公开(公告)号：JPH0853446A

公开(公告)日：1996-02-27

申请号：JP33644894

申请日：1994-12-22

Applicant: BASF AG

Inventor： HAMPRECHT GERHARD ,  FUCHS EBERHARD ,  GERBER MATTHIAS ,  WALTER HELMUT ,  WESTPHALEN KARL-OTTO

IPC: A01N43/40 ,  A01N43/90 ,  C07D213/80 ,  C07D471/04 ,  C07D491/04 ,  C07D491/048

公开(公告)号：WO9636592A3

公开(公告)日：1997-01-09

申请号：PCT/EP9601890

申请日：1996-05-07

Applicant: BASF AG ,  FUCHS EBERHARD

Inventor： FUCHS EBERHARD

IPC: C07D213/79 ,  C07B61/00 ,  C07C67/22 ,  C07C69/34 ,  C07C231/06 ,  C07C233/02 ,  C07D213/80 ,  C07D213/803 ,  C07D213/81 ,  C07D213/84 ,  C07D213/82

CPC classification number: C07D213/803 ,  C07C67/22 ,  C07C231/06 ,  C07D213/80 ,  C07D213/81 ,  C07C69/675

Abstract: A process is disclosed for preparing carboxylic acid derivatives having the general formula (I), in which X stands for OR2 or NH¿2, R?1 stands for C¿1?-C20 alkyl, C1-C20 hydroxyalkyl, C3-C12-cycloalkyl, C4-C12 alkyl-cycloalkyl, C4-C12-cycloalkyl-alkyl, C5-C20 alkyl-cycloalkyl-alkyl, aryl, C7-C20 aralkyl, C7-C20 alkylaryl, an heteroaliphatic or heteroaromatic ring with 5 to 8 carbon atoms and R?2¿ stands for C¿1?-C20 alkyl, from carboxylic acid nitriles having the general formula (II) R?1¿-C N, in which R1 has the above-mentioned meanings, and from alcohols having the general formula (III) R2-OH, in which R2 has the above-mentioned meanings. The reaction is carried out in the liquid phase at temperatures from 50 to 300 °C and pressures from 0.1 to 350 bars in the presence of an heterogeneous catalyst.

Abstract translation: PCT No.PCT / EP96 / 01890 Sec。 371日期：1997年11月10日 102（e）日期1997年11月10日PCT提交1996年5月7日PCT公布。 第WO96 / 36592号公报 日期：1996年11月21日制备式I的羧酸衍生物的方法，其中X是OR 2或NH 2，R 1是C 1 -C 20烷基，C 1 -C 20羟烷基，C 3 -C 12环烷基，C 4 -C 12烷基环烷基，C 4 C 12 - 环烷基烷基，C 5 -C 20 - 烷基环烷基烷基，芳基，C 7 -C 20 - 芳烷基，C 7 -C 20烷基芳基，具有5至8个碳原子的杂脂族或杂芳族环，R 2为C 1 -C 20 - 烷基， IIR1-C 3BOND N（II）其中R1具有上述含义，和式IIIR2-OH（III）的醇，其中R2具有上述含义，在50至300℃，0.1至350巴 存在非均相催化剂，其中反应在液相中进行。

