公开(公告)号：US20190240002A1

公开(公告)日：2019-08-08

申请号：US16388992

申请日：2019-04-19

Applicant: University of Rochester

Inventor： Wayne H. Knox ,  Li Ding ,  Jay F. Kunzler ,  Dharmendra Jani

IPC: A61F2/14 ,  B29D11/00 ,  A61F2/16 ,  B29D11/02 ,  C08J7/12 ,  G02C7/02 ,  A61L27/18 ,  G02B1/04 ,  A61L27/52 ,  A61L27/16 ,  A61F9/008 ,  A61B18/20

CPC classification number: A61F2/14 ,  A61B18/20 ,  A61F2/142 ,  A61F2/1451 ,  A61F2/147 ,  A61F2/16 ,  A61F2/1627 ,  A61F9/008 ,  A61L27/16 ,  A61L27/18 ,  A61L27/52 ,  B29D11/00355 ,  B29D11/00461 ,  B29D11/00769 ,  B29D11/023 ,  B29K2083/00 ,  B29K2105/0061 ,  C08J7/12 ,  C08J7/123 ,  C08J2333/14 ,  C08J2339/06 ,  C08J2383/04 ,  G02B1/041 ,  G02C7/022 ,  G02C2202/12 ,  G02C2202/14

Abstract: An optical device comprising an optical hydrogel with select regions that have been irradiated with laser light having a pulse energy from 0.01 nJ to 50 nJ and a wavelength from 600 nm to 900 nm. The irradiated regions are characterized by a positive change in refractive index of from 0.01 to 0.06, and exhibit little or no scattering loss. The optical hydrogel is prepared with a hydrophilic monomer.

公开(公告)号：US20170181846A1

公开(公告)日：2017-06-29

申请号：US15455870

申请日：2017-03-10

Applicant: University of Rochester

Inventor： Wayne H. Knox ,  Li Ding ,  Jay F. Kunzler ,  Dharmendra Jani

IPC: A61F2/14 ,  A61F2/16 ,  A61F9/008 ,  A61L27/18 ,  B29D11/02 ,  A61L27/16 ,  A61L27/52 ,  C08J7/12 ,  G02B1/04 ,  B29D11/00

CPC classification number: A61F2/14 ,  A61B18/20 ,  A61F2/142 ,  A61F2/1451 ,  A61F2/147 ,  A61F2/16 ,  A61F9/008 ,  A61L27/16 ,  A61L27/18 ,  A61L27/52 ,  B29D11/00355 ,  B29D11/00461 ,  B29D11/023 ,  B29K2083/00 ,  B29K2105/0061 ,  C08J7/12 ,  C08J7/123 ,  C08J2333/14 ,  C08J2339/06 ,  C08J2383/04 ,  G02B1/041 ,  G02C7/022 ,  G02C2202/12 ,  G02C2202/14

Abstract: An optical device comprising an optical hydrogel with select regions that have been irradiated with laser light having a pulse energy from 0.01 nJ to 50 nJ and a wavelength from 600 nm to 900 nm. The irradiated regions are characterized by a positive change in refractive index of from 0.01 to 0.06, and exhibit little or no scattering loss. The optical hydrogel is prepared with a hydrophilic monomer.

公开(公告)号：US20210128294A1

公开(公告)日：2021-05-06

申请号：US17150546

申请日：2021-01-15

Applicant: University of Rochester

Inventor： Wayne H. Knox ,  Li Ding ,  Jay F. Kunzler ,  Dharmendra Jani

IPC: A61F2/14 ,  G02C7/02 ,  B29D11/00 ,  A61F2/16 ,  B29D11/02 ,  C08J7/12 ,  A61B18/20 ,  A61F9/008 ,  A61L27/16 ,  A61L27/52 ,  A61L27/18 ,  G02B1/04

Abstract: An optical device comprising an optical hydrogel with select regions that have been irradiated with laser light having a pulse energy from 0.01 nJ to 50 nJ and a wavelength from 600 nm to 900 nm. The irradiated regions are characterized by a positive change in refractive index of from 0.01 to 0.06, and exhibit little or no scattering loss. The optical hydrogel is prepared with a hydrophilic monomer.

公开(公告)号：US20150378065A1

公开(公告)日：2015-12-31

申请号：US14849058

申请日：2015-09-09

Applicant: University of Rochester

Inventor： Wayne H. Knox ,  Dharmendra Jani ,  Li Ding

IPC: G02B3/00

CPC classification number: G02B3/0087 ,  A61F2/1618 ,  A61F2/1627 ,  A61F9/00834 ,  A61L27/16 ,  A61L27/50 ,  A61L27/52 ,  A61L2400/18 ,  A61L2430/16 ,  G02B2003/0093 ,  G02C2202/12 ,  G02C2202/14 ,  C08L33/10

Abstract: A method for modifying the refractive index of an optical polymeric material. The method comprises continuously irradiating predetermined regions of an optical, polymeric material with femtosecond laser pulses to form a gradient index refractive structure within the material. The optical polymeric material can include a photosensitizer to increase the photoefficiency of the two-photo process resulting in the formation of the observed refractive structures. An optical device includes an optical, polymeric lens material having an anterior surface and posterior surface and an optical axis intersecting the surfaces and at least one laser-modified, GRIN layer disposed between the anterior surface and the posterior surface and arranged along a first axis 45° to 90° to the optical axis. The at least one laser-modified GRIN layer comprises a plurality of adjacent refractive segments characterized by a variation in index of refraction across at least one of at least a portion of the adjacent segments and along each segment.

