公开(公告)号：WO2006042675A2

公开(公告)日：2006-04-27

申请号：PCT/EP2005010956

申请日：2005-10-12

Applicant: BASF AG ,  DECKERT PETRA ,  BASSLER PETER ,  BARTSCH MICHAEL ,  HADERLEIN GERD ,  LUYKEN HERMANN ,  SCHEIDEL JENS ,  PFAB PETER ,  AECHTNER TOBIAS ,  SIEGEL WOLFGANG

Inventor： DECKERT PETRA ,  BASSLER PETER ,  BARTSCH MICHAEL ,  HADERLEIN GERD ,  LUYKEN HERMANN ,  SCHEIDEL JENS ,  PFAB PETER ,  AECHTNER TOBIAS ,  SIEGEL WOLFGANG

CPC classification number: B01J31/4053 ,  B01D11/0434 ,  B01J31/1845 ,  B01J31/185 ,  B01J31/24 ,  B01J31/403 ,  B01J2231/323 ,  B01J2531/847 ,  C07C253/10 ,  C07C253/32 ,  Y02P20/584 ,  C07C255/04

Abstract: The invention relates to a method for the extractive separation of homogeneously dissolved catalysts from a reaction product from a hydrocyanation of unsaturated mononitriles to dinitriles, by extraction with a carbon material (K), characterised in that a) a non-polar aprotic liquid (F) is added to the reaction product to give a stream (I) and b) the stream (I) is extracted with a carbon material (K) at a temperature (T), to give a stream (II), containing the carbon material (K), enriched with the catalyst and a stream (III), stripped of catalyst.

Abstract translation: 通过烃的装置（K），其特征在于用于由不饱和单腈向二腈，通过萃取的氢氰化反应流出物均匀溶解的催化剂的提取分离方法，包括：a）向所述反应在非极性非质子液体（F），由此电流 在温度（T）（与烃K（I）获得，以及b）的电流（I））被提取，其特征在于，一个流（II）含有富含与催化剂烃（K）和催化剂贫流（ III）。

公开(公告)号：WO2005056507A3

公开(公告)日：2006-12-21

申请号：PCT/EP2004014119

申请日：2004-12-10

Applicant: BASF AG ,  RUMPF BERND ,  DECKERT PETRA ,  MUELLER THOMAS ,  GRIMMER JOHANNES

Inventor： RUMPF BERND ,  DECKERT PETRA ,  MUELLER THOMAS ,  GRIMMER JOHANNES

IPC: C07C403/08 ,  C07C45/00 ,  C07C45/59 ,  C07C49/743

CPC classification number: C07C403/08 ,  C07C2601/16 ,  Y02P20/55

Abstract: The invention relates to a method for producing cyclohexenone derivatives of general formula (I), wherein R 1 represents hydrogen or OH; R 2 represents (Ia), comprising the following steps: (a) hydrolyzing a cyclohexenol compound of formula (II), wherein R 3 represents hydrogen and R 4 represents C 1 -C 6 -alkoxy or R 3 and R 4 represent vicinal hydroxy groups, which carry a common acetal protective group or a ketone protective group, R 5 represents (IIa), and R 6 represents a protected hydroxy group, in the absence of an organic solvent and in the presence of an acid catalyst; and; (b) extracting the reaction mixture by using a polar extracting agent.

Abstract translation: 本发明涉及一种用于（I），其中R ^{1 是氢或OH通式环己烯酮衍生物的制备; [R 2 表示（Ia）中，其包括以下步骤：（a）式的Cyclohexenolverbindung水解（II）其中R 3 是氢并且R 4 < 6 为C _{1 -C >烷氧基，或R 3 和R 4 连位羟基的 都携带一个共同的缩醛或缩酮保护基团，R 5 是（IIa）中，R 6 是被保护的羟基，在酸中不存在有机溶剂的存在 催化剂; 和（b）用与极性萃取反应混合物。}}

