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公开(公告)号:DE4229142A1
公开(公告)日:1994-03-03
申请号:DE4229142
申请日:1992-09-01
Applicant: BASF AG
Inventor: DE CLERCQ ARNOLD DR , ETTL ROLAND DR , GONCALVES CARLOS ALBERTO , HOEHR LOTHAR DR , HOHMANN ANDREAS DR , RIEBELING ULRICH
Abstract: Mixtures of paper sizing agents are produced by mixing an aqueous suspension of a hydrolyzed cationic starch with fine particle aqueous polymer dispersions which constitute a paper sizing agent, and by emulsifying C14-C22-alkyl diketens in said mixture at temperatures of at least 70 DEG C. The mixtures are used for paper beater and surface sizing.
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公开(公告)号:DE19606845A1
公开(公告)日:1997-08-28
申请号:DE19606845
申请日:1996-02-23
Applicant: BASF AG
Inventor: JULIUS MANFRED DR , ETTL ROLAND DR , GUENTHER WOLFGANG DR , GREINDL THOMAS DR
IPC: C07C255/25 , C08F8/30 , C10L1/14 , C10L1/18 , C10L1/22 , C10L1/238 , C10L10/00 , C10M133/54 , C10M149/12 , C07C253/00 , C07C255/24 , C08F10/00 , C10M145/26
Abstract: Polyalkylamine derivatives of formula ZCH2NH2-nHn (I) are new. (where, n = 0 or 1; z = polyalkyl residue of molecular weight 150-40000; Y = residue of formula (IIa) or (IIb); R, R1 and R2 = H, optionally substituted alk(en)yl, alkinyl, and optionally substituted cycloalkyl, aryl(alkyl) having heteroatom(s); A = alkylene imine residues of formula (III); m = 0-10; Alk = optionally substituted alkylene; R3 = H, alk(en)yl, alkinyl, or aryl or when Y is a residue of formula (IIa) keto residue of formula (IVa); in (IVa): R = as above or when Y = group of formula (IIb), is a cyano residue of formula (IVb) (where, R1 and R2 = as above) or when n = 0 one of the residues Y is optionally a polyoxyalkylene residue (V) (where, q = 1-30; Alk = as above; and E = H or 1-6C alkyl). Preparation of the derivatives is also claimed. Also claimed are lubricant and fuel compositions containing the above derivatives.
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公开(公告)号:DE19618675A1
公开(公告)日:1997-03-27
申请号:DE19618675
申请日:1996-05-09
Applicant: BASF AG
Inventor: KOKEL NICOLAS DR , RAU MARIA GYOPAR DR , ETTL ROLAND DR , LARBIG HARALD DR , MELDER JOHANN-PETER DR , GULBINS ERICH DR
IPC: C08G18/08 , C08G18/12 , C08G18/38 , C08G18/50 , C08G18/83 , C14C11/00 , C08G18/10 , C08G18/32 , C08G18/34 , C08G18/42 , C08G18/66 , C08G63/685 , C08J5/12 , C08J7/16 , C09D175/04 , C09J175/04
Abstract: The invention concerns aqueous dispersions containing a polyurethane (A), containing structural units derived from compounds of formula (I), in which the substituents have the following meanings: R , R , R each designate hydrogen, C1-C24 alkyl or C6 - C24 alkenyl; R designates hydrogen; R , R a) together designate C4-C10 alkane-diyl, b) each designate C2-C10 alkyl, C5-C8 cycloalkyl or C7-C20 aralkyl, c) each designate a hydroxyl-terminated poly(C2-C4 alkylene oxide), or d) designate an R or R group with the meaning given in (a) to (c) and the other group designating hydrogen or a group of formula (II), in which X designates C2-C6 alkane-diyl; and R has the same meaning as R or R with the exception that R is not a group of formula II, R and R carrying a total of between 2 and 5 hydroxyl groups bonded to aliphatic carbon atoms; and R and/or R optionally carrying 1 or 2 aromatically bonded hydroxyl groups or 1 nitrile, tertiary amino, carboxylic acid or sulphonic acid group which are optionally present in the form of their salts.