Abstract translation: 一种用于改变光学聚合物材料的折射率的方法。 该方法包括用飞秒激光脉冲连续照射光学聚合材料的预定区域，以在材料内形成梯度折射率折射结构。 光学聚合物材料可以包括光敏剂以增加双光过程的光效率，导致观察到的折射结构的形成。 光学装置包括具有前表面和后表面的光学聚合物透镜材料和与表面相交的光轴以及设置在前表面和后表面之间并且沿着第一轴线45布置的至少一个激光修饰的GRIN层 °至90°。 所述至少一个激光修饰的GRIN层包括多个相邻的折射片段，其特征在于相邻片段的至少一部分中的至少一个和沿着每个片段的折射率的变化。

公开(公告)号：US10893936B2

公开(公告)日：2021-01-19

申请号：US16388992

申请日：2019-04-19

Applicant: University of Rochester

Inventor： Wayne H. Knox ,  Li Ding ,  Jay F. Kunzler ,  Dharmendra Jani

IPC: A61F2/16 ,  A61F2/14 ,  G02C7/02 ,  B29D11/00 ,  B29D11/02 ,  C08J7/12 ,  A61B18/20 ,  A61F9/008 ,  A61L27/16 ,  A61L27/52 ,  A61L27/18 ,  G02B1/04 ,  B29K83/00 ,  B29K105/00

Abstract: An optical device comprising an optical hydrogel with select regions that have been irradiated with laser light having a pulse energy from 0.01 nJ to 50 nJ and a wavelength from 600 nm to 900 nm. The irradiated regions are characterized by a positive change in refractive index of from 0.01 to 0.06, and exhibit little or no scattering loss. The optical hydrogel is prepared with a hydrophilic monomer.

公开(公告)号：US10649115B2

公开(公告)日：2020-05-12

申请号：US15946287

申请日：2018-04-05

Applicant: University of Rochester

Inventor： Wayne H. Knox ,  Dharmendra Jani ,  Li Ding

IPC: B29D11/00 ,  G02B3/00 ,  A61F9/008 ,  A61L27/16 ,  A61L27/50 ,  A61L27/52 ,  A61F2/16

Abstract: A method for modifying the refractive index of an optical polymeric material. The method comprises continuously irradiating predetermined regions of an optical, polymeric material with femtosecond laser pulses to form a gradient index refractive structure within the material. The optical polymeric material can include a photosensitizer to increase the photoefficiency of the two-photo process resulting in the formation of the observed refractive structures. An optical device includes an optical, polymeric lens material having an anterior surface and posterior surface and an optical axis intersecting the surfaces and at least one laser-modified, GRIN layer disposed between the anterior surface and the posterior surface and arranged along a first axis 45° to 90° to the optical axis. The at least one laser-modified GRIN layer comprises a plurality of adjacent refractive segments characterized by a variation in index of refraction across at least one of at least a portion of the adjacent segments and along each segment.

公开(公告)号：US20180231696A1

公开(公告)日：2018-08-16

申请号：US15946287

申请日：2018-04-05

Applicant: University of Rochester

Inventor： Wayne H. Knox ,  Dharmendra Jani ,  Li Ding

IPC: G02B3/00 ,  A61F2/16 ,  A61F9/008 ,  A61L27/52 ,  A61L27/50 ,  A61L27/16 ,  C08L33/10

CPC classification number: G02B3/0087 ,  A61F2/1618 ,  A61F2/1627 ,  A61F9/00834 ,  A61L27/16 ,  A61L27/50 ,  A61L27/52 ,  A61L2400/18 ,  A61L2430/16 ,  G02B2003/0093 ,  G02C2202/12 ,  G02C2202/14 ,  C08L33/10

Abstract: A method for modifying the refractive index of an optical polymeric material. The method comprises continuously irradiating predetermined regions of an optical, polymeric material with femtosecond laser pulses to form a gradient index refractive structure within the material. The optical polymeric material can include a photosensitizer to increase the photoefficiency of the two-photo process resulting in the formation of the observed refractive structures. An optical device includes an optical, polymeric lens material having an anterior surface and posterior surface and an optical axis intersecting the surfaces and at least one laser-modified, GRIN layer disposed between the anterior surface and the posterior surface and arranged along a first axis 45° to 90° to the optical axis. The at least one laser-modified GRIN layer comprises a plurality of adjacent refractive segments characterized by a variation in index of refraction across at least one of at least a portion of the adjacent segments and along each segment.

