing a molded article excellent in mechanical properties and heat resistance as well as in long-term hydrolysis resistance; and the molded article. The thermoplastic polyester resin includes 100 parts by weight of a thermoplastic polyester resin (A) and 0.1 to 10 parts by weight of a biphenyl aralkyl-type epoxy resin or cyclopentadiene-type epoxy resin (B) of a specific type.
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5.发明申请公开(公告)号：US20170029620A1
公开(公告)日：2017-02-02
申请号：US15302635
申请日：2015-10-26
Applicant: Toray Industries, Inc.
Inventor： Daisuke Sato , Shinichiro Ochiai , Sadayuki Kobayashi
CPC classification number: C08L77/02 , B32B27/34 , B32B2439/00 , C08J5/00 , C08J2377/02 , C08J2477/06 , C08L23/26 , C08L77/06 , C08L2205/025 , F17C1/16 , F17C13/04 , F17C2203/0604 , F17C2203/066 , F17C2203/0675 , F17C2205/0323 , F17C2221/012 , F17C2270/0184 , C08L23/0815
Abstract: A polyamide resin composition for a molded article exposed to high-pressure hydrogen contains a polyamide 6 resin (A) and a polyamide resin (B) having a melting point, as determined by DSC, that is not higher than a melting point of the polyamide 6 resin (A) +20° C. and a cooling crystallization temperature, as determined by DSC, that is higher than a cooling crystallization temperature of the polyamide 6 resin (A), the polyamide resin (B) present in an amount of 0.01 to 5 parts by weight based on 100 parts by weight of the polyamide 6 resin (A). The polyamide resin composition can provide a molded article having excellent weld properties and is less likely to suffer failure points despite repeated charging and discharging of high-pressure hydrogen.
Abstract translation: 用于暴露于高压氢的模塑制品的聚酰胺树脂组合物含有聚酰胺6树脂（A）和聚酰胺树脂（B），其通过DSC测定的熔点不高于聚酰胺的熔点 6树脂（A）+ 20℃，通过DSC测定的冷却结晶温度高于聚酰胺6树脂（A）的冷却结晶温度，聚酰胺树脂（B）的存在量为0.01 至5重量份，基于100重量份的聚酰胺6树脂（A）。 聚酰胺树脂组合物可以提供具有优异的焊接性能的模制品，并且尽管反复充放电高压氢，也不太可能遭受故障点。
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Patent Agency Ranking
6.发明授权公开(公告)号：US09505926B2
公开(公告)日：2016-11-29
申请号：US14417906
申请日：2013-07-17
Applicant: TORAY INDUSTRIES, INC.
Inventor： Kentaro Togawa , Daisuke Sato , Sadanori Kumazawa
IPC: C09J133/10 , C08L67/02
CPC classification number: C08L67/02 , C08K5/0066 , C08K5/34924 , C08K5/521 , C08K5/5313 , C08K5/5399 , C08K7/14 , C08L33/10 , C08L2201/02 , C09J133/10
Abstract: The present invention includes a flame-retardant thermoplastic polyester resin composition which provides a molded article having excellent tracking resistance and excellent mechanical characteristics, while maintaining high flame retardancy; and a molded article which is obtained by molding the flame-retardant thermoplastic polyester resin composition. A flame-retardant thermoplastic polyester resin composition of an embodiment of the present invention contains 1-70 parts by weight of two or more (C) phosphorus-containing flame retardants that are selected from the group consisting of (C-1) condensed phosphoric acid esters, (C-2) phosphazene compounds and (C-3) organic metal phosphinates and 1-90 parts by weight of (D) a nitrogen-containing flame retardant per 100 parts by weight of the total of 50-95 parts by weight of (A) a thermoplastic polyester resin and 5-50 parts by weight of (B) a methacrylic resin.
Abstract translation: 本发明包括阻燃热塑性聚酯树脂组合物，其提供具有优异的耐追踪性和优异的机械特性的模塑制品，同时保持高阻燃性; 以及通过模塑阻燃性热塑性聚酯树脂组合物而获得的成型体。 本发明实施方案的阻燃热塑性聚酯树脂组合物含有1-70重量份选自（C-1）缩合磷酸的（C）含磷阻燃剂 酯类，（C-2）磷腈化合物和（C-3）有机金属次膦酸酯和1-90重量份的（D）含氮阻燃剂，每100重量份总共50-95重量份 （A）热塑性聚酯树脂和5-50重量份（B）甲基丙烯酸树脂。
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公开(公告)号：US11485854B2
公开(公告)日：2022-11-01
申请号：US17598235
申请日：2020-03-23
Applicant: Toray Industries, Inc.
Inventor： Takashi Ueda , Masanori Kobayashi , Daisuke Sato
Abstract: A thermoplastic resin composition includes: a polycarbonate resin (I); a specific graft copolymer (II); a vinyl copolymer (III); an inorganic filler (IV); and a phosphate ester compound (V). The vinyl-based copolymer (III) has a weight average molecular weight of 110,000 or less. A ratio of a melt flow rate of the vinyl-based copolymer (III) to a melt flow rate of the polycarbonate resin (I) is 7 or more and 12 or less. A blending amount of the phosphoric acid ester-based compound (V) is 1 to 10 parts by weight with respect to 100 parts by weight of a total amount of (I) to (IV).
