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    CATALYTIC DEAMINATION FOR CARPROLACTAM PRODUCTION
    1.
    发明申请
    CATALYTIC DEAMINATION FOR CARPROLACTAM PRODUCTION 审中-公开
    卡培兰生产的催化灭活

    公开(公告)号：WO2008103366A3

    公开(公告)日：2008-12-24

    申请号：PCT/US2008002202

    申请日：2008-02-20

    Applicant: UNIV MICHIGAN STATE ,  FROST JOHN W

    Inventor： FROST JOHN W

    IPC: C07D201/00 ,  C07D201/02 ,  C07D201/08

    CPC classification number: C07D201/00 ,  C07D201/02 ,  C07D201/08 ,  Y02P20/52

    Abstract: Catalytic processes for preparing caprolactam, pipecolinic acid, and their derivatives, from lysine or alpha-amino-epsilon-caprolactam starting materials, and products produced thereby. A process for preparing caprolactam or a derivative thereof, the process comprising contacting a reactant comprising lysine or alpha aminocaprolactam with a catalyst and a gas comprising hydrogen gas, in the presence of a solvent. The catalyst may be provided on a support material, such as a transition metal.

    Abstract translation: 从赖氨酸或α-氨基-ε-己内酰胺起始原料制备己内酰胺，哌可啶酸及其衍生物的催化方法，以及由此产生的产物。 一种制备己内酰胺或其衍生物的方法，该方法包括在溶剂存在下使包含赖氨酸或α-氨基己内酰胺的反应物与催化剂和包含氢气的气体接触。 催化剂可以设置在载体材料如过渡金属上。

    PROCESS FOR MAKING CAPROLACTAM
    2.
    发明申请
    PROCESS FOR MAKING CAPROLACTAM 审中-公开
    制造CAPROLACTAM的方法

    公开(公告)号：WO2006101871A1

    公开(公告)日：2006-09-28

    申请号：PCT/US2006/009232

    申请日：2006-03-15

    Applicant: INVISTA TECHNOLOGIES S.A.R.L. ,  SENGUPTA, Sourav, K. ,  OSTERMAIER, John, J. ,  KIRBY, Gregory, S.

    Inventor： SENGUPTA, Sourav, K. ,  OSTERMAIER, John, J. ,  KIRBY, Gregory, S.

    IPC: C07D201/08 ,  C07D223/10

    CPC classification number: C07D201/08

    Abstract: Lactams, in particular ε-caprolactam, are produced by the hydrolytic cyclization of aminonitriles, in particular 6-aminocapronitrile, in the vapor phase in a plurality of adiabatic fixed bed reaction zones arranged in succession wherein at least a portion of the heat of the exothermic reaction is removed between each of the successive reaction zones. Conducting the reaction in such a manner requires less capital for the reactor itself. It has also been found that the product exiting such a reaction system can be directly fed to a distillation unit without the need of additional cooling or storing.

    Abstract translation: 内酰胺，特别是ε-己内酰胺，是通过氨基腈，特别是6-氨基己腈在气相中的水解环化而生成的，所述多个绝热固定床反应区依次排列，其中放热的至少一部分热量 在每个连续反应区之间除去反应。 以这种方式进行反应需要较少的反应堆本身资本。 还已经发现，离开这种反应体系的产物可以直接进料到蒸馏装置，而不需要额外的冷却或储存。

    SYNTHESIS OF CAPROLACTAM FROM LYSINE
    3.
    发明申请
    SYNTHESIS OF CAPROLACTAM FROM LYSINE 审中-公开
    来自LYSINE的CAPROLACTAM的合成

    公开(公告)号：WO2005123669A1

    公开(公告)日：2005-12-29

    申请号：PCT/US2005/020326

    申请日：2005-06-09

    Applicant: BOARD OF TRUSTEES OF MICHIGAN STATE UNIVERSITY ,  FROST, John, W.

    Inventor： FROST, John, W.