公开(公告)号：BRPI0507197A

公开(公告)日：2007-06-26

申请号：BRPI0507197

申请日：2005-01-27

Applicant: BASF AG

Inventor： JUNGKAMP TIM ,  BAUMANN ROBERT ,  BARTSCH MICHAEL ,  HADERLEIN GERD ,  LUYKEN HERMANN ,  SCHEIDEL JENS ,  AECHTNER TOBIAS ,  PFAB PETER ,  DECKERT PETRA ,  SIEGEL WOLFGANG ,  BASSLER PETER

IPC: C07C253/10 ,  C07C255/07

Abstract: A process is described for preparing 3-pentenenitrile, characterized by the following process steps: (a) isomerizing a reactant stream which comprises 2-methyl-3-butenenitrile over at least one dissolved or dispersed isomerization catalyst to give a stream 1 which comprises the at least one isomerization catalyst, 2-methyl-3-butenenitrile, 3-pentenenitrile and (Z)-2-methyl-2-butenenitrile, (b) distilling stream 1 to obtain a stream 2 as the top product which comprises 2-methyl-3-butenenitrile, 3-pentenenitrile and (Z)-2-methyl-2-butenenitrile, and a stream 3 as the bottom product which comprises the at least one isomerization catalyst, (c) distilling stream 2 to obtain a stream 4 as the top product which, compared to stream 2, is enriched in (Z)-2-methyl-2-butenenitrile, based on the sum of all pentenenitriles in stream 2, and a stream 5 as the bottom product which, compared to stream 2, is enriched in 3-pentenenitrile and 2-methyl-3-butenenitrile, based on the sum of all pentenenitriles in stream 2, (d) distilling stream 5 to obtain a stream 6 as the bottom product which comprises 3-pentenenitrile and a stream 7 as the top product which comprises 2-methyl-3-butenenitrile.

公开(公告)号：CA2582813A1

公开(公告)日：2006-04-27

申请号：CA2582813

申请日：2005-10-12

Applicant: BASF AG

Inventor： BARTSCH MICHAEL ,  BASSLER PETER ,  PFAB PETER ,  DECKERT PETRA ,  SIEGEL WOLFGANG ,  AECHTNER TOBIAS ,  HADERLEIN GERD ,  LUYKEN HERMANN ,  SCHEIDEL JENS

IPC: B01J38/56 ,  B01D11/04 ,  B01J31/18 ,  B01J31/24 ,  B01J31/40 ,  C07C253/10

Abstract: A process for extractively removing homogeneously dissolved catalysts from a reaction effluent of a hydrocyanation of unsaturated mononitriles to dinitriles with a hydrocarbon H, including performing the steps of a) concentrating the reaction effluent before step b) by distillation at pressures of from 0.1 to 5000 mbar and temperatures of from 10 to 150° C., b) adding a hydrocarbon H to the concentrated reaction effluent to obtain a stream I, and c) feeding stream I, without prior separation of the liquid phases, into an extraction apparatus and extracting it at a temperature T with the hydrocarbon H to obtain a stream II comprising the hydrocarbon H enriched with the catalyst and a stream III having a low catalyst content.

公开(公告)号：AR048152A1

公开(公告)日：2006-04-05

申请号：ARP050100306

申请日：2005-01-28

Applicant: BASF AG

Inventor： JUNGKAMP TIM ,  BAUMANN ROBERT ,  BARTSCH MICHAEL ,  HADERLEIN GERD ,  LUYKEN HERMANN ,  SCHEIDEL JENS ,  DECKERT PETRA ,  PFAB PETER ,  SIEGEL WOLFGANG ,  AECHTNER TOBIAS

IPC: C07C253/34 ,  C07C255/04 ,  C07F9/02 ,  C07B63/00 ,  B01J31/40

Abstract: Procedimientos para la separacion extractiva de complejos de níquel (0) con ligandos y/o ligandos libres fosforados del producto de una reaccion de hidrocianacion de mononitrilos insaturados para obtener dinitrilos por extraccion mediante un hidrocarburo, donde se lleva a cabo la separacion de fases del hidrocarburo y del producto de la reaccion en dos fases, a una temperatura T (en sC) caracterizado porque el contenido de complejos de níquel (0) con ligandos fosforados y/o ligandos libres fosforados del producto de la reaccion de hidrocianacion es, segun la temperatura T, de por lo menos y % en peso, y es independiente de la temperatura T, como máximo de 60% en peso, siendo dado el valor numérico del contenido mínimo y por la ecuacion y = 0,5 ò T l 20 y T debe usarse en la ecuacion como valor numérico adimensional.

