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    UNIT FOR PROCESSING A LIQUID/GAS PHASE MIXTURE, MERCAPTAN OXIDATION SYSTEM INCLUDING THE SAME, AND METHOD OF PROCESSING A LIQUID/GAS PHASE MIXTURE
    2.
    发明申请
    UNIT FOR PROCESSING A LIQUID/GAS PHASE MIXTURE, MERCAPTAN OXIDATION SYSTEM INCLUDING THE SAME, AND METHOD OF PROCESSING A LIQUID/GAS PHASE MIXTURE 有权
    用于处理液相/气相混合物的单元，包括其的MERCAPTAN氧化系统以及处理液相/气相混合物的方法

    公开(公告)号：US20150151263A1

    公开(公告)日：2015-06-04

    申请号：US14093155

    申请日：2013-11-29

    Applicant: UOP LLC

    Inventor： Jonathan Andrew Tertel ,  Quan Yuan ,  Stephen R. Addison

    IPC: B01F15/02 ,  C10G19/02 ,  B01J19/00 ,  B01F3/04 ,  B01J19/24

    CPC classification number: B01J10/002 ,  B01J4/004 ,  B01J4/008 ,  C10G19/02 ,  C10G2300/202

    Abstract: A unit for processing a liquid/gas phase mixture, a mercaptan oxidation apparatus, and a method of processing a liquid/gas phase mixture are provided. In an embodiment, a unit for processing a liquid/gas phase mixture includes a vessel that is adapted to receive the liquid/gas phase mixture and a distributor that is disposed in the vessel. The distributor is adapted for flow of the liquid/gas phase mixture into the vessel, and the distributor includes a first outlet pipe that is horizontally disposed within the vessel. The first outlet pipe includes top orifices and bottom orifices that are spaced along the first outlet pipe, and the first outlet pipe is in fluid communication with the vessel through the top orifices and the bottom orifices. The top orifices have a smaller cross-sectional area than the bottom orifices.

    Abstract translation: 提供了处理液/气相混合物的单元，硫醇氧化装置和处理液/气相混合物的方法。 在一个实施例中，用于处理液体/气相混合物的单元包括适于接收液体/气相混合物的容器和设置在容器中的分配器。 分配器适用于液/气相混合物流入容器中，并且分配器包括水平地设置在容器内的第一出口管。 第一出口管包括沿着第一出口管间隔的顶部孔口和底部孔口，第一出口管道通过顶部孔口和底部孔口与容器流体连通。 顶孔具有比底孔更小的横截面面积。

    METHODS FOR TREATING HYDROCARBON STREAMS CONTAINING MERCAPTAN COMPOUNDS
    3.
    发明申请
    METHODS FOR TREATING HYDROCARBON STREAMS CONTAINING MERCAPTAN COMPOUNDS 有权
    用于处理含有化合物的碳氢化合物的方法

    公开(公告)号：US20150114883A1

    公开(公告)日：2015-04-30

    申请号：US14066544

    申请日：2013-10-29

    Applicant: UOP LLC

    Inventor： Jonathan Andrew Tertel ,  Luigi Laricchia

    IPC: C10G19/08

    CPC classification number: A61K38/14 ,  A61K31/337 ,  A61K31/5025 ,  A61K31/506 ,  A61K31/513 ,  A61K31/517 ,  A61K31/555 ,  A61K31/704 ,  A61K31/7048 ,  A61K33/24 ,  A61K39/39558 ,  A61K45/06 ,  A61N2005/1098 ,  C07B59/002 ,  C07B2200/05 ,  C07B2200/13 ,  C07C55/10 ,  C07C55/14 ,  C07C57/145 ,  C07C57/15 ,  C07C59/265 ,  C07C63/08 ,  C07D401/14 ,  C07K16/2863 ,  C07K2317/24 ,  C10G19/02 ,  C10G19/08 ,  C10G53/16 ,  C10G2300/104 ,  C10G2300/202

    Abstract: Disclosed is a method for treating hydrocarbon streams containing mercaptan compounds including contacting a first, relatively light hydrocarbon stream including mercaptan compounds with a first alkaline caustic solution to remove the mercaptan compounds from the first hydrocarbon stream and generate a second alkaline caustic solution including mercaptan compounds and oxidizing the mercaptan compounds in the second alkaline caustic solution to generate a third alkaline solution including a first concentration of disulfide compounds. The method further includes separating a portion of the disulfide compounds in the third alkaline solution to form a fourth alkaline solution including a second concentration of disulfide compounds. Still further, the method includes contacting the fourth alkaline solution with a second, relatively heavy hydrocarbon stream including mercaptan compounds to remove the mercaptan compounds from the second hydrocarbon stream, remove the disulfide compounds from the fourth alkaline solution, and generate the first alkaline caustic solution.