    IPC: C07D201/08

    CPC classification number: C07D223/12 ,  C07D201/08

    Abstract: In various embodiments, the present invention can involve a method of synthesizing α-amino-ε -caprolactam. The method can comprise heating a salt of L-lysine in a solvent comprising an alcohol. In other embodiments, the present invention can involve methods for synthesizing ε-caprolactam. The methods can comprise heating a salt of L-lysine in a solvent comprising an alcohol and deaminating the reaction product. In various embodiments, the invention can include methods of converting biomass into nylon 6. The methods can comprise heating L-lysine in a solvent comprising an alcohol to produce α-amino -ε­ caprolactam, deaminating to produce ε-caprolactam and polymerizing into nylon 6, wherein the L-lysine is derived from the biomass. In other embodiments, the present invention can include methods of making nylon 6. The methods can comprise synthesizing ε-caprolactam and then polymerizing, wherein the ε-­caprolactam is derived from L-lysine.

    Abstract translation: 在各种实施方案中，本发明可以涉及一种合成α-氨基-ε-己内酰胺的方法。 该方法可以包括在包含醇的溶剂中加热L-赖氨酸的盐。 在其它实施方案中，本发明可以涉及合成ε-己内酰胺的方法。 该方法可以包括在包含醇的溶剂中加热L-赖氨酸的盐并使反应产物脱氨。 在各种实施方案中，本发明可以包括将生物质转化成尼龙6的方法。该方法可以包括在包含醇的溶剂中加热L-赖氨酸以产生α-氨基-ε己内酰胺，脱氨以产生ε-己内酰胺并聚合成尼龙6 ，其中所述L-赖氨酸衍生自所述生物质。 在其它实施方案中，本发明可以包括制备尼龙6的方法。该方法可以包括合成ε-己内酰胺，然后聚合，其中ε-己内酰胺衍生自L-赖氨酸。

    PRODUCTION OF 6-AMINOCAPROIC ACID
    6.
    发明申请
    PRODUCTION OF 6-AMINOCAPROIC ACID 审中-公开
    6-氨基己酸的生产

    公开(公告)号：WO02040440A1

    公开(公告)日：2002-05-23

    申请号：PCT/US2001/048001

    申请日：2001-10-31

    IPC: C07D223/10 ,  C07B61/00 ,  C07C227/06 ,  C07C229/08 ,  C07C253/30 ,  C07C255/07 ,  C07C255/17 ,  C07C255/19 ,  C07D201/08 ,  C08G69/08 ,  C07C227/12 ,  C07C229/06

    CPC classification number: C07D201/08 ,  C07C227/06 ,  C07C253/30 ,  C07C229/08 ,  C07C255/07 ,  C07C255/17 ,  C07C255/19

    Abstract: A process for making 6-aminocaproic acid by hydroformylating 3-pentenenitrile to produce 3-, 4-, and 5-formylvaleronitrile (FVN mixture), oxidizing the FVN mixture to produce 3-, 4-, and 5-cyanovaleric acid; hydrogenating the resulting product to produce 6-aminocaproic acid, 5-amino-4-methylvaleric acid, and 4-amino-3-ethylbutyric acid; and isolating 6-aminocaproic acid from the reaction product. The resulting 6-aminocaproic acid can be cyclized to produce caprolactam.

    Abstract translation: 通过加氢甲酰化3-戊烯腈生产3-，4-和5-甲酰基戊腈（FVN混合物）制备6-氨基己酸的方法，氧化FVN混合物以产生3-，4-和5-氰基戊酸; 氢化所得产物以产生6-氨基己酸，5-氨基-4-甲基戊酸和4-氨基-3-乙基丁酸; 并从反应产物中分离出6-氨基己酸。 所得6-氨基己酸可以环化以制备己内酰胺。

    PROCESS FOR THE PREPARATION OF A MIXTURE OF epsilon -CAPROLACTAM AND/OR epsilon -CAPROLACTAM PRECURSORS
    7.
    发明申请
    PROCESS FOR THE PREPARATION OF A MIXTURE OF epsilon -CAPROLACTAM AND/OR epsilon -CAPROLACTAM PRECURSORS 审中-公开
    用于制备DOLLAR G（E）己内酰胺和/或前体DOLLAR G（E）己内酰胺的混合物

