公开(公告)号：US20250122412A1

公开(公告)日：2025-04-17

申请号：US18685313

申请日：2022-09-08

Applicant: TOYOBO MC Corporation

Inventor： Hiroyuki MIEDA ,  Koichi SAKAMOTO ,  Tadahiko MIKAMI

IPC: C09J167/02 ,  C08G63/183 ,  C08G63/189 ,  C08G63/199 ,  C08G63/52

Abstract: An adhesive resin composition according to the present invention is characterized by containing a polyester resin (A) and satisfying: (i) the polyester resin (A) has an acid value of 100 eq/ton or more; (ii) the adhesive resin composition contains substantially no curing agent; and (iii) the polyester resin (A) contains, as polyol components constituting the polyester resin (A), a diol (a) having two primary hydroxy groups and having no alicyclic structure, and either one or both of a diol (b) having an alicyclic structure and a diol (c) having one primary hydroxy group and one secondary hydroxy group and having no alicyclic structure. The adhesive resin composition according to the present invention has good pot life property, and has excellent solder heat resistance and adhesiveness to various base materials, even with use of substantially no curing agent. The present invention also provides a laminate or an adhesive sheet comprising an adhesive layer made from the adhesive resin composition, a printed-wiring board or a packing material comprising the laminate as a constituent element, and a laminated film for decorating three-dimensional molded article or a film for laminating metal can comprising the adhesive sheet as a constituent element.

公开(公告)号：US20240084127A1

公开(公告)日：2024-03-14

申请号：US18275500

申请日：2022-02-03

Applicant: TOYOBO MC Corporation

Inventor： Hiroyuki MIEDA ,  Katsuya SHIMENO ,  Tadahiko MIKAMI

IPC: C08L67/02 ,  C09D167/02

CPC classification number: C08L67/02 ,  C09D167/02 ,  C08L2201/50

Abstract: It is provided that a polyester resin and a polyester resin composition that allow induction of harmful outgas and can form a coating film having excellent characteristics such as curability, retort resistance, and processability. A polyester resin composition comprising polyester resin (A), wherein the polyester resin composition satisfies the following requirements (i) to (iii), (i) the polyester resin (A) has an acid value of 100 eq/ton or more, (ii) the polyester resin (A) includes, as a polyol component constituting the polyester resin (A), a diol (a) having two primary hydroxy groups and having no alicyclic structure, and, furthermore, one or both of a diol (b) having an alicyclic structure, and a diol (c) having one primary hydroxy group and one secondary hydroxy group and having no alicyclic structure, and (iii) the polyester resin (A) has unsaturated dicarboxylic acid (d) as a polycarboxylic acid component constituting the polyester resin (A).

公开(公告)号：US20250059321A1

公开(公告)日：2025-02-20

申请号：US18721436

申请日：2022-12-21

Applicant: TOYOBO MC CORPORATION

Inventor： Hiroyuki MIEDA ,  Kanta SUGIMOTO ,  Tadahiko MIKAMI

IPC: C08G63/688 ,  C08J3/07 ,  C08K5/10 ,  C09D5/02 ,  C09D7/63 ,  C09D167/06 ,  C09J9/00 ,  C09J167/06

Abstract: An object of the present invention is to provide an aqueous dispersion composition containing polyester resin having high storage stability, film-forming properties, tackiness, adhesiveness, and water resistance. An aqueous dispersion composition containing polyester resin, comprises, a polyester resin (A), a coalescing aid (B), and an aqueous medium (C), wherein the coalescing aid (B) has a Hansen solubility parameter with a dispersion term (δd) of 15.4 MPa0.5 or more and less than 18.0 MPa0.5, a polarization term (δp) of 4.1 MPa0.5 or more and less than 9.1 MPa0.5, and a hydrogen bond term (δh) of 7.0 MPa0.5 or more and less than 12.3 MPa0.5.

