Abstract:
A silicon-containing alumina support, a process for preparing the support, and a catalyst containing the support are provided. The alumina support includes an additive silicon enriched on its surface, with the difference between the atomic ratio of silicon to aluminum on the surface of alumina support and that of the alumina support is at least 0.10. The process for preparing the silicon-containing alumina support comprises adding a nanometer silicon compound. The inventive alumina support can be used in manufacturing a catalyst for hydrotreating hydrocarbons with good physico-chemical properties and performance.
Abstract:
Initiator systems of the present invention include both a complexed initiator and a carboxylic acid decomplexer. For example, dicarboxylic acid decomplexer, carboxylic acid ester decomplexers, and monocarboxylic acid decomplexers (preferably those comprising an alkyl group having at least nine carbon atoms for low odor compositions) are useful in the present invention.
Abstract:
Noble metal catalysts supported by the boron nitride (BN) to be used for oxidizing the volatile organic compound (VOC) are provided. The noble metal is selected from a group consisting of platinum (Pt), palladium (Pd), rhodium (Rh) and Ruthenium (Ru). The process for forming the catalyst includes steps of dissolving a noble metal complex compound in an organic solvent for forming a solution, mixing the solution with the boron nitride (BN) for forming a wetted boron nitride (BN) such that the noble metal complex compound is spread on a surface of the boron nitride (BN), and reducing the noble metal complex on the surface of the wetted boron nitride (BN) into the noble metal at a specific temperature by a gas.
Abstract:
A modified carrier carrying on at least a part of an inert carrier surface an oxide which is represented by the formula (1): XaYbZcOd (wherein X is at least an element selected from alkaline earth metals; Y is at least an element selected from Si, Al, Ti and Zr; Z is at least an element selected from Group IA elements and Group IIIb elements of the periodic table, B, Fe, Bi, Co, Ni and Mn; and O is oxygen; a, b, c and d denote the atomic ratios of X, Y, Z and O, respectively, where anull1, 0
Abstract:
The invention pertains to new catalyst systems for polycondensation reactions, for example for producing polyethylene terephthalate. In accordance with the invention, complex compounds with hydrotalcite-analogous structures of general formula nullM(II)1nullxM(III)x(OH)2nullxnull(Annullx/n).mH2O are used, wherein M(II) represents divalent metals, preferably Mg or Zn or NI or Cu or Fe(II) or Co, and M(III) represents trivalent metals, for example Al or Fe(III), and A represents anions, preferably carbonates or borates. These catalysts can be calcinated and can be used in combination with phosphorus compounds that contain at least one hydrolyzable phosphorus-oxygen bond.
Abstract:
A mixed metal oxide, which may be an orthorhombic phase material, is improved as a catalyst for the production of unsaturated carboxylic acids, or unsaturated nitrites, from alkanes, or mixtures of alkanes and alkenes, by contact with a liquid contacting member selected from the group consisting of organic acids, alcohols, inorganic acids and hydrogen peroxide.
Abstract:
This invention provides compositions that are useful for polymerizing at least one monomer to produce a polymer. This invention also provides compositions that are useful for polymerizing at least one monomer to produce a polymer, wherein said composition comprises a post-contacted organometal compound, a post-contacted organoaluminum compound, and a post-contacted treated solid oxide compound.
Abstract:
A process is disclosed for producing hydrocarbons. The process involves contacting a feed stream comprising hydrogen and carbon monoxide with a catalyst in a reaction zone maintained at conversion-promoting conditions effective to produce an effluent stream comprising hydrocarbons. In accordance with this invention, the catalyst used in the process includes at least a Fischer-Tropsch metal and boron. The Fischer-Tropsch metal preferably includes cobalt and optionally ruthenium or platinum. The catalyst may also comprise a support material selected from the group including silica, titania, titania/alumina, zirconia, alumina, aluminum fluoride, and fluorided aluminas.
Abstract:
A composition comprising a promoter, a metal oxide, a support component, and a silicon-containing material, wherein at least a portion of the promoter is present as a reduced valence promoter and methods of preparing such composition are disclosed. The thus-obtained composition is employed in a desulfurization zone to remove sulfur from a hydrocarbon stream.
Abstract:
A process for preparing an antimonate-based mixed metal oxide catalyst in a catalytically active oxidized state, wherein the catalyst is represented by the empirical formula MeaSbbXcQdReOf, wherein Me, X, Q, R, a, b, c, d, e, and f are as defined herein, comprising (a) contacting an aqueous Sb2O3 slurry with HNO3 and one or more Me compounds, and, optionally, one or more compounds selected from X, Q, or R compounds to form a first mixture; (b) heating and drying the first mixture to form a solid product; and (c) calcining the solid product to form the catalyst, the catalysts prepared by the process, and the use of the catalysts in ammoxidation and oxidation processes. The catalysts of the invention are particularly useful for the production of acrylonitrile from propylene, ammonia, and an oxygen-containing gas.
Abstract translation:一种制备催化活性氧化态的锑酸盐型混合金属氧化物催化剂的方法,其中催化剂由经验式MeaSbbXcQdReOf表示,其中Me,X,Q,R,a,b,c,d,e和 f如本文所定义,包括(a)使Sb 2 O 3水溶液与HNO 3和一种或多种Me化合物和任选的一种或多种选自X,Q或R化合物的化合物接触以形成第一混合物; (b)加热和干燥第一混合物以形成固体产物; 和(c)煅烧固体产物以形成催化剂,通过该方法制备的催化剂,以及在氨氧化和氧化过程中使用催化剂。 本发明的催化剂特别可用于从丙烯,氨和含氧气体制备丙烯腈。