公开(公告)号：AU2003246393A1

公开(公告)日：2004-02-02

申请号：AU2003246393

申请日：2003-07-07

Applicant: BASF AG

Inventor： KAIBEL GERD ,  MERGER MARTIN ,  DOMSCHKE THOMAS ,  DECKERT PETRA ,  SAUER FRIEDRICH

IPC: C07D307/62

Abstract: The invention relates to a method for the separation of ascorbic acid from a mixture containing ascorbic acid and 2-keto-L-gulonic acid in a polar, preferably aqueous solvent, by means of liquid/liquid extraction using an amide. The method preferably also comprises steps for the back-extraction of the ascorbic acid, recycling of the extraction solvent and/or the back extraction solvent and for isolation of the ascorbic acid from the back extraction solvent. The invention further relates to a method for the production of ascorbic acid from KGA and isolation of the ascorbic acid so produced.

公开(公告)号：DE50301577D1

公开(公告)日：2005-12-08

申请号：DE50301577

申请日：2003-07-07

Applicant: BASF AG

Inventor： KAIBEL GERD ,  MERGER MARTIN ,  DOMSCHKE THOMAS ,  DECKERT PETRA ,  SAUER FRIEDRICH

IPC: C07D307/62

Abstract: The invention relates to a method for the separation of ascorbic acid from a mixture containing ascorbic acid and 2-keto-L-gulonic acid in a polar, preferably aqueous solvent, by means of liquid/liquid extraction using an amide. The method preferably also comprises steps for the back-extraction of the ascorbic acid, recycling of the extraction solvent and/or the back extraction solvent and for isolation of the ascorbic acid from the back extraction solvent. The invention further relates to a method for the production of ascorbic acid from KGA and isolation of the ascorbic acid so produced.

公开(公告)号：DE10358003A1

公开(公告)日：2005-07-14

申请号：DE10358003

申请日：2003-12-11

Applicant: BASF AG

Inventor： RUMPF BERND ,  DECKERT PETRA ,  MUELLER THOMAS ,  GRIMMER JOHANNES

IPC: C07C45/00 ,  C07C45/59 ,  C07C49/743 ,  C07C403/08

公开(公告)号：AU2003290036A1

公开(公告)日：2004-07-14

申请号：AU2003290036

申请日：2003-12-13

Applicant: BASF AG

Inventor： DOMSCHKE THOMAS ,  MERGER MARTIN ,  DECKERT PETRA ,  SAUER FRIEDRICH

IPC: C07H1/06 ,  C07H7/027

公开(公告)号：CA2492155A1

公开(公告)日：2004-01-22

申请号：CA2492155

申请日：2003-07-07

Applicant: BASF AG

Inventor： KAIBEL GERD ,  DECKERT PETRA ,  DOMSCHKE THOMAS ,  MERGER MARTIN ,  SAUER FRIEDRICH

IPC: C07D307/62

Abstract: The invention relates to a method for the separation of ascorbic acid from a mixture containing ascorbic acid and 2-keto-L-gulonic acid in a polar, preferably aqueous solvent, by means of liquid/liquid extraction using an amide. The method preferably also comprises steps for the back-extraction of the ascorbic acid, recycling of the extraction solvent and/or the back extraction solvent and for isolation of the ascorbic acid from the back extraction solvent. The invention further relates to a method for the production of ascorbic acid from KGA and isolation of the ascorbic acid so produced.