公开(公告)号：US20250066651A1

公开(公告)日：2025-02-27

申请号：US18687156

申请日：2022-09-08

Applicant: TOYOBO MC Corporation

Inventor： Hiroyuki MIEDA ,  Koichi SAKAMOTO ,  Tadahiko MIKAMI

IPC: C09J167/02 ,  C09J7/30 ,  H05K1/03

Abstract: The adhesive resin composition according to the present invention is characterized by containing a polyester resin (A) and satisfying: (i) the polyester resin (A) has an acid value of 100 eq/ton or more; (ii) the polyester resin (A) contains, as polyol components constituting the polyester resin (A), a diol (a) having two primary hydroxy groups and having no alicyclic structure, and either one or both of a diol (b) having an alicyclic structure and a diol (c) having one primary hydroxy group and one secondary hydroxy group and having no alicyclic structure; and (iii) the polyester resin (A) contains, as polycarboxylic acid components constituting the polyester resin (A), an unsaturated dicarboxylic acid (d). The adhesive resin composition according to the present invention enables curing even if the adhesive resin composition contains substantially no curing agent and therefore has excellent properties such as high solder heat resistance and adhesiveness to various base materials. The present invention also provides a laminate or an adhesive sheet comprising an adhesive layer made from the adhesive resin composition, a printed-wiring board or a packing material comprising the laminate as a constituent element, and a laminated film for decorating three-dimensional molded article or a film for laminating metal can comprising the adhesive sheet as a constituent element.

公开(公告)号：US20240279390A1

公开(公告)日：2024-08-22

申请号：US18571853

申请日：2022-07-26

Applicant: TOYOBO MC Corporation

Inventor： Hiroyuki MIEDA ,  Tadahiko MIKAMI

IPC: C08G63/183 ,  C09D5/02 ,  C09D167/02

CPC classification number: C08G63/183 ,  C09D5/02 ,  C09D167/02 ,  C08G2150/00

Abstract: The present invention relates to a polyester resin composition containing a polyester resin (A) which satisfies requirements (i) The polyester resin (A) has an acid value of 100 eq/ton or more; (ii) The polyester resin composition contains substantially no curing agent; and (iii) The polyester resin composition has a storage elastic modulus E′ at 200°° C. of 1.0×104 Pa or more after subjected to a heating treatment at 240° C. for 1 hour. The polyester resin composition of the present invention is capable of suppressing a harmful outgas and is suitable for a paint for cans having excellent properties such as curing properties, retort resistance, and processability.

公开(公告)号：US20240166863A1

公开(公告)日：2024-05-23

申请号：US18282842

申请日：2022-03-22

Applicant: TOYOBO MC Corporation

Inventor： Hiroyuki MIEDA ,  Tadahiko MIKAMI ,  Katsuya SHIMENO

IPC: C08L67/02 ,  C08L67/06 ,  C09D167/02 ,  C09D167/06

CPC classification number: C08L67/02 ,  C08L67/06 ,  C09D167/02 ,  C09D167/06 ,  C08L2205/025

Abstract: It is provided that a polyester resin and a polyester resin composition that allow reduction of harmful outgas and can form a coating film having excellent characteristics such as curability, retort resistance, and processability. A polyester resin composition comprising: a polyester resin (A) having an acid value of 100 eq/ton or more and smaller than 500 eq/ton; and a polyester resin (B) having an acid value of 500 eq/ton or more, wherein a content of the polyester resin (A) is 55 parts by mass or more and 95 parts by mass or smaller, and a content of the polyester resin (B) is 5 parts by mass or more and 45 parts by mass or smaller when a total mass of solid contents of the polyester resin (A) and the polyester resin (B) is 100 parts by mass.

公开(公告)号：US20240124642A1

公开(公告)日：2024-04-18

申请号：US18275492

申请日：2022-02-03

Applicant: TOYOBO MC Corporation

Inventor： Hiroyuki MIEDA ,  Katsuya SHIMENO ,  Tadahiko MIKAMI

IPC: C08G63/189 ,  C08G63/183 ,  C08G63/47 ,  C08G63/85 ,  C08L67/02 ,  C09D167/02

CPC classification number: C08G63/189 ,  C08G63/183 ,  C08G63/47 ,  C08G63/85 ,  C08L67/02 ,  C09D167/02 ,  C08G2390/40 ,  C08L2201/54 ,  C08L2203/16

Abstract: It is provided that a polyester resin and a polyester resin composition that allow reduction of harmful outgas and can form a coating film having excellent characteristics such as curability, retort resistance, and processability. A polyester resin composition comprising polyester resin (A), wherein the polyester resin composition satisfies the following requirements (i) to (iii), (i) the polyester resin (A) has an acid value of 100 eq/ton or more, (ii) the polyester resin composition substantially contains no curing agent, and (iii) the polyester resin (A) includes, as a polyol component constituting the polyester resin (A), a diol (a) having two primary hydroxy groups and having no alicyclic structure, and, furthermore, one or both of a diol (b) having an alicyclic structure, and a diol (c) having one primary hydroxy group and one secondary hydroxy group and having no alicyclic structure.