Invention Grant
- Patent Title: Process for preparing unsaturated esters proceeding from aldehydes by direct oxidative esterification
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Application No.: US15030775Application Date: 2014-12-05
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Publication No.: US09617199B2Publication Date: 2017-04-11
- Inventor: Steffen Krill , Alexander Lygin , Torsten Balduf , Rudolf Burghardt , Andreas Tepperis , Matthias Groemping
- Applicant: Steffen Krill , Alexander Lygin , Torsten Balduf , Rudolf Burghardt , Andreas Tepperis , Matthias Groemping
- Applicant Address: DE Darmstadt
- Assignee: EVONIK ROEHM GmbH
- Current Assignee: EVONIK ROEHM GmbH
- Current Assignee Address: DE Darmstadt
- Agency: Oblon, McClelland, Maier & Neustadt, L.L.P.
- Priority: EP13198863 20131220
- International Application: PCT/EP2014/076682 WO 20141205
- International Announcement: WO2015/091018 WO 20150625
- Main IPC: C07C67/39
- IPC: C07C67/39 ; B01J23/02 ; B01J23/89 ; B01J35/00

Abstract:
The present invention relates to a process for preparing methyl methacrylate by a direct oxidative esterification of methacrolein with oxygen and methanol, which is conducted in the liquid phase at a pressure of 2 to 100 bar with a gold catalyst. According to the invention, the liquid phase is withdrawn continuously from the reactor and optionally enriched with oxygenous gas, the pH, after the withdrawal, is adjusted to a pH between 5 and 9 by means of addition of a basic solution and this liquid phase is conducted back into the reactor again to an extent of at least 50%.
Public/Granted literature
- US20160251301A1 PROCESS FOR PREPARING UNSATURATED ESTERS PROCEEDING FROM ALDEHYDES BY DIRECT OXIDATIVE ESTERIFICATION Public/Granted day:2016-09-01
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