    Abstract translation: 公开了一种用于处理含有硫醇化合物的烃流的方法，包括使包含硫醇化合物的第一相对轻质烃流与第一碱性苛性碱溶液接触，以从第一烃流中除去硫醇化合物，并产生包含硫醇化合物的第二碱性苛性碱溶液， 氧化第二碱性苛性碱溶液中的硫醇化合物以产生包含第一浓度的二硫化物的第三碱性溶液。 该方法还包括在第三碱性溶液中分离一部分二硫化物化合物以形成包含第二浓度二硫化物的第四碱性溶液。 此外，该方法包括使第四碱性溶液与第二相对重的烃流（包括硫醇化合物）接触，以从第二烃流中除去硫醇化合物，从第四碱性溶液中除去二硫化物，并产生第一碱性苛性碱溶液 。

    Process and vessel for removing one or more sulfur compounds
    6.
    发明授权
    Process and vessel for removing one or more sulfur compounds 有权
    用于除去一种或多种硫化合物的方法和容器

    公开(公告)号：US09458068B2

    公开(公告)日：2016-10-04

    申请号：US13709613

    申请日：2012-12-10

    Applicant: UOP LLC ,  Boreskov Institute of Catalysis, Siberian Branch of Russian Academy of Sciences

    Inventor： Andrey Kuzmin ,  Aziz Sattar ,  Lev Davydov ,  Jonathan Andrew Tertel

    IPC: C07C7/10 ,  B01D11/04

    CPC classification number: C07C7/10 ,  B01D11/04 ,  B01D11/0461

    Abstract: One exemplary embodiment can be a process for removing one or more sulfur compounds from a first liquid. The process can include passing the first liquid through a first inlet and a second liquid through a second inlet of a vessel, passing the first and second liquids through the passageway for facilitating contacting of the first and second liquids to extract the one or more sulfur compounds from the first liquid to the second liquid, and passing the first liquid through the first outlet and the second liquid through the second outlet. Often, the vessel has a plurality of vortex contactors, and a first outlet and a second outlet. The plurality of vortex contactors can include a first vortex contactor, in turn having at least one wall forming a perimeter about an interior region and including a first side and a second side forming a passageway communicating the first liquid from an exterior to the interior region, and a frustum positioned proximate to the passageway and abutting the at least one wall.

    Abstract translation: 一个示例性实施方案可以是从第一液体中除去一种或多种硫化合物的方法。 该方法可以包括使第一液体通过第一入口和第二液体通过容器的第二入口，使第一和第二液体通过通道，以便于使第一和第二液体接触以提取一种或多种硫化合物 从第一液体到第二液体，并使第一液体通过第一出口和第二液体通过第二出口。 通常，容器具有多个涡旋接触器，以及第一出口和第二出口。 多个涡旋接触器可以包括第一涡旋接触器，其又具有围绕内部区域形成周边的至少一个壁，并且包括第一侧和第二侧，形成将第一液体从外部连通到内部区域的通道， 以及平截头体，其定位成靠近所述通道并邻接所述至少一个壁。

    METHODS AND APPARATUSES FOR REMOVING AMINES FROM EXTRACTED HYDROCARBON STREAMS
    7.
    发明申请
    METHODS AND APPARATUSES FOR REMOVING AMINES FROM EXTRACTED HYDROCARBON STREAMS 审中-公开
    从提取的碳氢化合物流中除去氨基酸的方法和装置

    公开(公告)号：US20150368568A1

    公开(公告)日：2015-12-24

    申请号：US14310192

    申请日：2014-06-20

    Applicant: UOP LLC

    Inventor： Jonathan Andrew Tertel ,  Ronald Gatan

    IPC: C10G19/02 ,  C10G21/08

    CPC classification number: C10G19/02 ,  C10G21/08 ,  C10G53/04 ,  C10G53/12 ,  C10G2300/202

    Abstract: Methods and apparatuses for processing hydrocarbons are provided. In one embodiment, a method for processing a hydrocarbon stream includes feeding a hydrocarbon stream including amine and mercaptan to an extraction zone. The method includes contacting the hydrocarbon stream with an alkaline stream in the extraction zone to convert the mercaptan to a mercaptide. Further, the method includes contacting the hydrocarbon stream with water in the extraction zone to remove the amine from the hydrocarbon stream.

