Invention Grant
- Patent Title: Durable hydrophilic-super-hydrophobic bipolar self-cleaning composite film, and preparation method therefor
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Application No.: US16309357Application Date: 2017-10-24
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Publication No.: US11149152B2Publication Date: 2021-10-19
- Inventor: Lizhi Zhang , Jinghui Zhi
- Applicant: South China University of Technology
- Applicant Address: CN Guangzhou
- Assignee: South China University of Technology
- Current Assignee: South China University of Technology
- Current Assignee Address: CN Guangzhou
- Agency: Fishman Stewart PLLC
- Priority: CN201710036759.9 20170118
- International Application: PCT/CN2017/107461 WO 20171024
- International Announcement: WO2018/133469 WO 20180726
- Main IPC: C09D5/16
- IPC: C09D5/16 ; B05D1/18 ; B05D3/02 ; B05D3/10 ; B05D7/00 ; C08K3/34 ; C08K5/17 ; C08K5/544 ; C09D183/06

Abstract:
The present invention belongs to the field of super-hydrophobic surface technology, and discloses a durable hydrophilic-super-hydrophobic bipolar self-cleaning composite film and a preparation method therefor. The preparation method is as follows: adding an epoxy silane coupling agent into an organic solvent; after stirring and mixing well, adding an amine curing agent and distilled water to the mixture; stirring and adding micron-sized solid particles and hydrophobic nano silicon dioxide particles; continuing stirring to obtain a hydrophilic layer solution; adding a hydrophobic modifier and a hydrophilic nano silicon dioxide particles into the solvent to obtain a hydrophobic layer solution; coating a pretreated substrate surface with the hydrophilic layer solution, and performing heating treatment at 60° C. to 80° C. for 10-50 min; then coating the surface with the hydrophobic layer solution, and performing heating treatment at 100° C. to 140° C. for 50-90 min to obtain the durable hydrophilic-super-hydrophobic bipolar self-cleaning composite film. The preparation method of the present invention is simple, and the super-hydrophobic surface of the obtained composite film has strong mechanical durability and a good industrial application prospect.
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