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公开(公告)号:DE19719059A1
公开(公告)日:1998-11-12
申请号:DE19719059
申请日:1997-05-06
Applicant: BASF AG
Inventor: ETTL ROLAND DR , MEIXNER HUBERT DR , ESSER ANTON DR , SCHOLZ RAINER , MAHR NORBERT DR , STEUERLE ULRICH DR , HOENE MATTHIAS DR , LORENZ KLAUS DR
IPC: D21H21/06 , C08F8/32 , C08F8/44 , C08G73/02 , D21H17/08 , D21H17/14 , D21H17/17 , D21H17/37 , D21H17/38 , D21H17/45 , D21H17/49 , D21H17/54 , D21H17/55 , D21H17/56 , D21H21/02 , D21H21/10 , D21H21/16
Abstract: The invention relates to a method for producing paper, paperboard and cardboard by dehydrating paper material containing interfering substances in the presence of fixing agents. Reaction products are used as fixing agents. Said products are obtained by reacting polymers, containing amino and/or ammonium groups, from the group of: polymers containing vinyl amino units, polyalkylene polyamines, polyamidoamines, polyamidoamines grafted with ethylene imine and optionally cross-linked, polydiallydldimethylammoniumchlorides; polymers containing dialkylaminoalkylacrylamide-units or dialkylaminoalkylmethacrylamide units and polyallylamines and dicyandiamide-formaldehyde-condensates, with reactive sizing agents for paper with a polymer/reactive sizing agent weight ratio of 15,000 : 1 to 1 : 1. The invention also relates to reaction products thus obtained and to their use as fixing agents for water soluble and water insoluble interfering substances in the production of paper, paperboard and cardboard from paper materials containing interfering substances.
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公开(公告)号:DE19518039A1
公开(公告)日:1996-11-21
申请号:DE19518039
申请日:1995-05-17
Applicant: BASF AG
Inventor: MUELLER REINHARD DR , WEHLAGE THOMAS DR , TRIESELT WOLFGANG DR , OFTRING ALFRED DR , KAPPES ELISABETH DR , OETTER GUENTER DR , BOECKH DIETER DR , ETTL ROLAND DR , HETTCHE ALBERT DR
IPC: C11D7/26 , A61L2/18 , C11D3/39 , C11D3/42 , C11D7/32 , C11D7/34 , C11D7/36 , C11D7/54 , D06L3/12 , D06L4/614 , D06L4/657 , D06L4/671 , C11D3/28 , C11D3/20 , D06L3/02 , A01N59/00 , C07D307/33 , C07D263/22 , C07D223/10 , C07F9/30
Abstract: Disclosed is the use of heterocyclic compounds of the formula (I) R -X-L, in which: L stands for a cyclic carbamate group, lactone oxy group or lactam group, X stands for an oxygen-containing group of one of the formulae (a), (b), (c), (d), (e) or (f), in which A represents a bridging group; and R indicates an organic group or an L group, as activators for inorganic peroxy compounds, in particular as cold bleach activators or optical brighteners in washing, cleaning and bleaching agents and in disinfectants.
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公开(公告)号:DE19710616A1
公开(公告)日:1998-09-17
申请号:DE19710616
申请日:1997-03-14
Applicant: BASF AG
Inventor: ETTL ROLAND DR , SCHUHMACHER RUDOLF DR , BONN JOHANN , REUTHER WOLFGANG DR , UTECHT JENS DR , JULIUS MANFRED DR
IPC: C08G73/02 , D21H17/16 , D21H17/17 , D21H17/54 , D21H21/16 , C08L39/02 , C08L79/04 , D06M13/13 , D06M13/192
Abstract: The invention relates to aqueous dispersions of reactive gluing agents containing 0.1 to 10 weight per cent of water-soluble or water-dispersible polymeric protective colloids which can be obtained by reacting polymers containing amino groups from the group: polymers containing vinylamine units; polyamidoamines; polyamidoamines grafted with ethylenimine - with diketenes at a weight ratio polymers:diketenes of 10000:1 to 1:3. The invention also relates to a method for producing aqueous dispersions of reactive gluing agents by homogenising said reactive gluing agents in an aqueous solution of at least one of the aforementioned protective colloids at temperatures of 20 to 90 DEG C under the effect of shear forces, and to the use of aqueous dispersions of gluing agents thus obtained as pulp sizing agents in the production of paper, board and cardboard and for hydrophobing cellulose fibers.