公开(公告)号：US09622912B2

公开(公告)日：2017-04-18

申请号：US14564207

申请日：2014-12-09

Applicant: University of Rochester

Inventor： Wayne H. Knox ,  Li Ding ,  Jay F. Kunzler ,  Dharmendra Jani

IPC: A61F2/16 ,  A61F9/008 ,  G02C7/02 ,  B29D11/00 ,  B29D11/02 ,  C08J7/12 ,  A61B18/20 ,  A61F2/14 ,  A61L27/16 ,  A61L27/52

CPC classification number: A61F2/14 ,  A61B18/20 ,  A61F2/142 ,  A61F2/1451 ,  A61F2/147 ,  A61F2/16 ,  A61F9/008 ,  A61L27/16 ,  A61L27/18 ,  A61L27/52 ,  B29D11/00355 ,  B29D11/00461 ,  B29D11/023 ,  B29K2083/00 ,  B29K2105/0061 ,  C08J7/12 ,  C08J7/123 ,  C08J2333/14 ,  C08J2339/06 ,  C08J2383/04 ,  G02B1/041 ,  G02C7/022 ,  G02C2202/12 ,  G02C2202/14

Abstract: An optical device comprising an optical hydrogel with select regions that have been irradiated with laser light having a pulse energy from 0.01 nJ to 50 nJ and a wavelength from 600 nm to 900 nm. The irradiated regions are characterized by a positive change in refractive index of from 0.01 to 0.06, and exhibit little or no scattering loss. The optical hydrogel is prepared with a hydrophilic monomer.

公开(公告)号：US08932352B2

公开(公告)日：2015-01-13

申请号：US13686952

申请日：2012-11-28

Applicant: University of Rochester

Inventor： Wayne H. Knox ,  Li Ding ,  Jay F. Kunzler ,  Dharmendra Jani

IPC: A61F2/16 ,  G02C7/02 ,  A61B18/20 ,  B29D11/00 ,  B29D11/02 ,  C08J7/12 ,  A61F2/14

CPC classification number: A61F2/14 ,  A61B18/20 ,  A61F2/142 ,  A61F2/1451 ,  A61F2/147 ,  A61F2/16 ,  A61F9/008 ,  A61L27/16 ,  A61L27/18 ,  A61L27/52 ,  B29D11/00355 ,  B29D11/00461 ,  B29D11/023 ,  B29K2083/00 ,  B29K2105/0061 ,  C08J7/12 ,  C08J7/123 ,  C08J2333/14 ,  C08J2339/06 ,  C08J2383/04 ,  G02B1/041 ,  G02C7/022 ,  G02C2202/12 ,  G02C2202/14

Abstract: An optical device comprising an optical hydrogel with select regions that have been irradiated with laser light having a pulse energy from 0.01 nJ to 50 nJ and a wavelength from 600 nm to 900 nm. The irradiated regions are characterized by a positive change in refractive index of from 0.01 to 0.06, and exhibit little or no scattering loss. The optical hydrogel is prepared with a hydrophilic monomer.

Abstract translation: 一种光学装置，包括具有已经用激光照射的选择区域的光学水凝胶，所述激光具有0.01nJ至50nJ的脉冲能量和600nm至900nm的波长。 照射区域的特征在于折射率的正变化为0.01至0.06，并且表现出很小的或没有散射损失。 用亲水性单体制备光学水凝胶。

公开(公告)号：US09939558B2

公开(公告)日：2018-04-10

申请号：US14849058

申请日：2015-09-09

Applicant: University of Rochester

Inventor： Wayne H. Knox ,  Dharmendra Jani ,  Li Ding

IPC: G02B3/00 ,  A61F2/16 ,  A61F9/008 ,  A61L27/16 ,  A61L27/50 ,  A61L27/52

CPC classification number: G02B3/0087 ,  A61F2/1618 ,  A61F2/1627 ,  A61F9/00834 ,  A61L27/16 ,  A61L27/50 ,  A61L27/52 ,  A61L2400/18 ,  A61L2430/16 ,  G02B2003/0093 ,  G02C2202/12 ,  G02C2202/14 ,  C08L33/10

Abstract: A method for modifying the refractive index of an optical polymeric material. The method comprises continuously irradiating predetermined regions of an optical, polymeric material with femtosecond laser pulses to form a gradient index refractive structure within the material. The optical polymeric material can include a photosensitizer to increase the photoefficiency of the two-photo process resulting in the formation of the observed refractive structures. An optical device includes an optical, polymeric lens material having an anterior surface and posterior surface and an optical axis intersecting the surfaces and at least one laser-modified, GRIN layer disposed between the anterior surface and the posterior surface and arranged along a first axis 45° to 90° to the optical axis. The at least one laser-modified GRIN layer comprises a plurality of adjacent refractive segments characterized by a variation in index of refraction across at least one of at least a portion of the adjacent segments and along each segment.