公开(公告)号：JPH1060263A

公开(公告)日：1998-03-03

申请号：JP12513097

申请日：1997-05-15

Applicant: BASF AG

Inventor： LICHT ULRIKE DR ,  KOKEL NICOLAS DR ,  HAEBERLE KARL DR ,  ANGEL MAXIMILIAN DR ,  WEYLAND PETER DR ,  SCHERR GUENTER DR

IPC: C08L75/14 ,  C08G18/08 ,  C08G18/67 ,  C08G73/04 ,  C09D175/14 ,  C09J175/14

Abstract: PROBLEM TO BE SOLVED: To obtain the subject dispersant which has a good storage stability and is used for forming a thermally stable bond by formulating a specific polyurethane and an amino-functional group-bearing macromolecular compound. SOLUTION: This dispersant contains (A) a mixture of (i) a polyurethane bearing a group which makes the polyurethane dispersible in water and a C-C double bond which is activated by the directly bonding carbonyl group, (ii) a polyurethane which makes the polyurethane dispersible in water, but does not bear the group bearing a C-C double bond activated by the directly bonding carbonyl group and (B) a compound which bears at least two of hydrogen bonds in the from of an amino functional group, has a solubility of >=1g/l (at 25 deg.C) and a number-average molecular weight (Mn ) of 200-1,000,000. Thus, a dispersant useful as a coating or an adhesive is obtained.

公开(公告)号：JP2000256436A

公开(公告)日：2000-09-19

申请号：JP6034999

申请日：1999-03-08

Applicant: BASF AG

Inventor： KOKEL NICOLAS DR ,  HAEBERLE KARL ,  KRAUS RUPERT DR

IPC: C07C267/00 ,  C08G18/79 ,  C08L67/00

Abstract: PROBLEM TO BE SOLVED: To provide a solid carbodiimide which has an urethane structures and/or an urea sructures, has a carbodiimide structures bonded to nonaromatic carbon atoms, and is useful as a stabilizer for polyester plastics. SOLUTION: This carbodiimide is solid at 25 deg.C and is produced by separating carbon dioxide in the presence of a catalyst from a diisocyanate having no isocyanate group bonded to an aromatic carbon atom, thus converting the diisocyanate into a carbodiimide, and reacting this isocyanate-group-containing carbodiimide with a compound having at least two isocyanate-reactive groups to form urethane structures and/or urea structures. Preferably, the diisocyanate is 1,3-bis(1-methyl-1-isocyanatoethyl)benzene. Preferable examples of the compound having at least two isocyanate-reactive groups are an organic compound having at least two hydroxyl groups, an organic compound having at least two amino groups, and an organic compound having at least one hydroxyl group and at least one amino group.

公开(公告)号：JP2000026398A

公开(公告)日：2000-01-25

申请号：JP13259899

申请日：1999-05-13

Applicant: BASF AG

Inventor： BOLLMANN HEINZ ,  HAEBERLE KARL ,  KOKEL NICOLAS DR ,  THAERIGEN RAINA

IPC: C08G18/08 ,  C07C267/00 ,  C07C271/20 ,  C08G18/02 ,  C08G18/28 ,  C08G18/38 ,  C08G18/79 ,  C08G18/80 ,  C08K5/29 ,  C08L75/06 ,  C09K15/18 ,  C08G18/09 ,  C08G18/48 ,  C08L67/00 ,  C08L67/02 ,  C08L67/04 ,  C08L67/06 ,  C08L75/00 ,  C08L77/00 ,  C08L77/12

Abstract: PROBLEM TO BE SOLVED: To obtain a new carbodiimide composed of a specific carbodiimide and useful as a stabilizer for the hydrolytic decomposition of a plastic composed mainly of a polyester. SOLUTION: The objective carbodiimide is based on 1,3-bis(1-methyl-1- isocyanatoethyl)benzene and contains 12-40 wt.% of ethylene oxide unit [CH2 - CH2 - O] based on the carbodiimide and the structural unit of formula I, e.g. a compound of formula II [R is NHCONHR1 or NHCOOR1 (R1 is a group derived from an isocyanate-reactive compound); (n) is 0-10]. The carbodiimide can be produced by reacting 1,3-bis(1-methyl-1-isocyanatoethyl)benzene in the presence of a catalyst to eliminate carbon dioxide and form a carbodiimide and reacting the carbodiimide with a compound reactive with isocyanate and having the ethylene oxide unit.