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8.发明申请公开(公告)号：US20150225564A1
公开(公告)日：2015-08-13
申请号：US14417906
申请日：2013-07-17
Applicant: TORAY INDUSTRIES, INC.
Inventor： Kentaro Togawa , Daisuke Sato , Sadanori Kumazawa
IPC: C08L67/02
CPC classification number: C08L67/02 , C08K5/0066 , C08K5/34924 , C08K5/521 , C08K5/5313 , C08K5/5399 , C08K7/14 , C08L33/10 , C08L2201/02 , C09J133/10
Abstract: The present invention includes a flame-retardant thermoplastic polyester resin composition which provides a molded article having excellent tracking resistance and excellent mechanical characteristics, while maintaining high flame retardancy; and a molded article which is obtained by molding the flame-retardant thermoplastic polyester resin composition. A flame-retardant thermoplastic polyester resin composition of an embodiment of the present invention contains 1-70 parts by weight of two or more (C) phosphorus-containing flame retardants that are selected from the group consisting of (C-1) condensed phosphoric acid esters, (C-2) phosphazene compounds and (C-3) organic metal phosphinates and 1-90 parts by weight of (D) a nitrogen-containing flame retardant per 100 parts by weight of the total of 50-95 parts by weight of (A) a thermoplastic polyester resin and 5-50 parts by weight of (B) a methacrylic resin.
Abstract translation: 本发明包括阻燃热塑性聚酯树脂组合物，其提供具有优异的耐追踪性和优异的机械特性的模塑制品，同时保持高阻燃性; 以及通过模塑阻燃性热塑性聚酯树脂组合物而获得的成型体。 本发明实施方案的阻燃热塑性聚酯树脂组合物含有1-70重量份选自（C-1）缩合磷酸的（C）含磷阻燃剂 酯类，（C-2）磷腈化合物和（C-3）有机金属次膦酸酯和1-90重量份的（D）含氮阻燃剂，每100重量份总共50-95重量份 （A）热塑性聚酯树脂和5-50重量份（B）甲基丙烯酸树脂。
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公开(公告)号：US10882992B2
公开(公告)日：2021-01-05
申请号：US16339849
申请日：2017-10-17
Applicant: Toray Industries, Inc.
Inventor： Takashi Ueda , Masanori Kobayashi , Daisuke Sato , Taro Yamashita
Abstract: A thermoplastic resin composition exhibiting good balance of mechanical properties, heat resistance, flowability, and size stability as well as excellent stability in retention in the molding, appearance of the molded article, and coating properties, and also, a molded article thereof are provided. The thermoplastic resin composition is a blend of a polycarbonate resin (I), a graft copolymer (II) which comprises a graft copolymer (II-1) prepared by graft polymerization of a monomer mixture containing an aromatic vinyl monomer and a vinyl cyanide monomer in the presence of a diene rubbery polymer or a graft copolymer (II-2) prepared by graft polymerization of a monomer mixture containing an aromatic vinyl monomer and a vinyl cyanide monomer in the presence of an acryl rubbery polymer, a vinyl copolymer (III) prepared by copolymerizing an aromatic vinyl monomer and a vinyl cyanide monomer, a crystalline resin (IV), and a plate-shaped inorganic filler (V), and when total amount of (I)+(II)+(III)+(IV)+(V) is 100% by weight, (I) is 50 to 70% by weight, (II) is 3 to 15% by weight, (III) is 10 to 25% by weight, (IV) is 1 to 9% by weight, and (V) is 10 to 20% by weight, and content ratio of (IV) to 100% by weight of (V) is at least 10% by weight and less than 50% by weight.
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公开(公告)号：US20200048457A1
公开(公告)日：2020-02-13
申请号：US16339849
申请日：2017-10-17
Applicant: Toray Industries, Inc.
Inventor： Takashi Ueda , Masanori Kobayashi , Daisuke Sato , Taro Yamashita
Abstract: A thermoplastic resin composition exhibiting good balance of mechanical properties, heat resistance, flowability, and size stability as well as excellent stability in retention in the molding, appearance of the molded article, and coating properties, and also, a molded article thereof are provided. The thermoplastic resin composition is a blend of a polycarbonate resin (I), a graft copolymer (II) which comprises a graft copolymer (II-1) prepared by graft polymerization of a monomer mixture containing an aromatic vinyl monomer and a vinyl cyanide monomer in the presence of a diene rubbery polymer or a graft copolymer (II-2) prepared by graft polymerization of a monomer mixture containing an aromatic vinyl monomer and a vinyl cyanide monomer in the presence of an acryl rubbery polymer, a vinyl copolymer (III) prepared by copolymerizing an aromatic vinyl monomer and a vinyl cyanide monomer, a crystalline resin (IV), and a plate-shaped inorganic filler (V), and when total amount of (I)+(II)+(III)+(IV)+(V) is 100% by weight, (I) is 50 to 70% by weight, (II) is 3 to 15% by weight, (III) is 10 to 25% by weight, (IV) is 1 to 9% by weight, and (V) is 10 to 20% by weight, and content ratio of (IV) to 100% by weight of (V) is at least 10% by weight and less than 50% by weight.
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