    Abstract translation: 提供了处理碳氢化合物的方法和装置。 在一个实施方案中，用于处理烃流的方法包括将包含胺和硫醇的烃流进料到萃取区。 该方法包括使烃流与萃取区中的碱性流接触以将硫醇转化成硫醇盐。 此外，该方法包括使烃流与萃取区中的水接触以从烃流中除去胺。

    APPARATUSES AND METHODS FOR CONVERSION OF MERCAPTANS
    8.
    发明申请
    APPARATUSES AND METHODS FOR CONVERSION OF MERCAPTANS 有权
    MERCAPTANS转换的装置和方法

    公开(公告)号：US20150353842A1

    公开(公告)日：2015-12-10

    申请号：US14300483

    申请日：2014-06-10

    Applicant: UOP LLC

    Inventor： Jonathan Andrew Tertel ,  Jasna Karagic ,  Luigi Laricchia

    IPC: C10G27/12

    CPC classification number: C10G53/14 ,  B01J8/02 ,  B01J8/0242 ,  B01J8/0446 ,  C10G19/02 ,  C10G27/04 ,  C10G27/06 ,  C10G2300/202

    Abstract: Embodiments of apparatuses and methods for conversion of mercaptans are provided. In one example, an apparatus comprises a vessel that is capable to receive a feed stream that comprises liquid hydrocarbons and the mercaptans. The vessel comprises a catalyst bed section that is capable of contacting the feed stream with a catalyst in the presence of oxygen (O2) and caustic at reaction conditions effective to oxidize the mercaptans and form a caustic-containing, sweetened liquid hydrocarbon-containing stream. A coalescing bed section is capable to coalesce and separate at least a portion of the caustic from the caustic-containing, sweetened liquid hydrocarbon-containing stream for forming a caustic-depleted, sweetened liquid hydrocarbon-containing product stream.

    Abstract translation: 提供了用于转化硫醇的装置和方法的实施方案。 在一个实例中，装置包括能够接收包含液体烃和硫醇的进料流的容器。 该容器包括催化剂床部分，该催化剂床部分能够在有氧氧化硫醇并形成含苛性含硫的含液态含烃流的反应条件下，在氧（O 2）和苛性碱的存在下使催化剂与催化剂接触。 聚结床部分能够从含苛性碱的含甜液体含烃流中聚合并分离至少一部分苛性碱，以形成贫碱化的含有液体烃的产物流。

    Methods and apparatuses for producing low sulfur propane and butane
    10.
    发明授权
    Methods and apparatuses for producing low sulfur propane and butane 有权
    生产低硫丙烷和丁烷的方法和设备

    公开(公告)号：US09522861B2

    公开(公告)日：2016-12-20

    申请号：US14083116

    申请日：2013-11-18

    Applicant: UOP LLC

    Inventor： Luigi Laricchia ,  Jonathan Andrew Tertel

    IPC: C07C7/148 ,  C07C7/152 ,  C10G19/02 ,  C10G19/08 ,  C07C7/10 ,  C07C7/00

    CPC classification number: C07C7/10 ,  C07C7/005 ,  C07C9/08 ,  C07C9/10

    Abstract: Methods and apparatuses are provided for producing low sulfur propane and butane. The method includes reacting a mercaptan in a washed feed stream with a caustic stream to produce a mercaptan salt in a rich caustic stream and a hydrocarbon treated stream. The mercaptan salt in the rich caustic stream is reacted with oxygen and water to produce a mixed caustic/disulfide stream, and the caustic and disulfides in the mixed caustic/disulfide stream are separated to produce a disulfide stream and the caustic stream. The hydrocarbon treated stream is fractionated to produce a propane stream, a butane stream, and a C5+ stream.

    Abstract translation: 提供了生产低硫丙烷和丁烷的方法和装置。 该方法包括使洗涤的进料流中的硫醇与苛性流反应，以在富碱苛性流和烃处理的流中产生硫醇盐。 富氧苛性碱流中的硫醇盐与氧和水反应产生混合的苛性碱/二硫化物流，混合的苛性碱/二硫化物流中的苛性碱和二硫化物被分离以产生二硫化物流和苛性流。 将烃处理的流分馏以产生丙烷料流，丁烷料流和C5 +料流。

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