公开(公告)号：JPH10182781A

公开(公告)日：1998-07-07

申请号：JP34965297

申请日：1997-12-18

Applicant: BASF AG

Inventor： KOKEL NICOLAS DR ,  LARBIG HARALD DR ,  MENZEL KLAUS ,  BECK ERICH DR ,  REICH WOLFGANG DR ,  VOIT GUIDO DR

IPC: C08G18/00 ,  C08G18/08 ,  C08G18/16 ,  C08G18/28 ,  C08G18/30 ,  C08G18/32 ,  C08G18/67 ,  C09D5/00 ,  C09D175/08

Abstract: PROBLEM TO BE SOLVED: To produce a polyurethane self-dispersible in water without any unpleasant odor by reacting a polyisocyanate with a polyol and a specific photoinitiator. SOLUTION: (A) At least one polyisocyanate is reacted with (B) at least one polyol composed of (i) 9-100mol% of a polyol having >=500 molecular weight or a mixture of two or more thereof and (ii) 0-91mol% of a polyol having R R , etc.; at least one of R , R , R , R and R is used incorporation into the polyurethane and one or more of R , R , R , R and R of the remaining radicals are H, a 1-12C alkyl, etc.; R and R are each H, COOH, etc.; R and R are each H, a 1-12C alkyl, etc.) to afford the objective polyurethane in which all the dispersions having a covalently bonded photoinitiator are capable of manifesting an improvement in film resistance after irradiation of ultraviolet light and physical drying.

公开(公告)号：JPH10158345A

公开(公告)日：1998-06-16

申请号：JP30276397

申请日：1997-11-05

Applicant: BASF AG

Inventor： HAEBERLE KARL DR ,  KOKEL NICOLAS DR ,  LICHT ULRIKE DR ,  GULBINS ERICH DR

IPC: C08F283/00 ,  C08G18/08 ,  C08G18/12 ,  C08G18/66 ,  C09D151/08 ,  C09D175/04 ,  C09J151/08 ,  C09J175/04

Abstract: PROBLEM TO BE SOLVED: To provide a method for producing a polyurethane hybrid dispersion good in gloss, stimulation and hardening rate. SOLUTION: This method for producing a polyurethane hybrid dispersion comprises a radical polymerization of at least one kind of a compound having at least one olefinically unsaturated double bond in the presence of at least one kind of polyurethane in a mixture of water and one or more organic solvents, at least one kind of which is the solvent compatible with water, includes no olefinically double bond, has

公开(公告)号：JPH1088041A

公开(公告)日：1998-04-07

申请号：JP23077397

申请日：1997-08-27

Applicant: BASF AG

Inventor： KOKEL NICOLAS DR ,  RAU MARIA GYOPAR DR

IPC: C09D5/00 ,  C08G18/08 ,  C08G18/83 ,  C08G63/20 ,  C09D7/12 ,  C09D201/08

Abstract: PROBLEM TO BE SOLVED: To provide an aqueous coating material which not only has excellent storage stability, but also is little poisonous, and further has high flexibility in making its formulation, by using an organic polymer having free and/or neutralized acid groups present in an aqueous solution or an aqueous dispersion together with a specific crosslinking agent. SOLUTION: This aqueous coating material comprises (a) an organic polymer having free and/or neutralized acid groups being present in an aqueous solution or an aqueous dispersion, and (b) a crosslinking agent which has a structure represented by the formula (wherein each of R1 to R4 is H, or an alkyl, an aryl or an aralkyl each having 1 to 24 carbon atoms; X is oxygen, sulfur or-N(R5 )-; R5 is an alkyl, an aryl or an aralkyl each having 1 to 24 carbon atoms; Z is an n-functional arkyl, aryl, or aralkyl; n is a number of at least 2, and which has a molar mass of 10,000 or less).

公开(公告)号：DE19618675A1

公开(公告)日：1997-03-27

申请号：DE19618675

申请日：1996-05-09

Applicant: BASF AG

Inventor： KOKEL NICOLAS DR ,  RAU MARIA GYOPAR DR ,  ETTL ROLAND DR ,  LARBIG HARALD DR ,  MELDER JOHANN-PETER DR ,  GULBINS ERICH DR

IPC: C08G18/08 ,  C08G18/12 ,  C08G18/38 ,  C08G18/50 ,  C08G18/83 ,  C14C11/00 ,  C08G18/10 ,  C08G18/32 ,  C08G18/34 ,  C08G18/42 ,  C08G18/66 ,  C08G63/685 ,  C08J5/12 ,  C08J7/16 ,  C09D175/04 ,  C09J175/04

Abstract: The invention concerns aqueous dispersions containing a polyurethane (A), containing structural units derived from compounds of formula (I), in which the substituents have the following meanings: R , R , R each designate hydrogen, C1-C24 alkyl or C6 - C24 alkenyl; R designates hydrogen; R , R a) together designate C4-C10 alkane-diyl, b) each designate C2-C10 alkyl, C5-C8 cycloalkyl or C7-C20 aralkyl, c) each designate a hydroxyl-terminated poly(C2-C4 alkylene oxide), or d) designate an R or R group with the meaning given in (a) to (c) and the other group designating hydrogen or a group of formula (II), in which X designates C2-C6 alkane-diyl; and R has the same meaning as R or R with the exception that R is not a group of formula II, R and R carrying a total of between 2 and 5 hydroxyl groups bonded to aliphatic carbon atoms; and R and/or R optionally carrying 1 or 2 aromatically bonded hydroxyl groups or 1 nitrile, tertiary amino, carboxylic acid or sulphonic acid group which are optionally present in the form of their salts.