    公开(公告)号：WO02028525A1

    公开(公告)日：2002-04-11

    申请号：PCT/NL2001/000728

    申请日：2001-10-03

    IPC: B01J19/02 ,  B01J19/24 ,  B01J23/46 ,  C07D201/08

    CPC classification number: B01J19/02 ,  B01J23/462 ,  B01J2219/0236 ,  B01J2219/0277 ,  B01J2219/0286 ,  C07D201/08

    Abstract: Process for the preparation of a mixture of epsilon -caprolactam and epsilon -caprolactam precursors by reductively aminating 5-formylvaleric acid and/or 5-formylvalerate ester(s) in water with hydrogen and an excess of ammonia in the presence of a hydrogenation catalyst, wherein the process is conducted in a reactor of which the inside reactor wall material is a material containing at most 8 wt.% nickel.

    Abstract translation: 本发明涉及一种方法，用于通过的5-甲酰基戊酸和/或酯（S）5-formylevalériate在水中还原胺化制备ε-己内酰胺和/或ε己内酰胺前体的混合物 与氢和过量的氨在氢化催化剂存在下反应。 该过程发生在内壁材料含镍最多为8重量％的反应器中。

    METHOD FOR PRODUCING CYCLIC LACTAMS
    8.
    发明申请
    METHOD FOR PRODUCING CYCLIC LACTAMS 审中-公开
    用于生产环内酰胺

    公开(公告)号：WO01083444A1

    公开(公告)日：2001-11-08

    申请号：PCT/EP2001/004841

    申请日：2001-04-30

    IPC: C07D223/10 ,  C07B61/00 ,  C07D201/08 ,  C07D207/263 ,  C07D211/76 ,  C07D225/02

    CPC classification number: C07D201/08

    Abstract: The invention relates to a method for producing cyclic lactams of the formula (II), wherein n and m may each represent 0, 1, 2, 3, 4, 5, 6, 7, 8 and 9 and the sum of n + m is at least 3, preferably at least 4, R and R represent C1-C6 alkyl, C5-C7 cycloalkyl or C6-C12 aryl groups, by reacting a compound of the formula (I), wherein R , R , m and n have the meaning indicated above, and R represents nitrile groups, carboxylic acid amide groups and carboxylic acid groups, with water vapor in the gaseous phase. The inventive method is further characterized in that a) the compound (I) is reacted with water vapor in the gaseous phase, adding an organic diluent (III) before or after the reaction, which diluent has a miscibility gap under certain quantitative, pressure and temperature conditions, said reaction resulting in a mixture (IV) that contains a lactam (II), b) adjusting the mixture (IV) before or after the removal of ammonia to quantitative, pressure and temperature conditions under which the diluent (III) and water are present in a liquid form and have a miscibility gap, and obtaining a two-phase system consisting of a phase (V) that has a higher proportion of diluent (III) than water, and a phase (VI) that has a higher proportion of water than diluent (III), c) separating phase (V) from phase (VI) and, d) removing from phase (V) the diluent (III) and optionally by-products selected from the group of the low-boilers, high-boilers and unreacted compound (I), and obtaining a lactam (II).

    Abstract translation: 一种用于制备式（II），其中n和m的环状内酰胺过程各自为0，1，2，3，4，5，6，7，8和9可以具有和n + m的和至少为3， 优选至少4，R <1>和R <2> C 1 -C 6 - 烷基，代表C 5 -C 7环烷基或C 6 -C 12 - 芳基，通过将式（I）化合物进行反应，其中R <1 >，R <2>，m和n是如上，R腈，羧酰胺和羧酸基团的意思是与水蒸汽在气相中通过使作为定义，与在气相中的水蒸汽，其特征在于：a）化合物（I） 之前或有机稀释剂（III）的反应之后被添加，含有水在一定的量，压力和温度条件下混溶隙，以得到混合物（IV），其包括内酰胺（II），b）将该混合物（ 转换后的IV）之前或在数量，压力和温度条件的去除氨之后在其下Verdünnungsm edium（III）和水的液体，并表现出混溶性间隙，得到的两两相体系包括包含稀释剂（III）比水高的比例的相（V），和一个相（VI）含有水的比例较高 具有作为稀释剂（III）中，c）相（V）（相VI）被分离出来和d）的相位（V），所述稀释剂（III）和任选的副产物选自低锅炉，高沸点和未反应的Verbindug的组中选择 （I）分离，得到内酰胺（II）。

