METHOD FOR MAKING CAPROLACTAM
    111.
    发明申请
    METHOD FOR MAKING CAPROLACTAM 审中-公开
    制备CAPROLACTAM的方法

    公开(公告)号:WO2004113288A1

    公开(公告)日:2004-12-29

    申请号:PCT/US2004/019432

    申请日:2004-06-17

    CPC classification number: C07D223/04

    Abstract: Method for making caprolactam from 6-aminocapronitrile that contains greater than 500 ppm tetrahydroazepine and its derivatives (THA) in which ammonia and water are removed from crude caprolactam in a single separation step and then THA is removed from the resulting caprolactam melt.

    Abstract translation: 从单一分离步骤中,从含有大于500ppm四氢氮杂及其衍生物(THA)的六氨基己腈制备己内酰胺的方法,其中氨和水从粗己内酰胺中除去,然后从所得己内酰胺熔体中除去THA。

    PROCESS FOR THE PREPARATION OF A NICKEL/PHOSPHOROUS LIGAND CATALYST
    112.
    发明申请
    PROCESS FOR THE PREPARATION OF A NICKEL/PHOSPHOROUS LIGAND CATALYST 审中-公开
    制备镍/磷光催化剂的方法

    公开(公告)号:WO2004091780A1

    公开(公告)日:2004-10-28

    申请号:PCT/US2004/010472

    申请日:2004-04-06

    CPC classification number: B01J31/185 B01J2231/323 B01J2531/847 C07F9/145

    Abstract: Process for preparing a nickel/ligand catalyst in which a crude ligand mixture is contacted with at least one member selected from the group consisting of (i) a weakly acidic organic resin, (ii) a weakly basic organic resin, (iii) a high-surface-area organic resin, (iv) activated carbon, (v) aluminosilicate zeolite, (vi) a two phase solvent system for liquid-liquid extraction and (vii) a Lewis acid; recovering a solution containing a ligand of the formula (R 1 O) 2 POZOP(OR 1 ) 2 ; and contacting the solution with nickel chloride in the presence of a nitrile solvent and a reducing metal which is more electropositive than nickel to produce the nickel/ligand catalyst.

    Abstract translation: 制备镍/配体催化剂的方法,其中粗配体混合物与选自(i)弱酸性有机树脂,(ii)弱碱性有机树脂,(iii)高碱性有机树脂, 表面区域有机树脂,(iv)活性炭,(v)硅铝酸盐沸石,(vi)用于液 - 液萃取的两相溶剂体系和(vii)路易斯酸; 回收含有式(R 1 O)2 POZOP(OR 1)2的配体的溶液; 并在腈溶剂和还原金属存在下使氯化镍与氯化镍接触,所述还原金属比镍更正电以产生镍/配体催化剂。

    MATERIALS AND METHODS FOR PRODUCING 6-CARBON MONOMERS SYNTHASE
    114.
    发明申请
    MATERIALS AND METHODS FOR PRODUCING 6-CARBON MONOMERS SYNTHASE 审中-公开
    用于生产6碳单体合成酶的材料和方法

    公开(公告)号:WO2016175901A2

    公开(公告)日:2016-11-03

    申请号:PCT/US2015/067099

    申请日:2015-12-21

    Abstract: This document describes materials and methods for, for example, producing 6-hydroxyhexanoic acid using a β-ketothiolase or synthase and an alcohol O-acetyltransferase to form a 6-acetyloxy-3-oxohexanoyl-CoA intermediate. This document describes biochemical pathways for producing 6-hydroxyhexanoic acid using a β-ketothiolase or synthase and an alcohol O-acetyltransferase to form a 6-acetyloxy-3-oxohexanoyl-CoA intermediate. 6-hydroxyhexanoic acid can be enzymatically converted to adipic acid, caprolactam, 6-aminohexanoic acid, hexamethylenediamine or 1,6-hexanediol. This document also describes recombinant hosts producing 6-hydroxyhexanoic acid as well as adipic acid, caprolactam, 6-aminohexanoic acid, hexamethylenediamine and 1,6-hexanediol.

    Abstract translation: 该文献描述了例如使用β-酮硫解酶或合酶和醇O-乙酰转移酶产生6-羟基己酸以形成6-乙酰氧基-3-氧代己酰-CoA中间体的材料和方法。 本文件描述了使用β-酮硫解酶或合酶和醇O-乙酰转移酶生成6-羟基己酸的生物化学途径以形成6-乙酰氧基-3-氧代己酰-CoA中间体。 6-羟基己酸可以酶促转化为己二酸,己内酰胺,6-氨基己酸,六亚甲基二胺或1,6-己二醇。 该文献还描述了生产6-羟基己酸以及己二酸,己内酰胺,6-氨基己酸,六亚甲基二胺和1,6-己二醇的重组宿主。

    METHOD OF MANUFACTURING 2-METHYL-1, 3-DIOXOLANE IN A SOLID STATE POLYCONDENSATION PROCESS
    117.
    发明申请
    METHOD OF MANUFACTURING 2-METHYL-1, 3-DIOXOLANE IN A SOLID STATE POLYCONDENSATION PROCESS 审中-公开
    在固体状态聚合过程中制备2-甲基-1,3-二氧戊环的方法

    公开(公告)号:WO2015095879A1

    公开(公告)日:2015-06-25

    申请号:PCT/US2014/071956

    申请日:2014-12-22

    CPC classification number: C07D317/12

    Abstract: The invention relates to a method for producing 2-methyl-1,3-dioxolane from a polyester solid state polymerization system. The method comprises using an acid catalyst to effectuate the conversion of acetaldehyde present within the system to 2-methyl-1,3-dioxolane, which can be readily removed in the ethylene glycol stream.

    Abstract translation: 本发明涉及一种由聚酯固相聚合体系制备2-甲基-1,3-二氧戊环的方法。 该方法包括使用酸催化剂来实现体系内存在的乙醛向2-甲基-1,3-二氧戊环的转化,其可在乙二醇流中容易地除去。

    MULTIPOLYMER FIBERS AND METHOD OF MAKING SAME
    118.
    发明申请
    MULTIPOLYMER FIBERS AND METHOD OF MAKING SAME 审中-公开
    多纤维纤维及其制造方法

    公开(公告)号:WO2015066689A1

    公开(公告)日:2015-05-07

    申请号:PCT/US2014/063862

    申请日:2014-11-04

    Abstract: A multipolymer fiber comprising a polyester phase formed from at least one polyester resin, present at between about 50 to about 95 percent by weight and a polyamide phase formed from at least one polyamide resin, present at between about 5 to about 50 percent by weight, wherein the polyamide phase is distinct from the polyester phase and comprises a plurality of polyamide fibrils dispersed in the polyester phase, and wherein the polyamide fibrils are separately distinguishable from each other.

    Abstract translation: 一种聚合物纤维,其包含由至少一种聚酯树脂形成的聚酯相,其存在于约50至约95重量%之间,以及由至少一种聚酰胺树脂形成的聚酰胺相,所述聚酰胺相以约5至约50重量% 其中所述聚酰胺相不同于聚酯相,并且包含分散在所述聚酯相中的多个聚酰胺原纤维,并且其中所述聚酰胺原纤维彼此分开区分。

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