公开(公告)号：ES2142642T3

公开(公告)日：2000-04-16

申请号：ES97107492

申请日：1997-05-07

Applicant: BASF AG

Inventor： LICHT ULRIKE DR ,  KOKEL NICOLAS DR ,  HABERLE KARL DR ,  ANGEL MAXIMILIAN DR ,  WEYLAND PETER DR ,  SCHERR GUNTER DR

IPC: C08L75/14 ,  C08G18/08 ,  C08G18/67 ,  C08G73/04 ,  C09D175/14 ,  C09J175/14

Abstract: Latent hardening aqueous polyurethane dispersions contain (1) a disperse phase (P.1) containing (1a) a polyurethane (PUR.1a) containing groups (G-1) imparting dispersibility in water and groups (G-2) with a carbon-carbon (C-C) double bond activated by a carbonyl group bound directly to this or (1b) a mixture of a polyurethane (PUR.1b) containing G-1 groups but not G-2 groups and a compound (I) containing G-2 groups, other than PUR.1a and PUR.1b; and (2) a compound (II) which contains an average of NOTLESS 2 hydrogen (H) atoms as amino function, has a water solubility > 1 g/l (25 degrees C) and has a number average molecular weight (Mn) of 200-1000000. Also claimed are wood, metal, textile, leather or plastics articles bonded, impregnated or coated with the dispersions.

公开(公告)号：DE19634598A1

公开(公告)日：1998-03-05

申请号：DE19634598

申请日：1996-08-27

Applicant: BASF AG

Inventor： KOKEL NICOLAS DR ,  RAU MARIA GYOPAR DR

IPC: C09D5/00 ,  C08G18/08 ,  C08G18/83 ,  C08G63/20 ,  C09D7/12 ,  C09D201/08 ,  C09D201/02 ,  C09D5/02

Abstract: An aqueous coating composition (CC), contains (a) an organic polymer with free and/or neutralised acid groups, in aqueous solution or dispersion, and (b) a crosslinker of formula (R1-CH(R2)-C(O)-C(R3)(R4)-C(O)-X)n-Z (I) with a molecular weight of less than 10000. In (I), R1-R4 = H and/or 1-24C alkyl, aryl and/or aralkyl; X = -O-, -S- or -NR5-; R5 = H or 1-24C alkyl, aryl or aralkyl; and Z = optionally substituted, n-functional alkyl, aryl or aralkyl group. Also claimed are (i) the production of CC by mixing (a) and (b); (ii) a process for coating substrates by applying composition CC; and (iii) coated objects obtained by process (ii).

公开(公告)号：DE19619636A1

公开(公告)日：1997-11-20

申请号：DE19619636

申请日：1996-05-15

Applicant: BASF AG

Inventor： LICHT ULRIKE DR ,  KOKEL NICOLAS DR ,  HAEBERLE KARL DR ,  ANGEL MAXIMILIAN DR ,  WEYLAND PETER DR ,  SCHERR GUENTER DR

IPC: C08L75/14 ,  C08G18/08 ,  C08G18/67 ,  C08G73/04 ,  C09D175/14 ,  C09J175/14 ,  C08L75/12 ,  C09J175/12 ,  C08J3/24 ,  C08J3/03 ,  C08G18/40 ,  C08G18/65 ,  C08G18/38 ,  C08G18/32

Abstract: Latent hardening aqueous polyurethane dispersions contain (1) a disperse phase (P.1) containing (1a) a polyurethane (PUR.1a) containing groups (G-1) imparting dispersibility in water and groups (G-2) with a carbon-carbon (C-C) double bond activated by a carbonyl group bound directly to this or (1b) a mixture of a polyurethane (PUR.1b) containing G-1 groups but not G-2 groups and a compound (I) containing G-2 groups, other than PUR.1a and PUR.1b; and (2) a compound (II) which contains an average of NOTLESS 2 hydrogen (H) atoms as amino function, has a water solubility > 1 g/l (25 degrees C) and has a number average molecular weight (Mn) of 200-1000000. Also claimed are wood, metal, textile, leather or plastics articles bonded, impregnated or coated with the dispersions.