    METHOD FOR CYCLIZING HYDROLYSIS OF AN AMINONITRILE COMPOUND INTO LACTAM
    9.
    发明申请
    METHOD FOR CYCLIZING HYDROLYSIS OF AN AMINONITRILE COMPOUND INTO LACTAM 审中-公开
    将氨基化合物水解成LACTAM的方法

    公开(公告)号：WO00005203A1

    公开(公告)日：2000-02-03

    申请号：PCT/FR1999/001730

    申请日：1999-07-15

    IPC: C07D223/10 ,  C07B61/00 ,  C07D201/08

    CPC classification number: C07D201/08

    Abstract: The invention concerns a method for cyclizing hydrolysis of an aminonitrile compound into a lactam in the presence of a catalyst. More particularly, it concerns a method for cyclizing hydrolysis of an aminonitrile compound in the presence of a macroporous particulate catalyst resulting from deposit/impregnation of an oxygen-containing compound on a macroporous support such as alumina. The invention is particularly useful for preparing epsilon -caprolactam by cyclizing hydrolysis of aminocapronitrile.

    Abstract translation: 本发明涉及在催化剂存在下环化氨基腈化合物水解成内酰胺的方法。 更具体地说，涉及一种在大孔颗粒催化剂存在下环化氨基腈化合物水解的方法，其由大孔载体如氧化铝沉积/浸渍含氧化合物得到。 本发明特别可用于通过环化氨基己腈的水解来制备ε-己内酰胺。

    PROCESS FOR THE PREPARATION OF epsilon -CAPROLACTAM
    10.
    发明申请
    PROCESS FOR THE PREPARATION OF epsilon -CAPROLACTAM 审中-公开
    用于制备ε-吡咯烷酮的方法

    公开(公告)号：WO99042440A1

    公开(公告)日：1999-08-26

    申请号：PCT/NL1999/000080

    申请日：1999-02-16

    IPC: C07D201/08

    CPC classification number: C07D201/08

    Abstract: Process to prepare epsilon -caprolactam starting from a starting mixture containing a 6-aminocaproate ester, in which in a first step (1) the 6-aminocaproate ester is converted into 6-aminocaproic acid and 6-aminocaproamide by reaction with water in the presence of ammonia at a temperature of between 50 and 250 DEG C, with a separate or simultaneous removal of alcohol(s), and in a subsequent step (2) the 6-aminocaproic acid and 6-aminocaproamide are cyclizised at an elevated temperature, wherein in step (1) the 6-aminocaproate ester is converted into 6-aminocaproic acid and 6-aminocaproamide in the presence of an amount higher than 2 wt.% and less than or equal to 25 wt.% NH3 (relative to the total amount of organic compounds, water and ammonia present in step (1)).

    Abstract translation: 从含有6-氨基己酸酯的起始混合物制备ε-己内酰胺的方法，其中在第一步（1）中，6-氨基己酸酯在存在下与水反应转化成6-氨基己酸和6-氨基己酰胺 的温度在50和250℃之间，分离或同时除去醇，并且在随后的步骤（2）中，6-氨基己酸和6-氨基己酰胺在升高的温度下进行环化，其中 在步骤（1）中，将6-氨基己酸酯在高于2重量％和小于或等于25重量％NH 3的量存在下转化成6-氨基己酸和6-氨基己酰胺（相对于总量 的步骤（1）中存在的有机化合物，水和氨）。

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