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公开(公告)号:DE19701523A1
公开(公告)日:1998-07-23
申请号:DE19701523
申请日:1997-01-17
Applicant: BASF AG
Inventor: NIESSNER MANFRED DR , NILZ CLAUDIA DR , LORENCAK PRIMOZ DR , RUEBENACKER MARTIN DR , ETTL ROLAND DR
IPC: C08B30/12 , C08B31/00 , C08L3/00 , C08L3/02 , C08L3/04 , C08L3/06 , C08L29/04 , C08L33/14 , C08L33/24 , C08L39/00 , D21H17/28 , D21H17/29 , D21H17/44 , D21H21/10 , D21H21/18 , C08L33/02 , C08L33/20 , C08L29/00 , C08L79/00 , D21H21/20
Abstract: The present invention relates to starch which is modified with at least one cationic polymer (P), and a method for producing same which is characterized in that: a) an anionically modified starch (A) is reacted with the cationic polymer (P); or that (b) a native starch (B) or a non-anionically modified starch (C) is reacted with the cationic polymer (P) in the presence of an anionic modifier (M). The invention also relates to the use of said polymer-modified starches.
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公开(公告)号:DE19605447A1
公开(公告)日:1997-08-28
申请号:DE19605447
申请日:1996-02-15
Applicant: BASF AG
Inventor: ETTL ROLAND DR , MEIXNER HUBERT DR , HEITZ WALTER PROF DR , NOEDING GUNNAR
Abstract: Stabilisers for aqueous alkyl diketene dispersions comprise amphiphilic alkylated polyethylene imines prepared by partial alkylation of polyethylene imines using alkyl halides containing at least 5C atoms. Also claimed are aqueous alkyl diketene dispersions containing these stabilisers, used as internal sizing agents for paper pulp. Preferably the polyethylene imines have a weight average molecular weight of 500-50000 (700-30000). The alkyl halides contain 5-30C atoms and are preferably 1-22C alkyl bromides. The degree of alkylation is 1-35 (3-33)%.
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公开(公告)号:DE19540998A1
公开(公告)日:1997-05-07
申请号:DE19540998
申请日:1995-11-03
Applicant: BASF AG
Inventor: ETTL ROLAND DR , REUTHER WOLFGANG DR , LORENCAK PRIMOZ DR , BONN JOHANN
IPC: C07C45/90 , C07C49/88 , C09K23/00 , D06M13/13 , D06M15/11 , D21H17/09 , D21H17/10 , D21H17/17 , D21H17/23 , D21H17/29 , D21H21/16 , D21H17/72 , B01F17/00
Abstract: The invention concerns aqueous alkyldiketene dispersions containing an alkyldiketene, cationic starch with an amylopectin content of at least 95 % by wt. and the following anionic dispersants: (a) 0.05 to 1.0 % by wt. of lignin sulphonic acid, condensation products of naphtalene sulphonic acid and formaldehyde, sulphonated polystyrene or salts or mixtures of such polymers and (b) 0.05 to 1.5 % by wt. of sulphuric acid half esters of alcohols with at least 10 C-atoms, mono- or diphosphoric acid half esters of alkoxylated alcohols with at least 10 C-atoms, sulphuric acid half esters of alkoxylated alcohols with at least 10 C-atoms, mono- or diphosphoric acid esters of alkoxylated alcohols with at least 10 C-atoms, C12-C30 alkyl sulphonic acids or salts or mixtures of such compounds. The invention also concerns the use of such alkyldiketene dispersions as bulk size in the manufacture of paper, paperboard and cardboard, as well as in making cellulose fibres water-repellent.
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公开(公告)号:DE4337785A1
公开(公告)日:1995-05-11
申请号:DE4337785
申请日:1993-11-05
Applicant: BASF AG
Inventor: ETTL ROLAND DR , REUTHER WOLFGANG DR
IPC: C07C51/60 , C07C57/66 , B01J31/02 , C07C51/64 , C07C233/05
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