公开(公告)号：WO9932429A3

公开(公告)日：1999-08-26

申请号：PCT/EP9808248

申请日：1998-12-16

Applicant: BASF AG ,  FUCHS EBERHARD ,  BREITSCHEIDEL BORIS ,  OHLBACH FRANK ,  STEFFEN FRANK ,  HUNGER JUERGEN

Inventor： FUCHS EBERHARD ,  BREITSCHEIDEL BORIS ,  OHLBACH FRANK ,  STEFFEN FRANK ,  HUNGER JUERGEN

IPC: C07C209/48 ,  C07C211/08 ,  C07C211/34

CPC classification number: C07C209/48 ,  C07C2601/14 ,  C07C211/08 ,  C07C211/34

Abstract: The invention relates to a method for producing amines of general formula (I) X(-CH2-NHR)n in which R independently represents C1-200-alkyl, C3-8-cycloalkyl, C4-20-alkyl cycloalkyl, C4-20-cylcoalkyl alkyl, C2-20-alkoxyalkyl, aryl, C7-20-alkylaryl, C7-20-aryl alkyl, C2-8-hyrodoxyalkyl, C2-8-mercaptoalkyl, C8-20-aryloxyalkyl or jointly represents a saturated or unsaturated C2-6-alkylene chain which is optionally substituted singly to triply by C1-4-alkyl and is optionally interrupted by oxygen or nitrogen. X is a C1-20-alkyl, C2-20-alkenyl or C3-8-cycloalkyl with n free valances optionally substituted by C1-20-alkyl, C3-8-cycloalkyl, C4-20-alkyl cycloalkyl, C4-20-cycloalkyl alkyl, C2-20-alkoxyalkyl, aryl, C7-20-alkylaryl, C7-20-aryl alkyl, C1-20-alkoxy, hydroxy, C1-20-hyrodoxyalkyl, amino, C1-20-alkyl amino, C2-20-dialkyl amino, C2-12-alkenyl amino, C3-8-cycloalkyl amino, aryl amino, diaryl amino, aryl-C1-8-alkyl amino, halogen, mercapto, C2-20-alkenyloxy, C3-8-cycloalkoxy, aryloxy, and C2-8-alkoxycarbonyl, and n is a whole number from 1 to 4. The amines are produced by reacting nitriles of general formula (II) X(-CN)n in which X and n have the above mentioned meanings with primary amines of general formula (III) H2NR in which R has the above mentioned meanings, and with hydrogen at temperatures ranging from 50 to 250 DEG C and pressure ranging from 5 to 350 bar in the presence of a catalyst containing Pd, whereby the catalyst comprises 0.1 to 10 wt. % Pd on a carrier, said wt. % being relative to the total weight of the catalyst.

Abstract translation: 一种制备通式的胺（I）X（CH 2 NHR）n，其中R独立地C1-200烷基，C 3-8环烷基，C 4-20烷基环烷基，C 4-20环烷基烷基，C2过程 20烷氧基烷基，芳基，C7-20烷基芳基，C7-20芳烷基，C2-8羟基烷基，C2-8巯基烷基，C 8-20芳氧基烷基或一起任选地被单取代由C 1-4 - 烷基取代的三取代 饱和或不饱和，任选地被氧或氮C 2-6亚平均X是任选被C 1-20烷基取代的，C 3-8环烷基，C 4-20烷基环烷基，C 4-20环烷基烷基，C 2-20烷氧基烷基中断 芳基，C7-20烷基芳基，C7-20芳烷基，C1-20烷氧基，羟基，C 1-20羟基烷基，氨基，C 1-20烷基氨基，C 2-20二烷基氨基，C 2-12 - 烯基，C3 8环烷基氨基，芳氨基，二芳基氨基，芳基-C 1-8 - 烷基氨基，卤素，巯基，C 2-20链烯氧基，C 3-8 - 环烷氧基，芳氧基，C2-8烷氧羰基取代的C 1-20 - 烷基，C 2-20 - 链烯基或C 3-8 - 环烷基，其中n自由价 并且n是从1到4的整数，通过使通式腈（II）X（-CN）n，其中X和n具有以上给出的含义，与通式的伯胺（III）H 2 NR ，其中R具有上述含义，并在温度为50至5〜350巴的含Pd催化剂的存在下250℃，氢气压力，其中，基于所述催化剂的总重量计所述催化剂为0.1〜10重量 包含.-在支撑％的Pd。

公开(公告)号：MY125884A

公开(公告)日：2006-08-30

申请号：MYPI9801951

申请日：1998-04-30

Applicant: BASF AG

Inventor： FUCHS EBERHARD ,  FISCHER ROLF

IPC: C07D201/08

Abstract: THE DISCLOSURE IS A PROCESS FOR PREPARING CYCLIC LACTAMS OF THE FORMULA 1:WHERE R1 IS HYDROGEN, ALKYL, CYCLOALKYL OR ARYL, AND A IS C3-C12-ALKYLENE UNSUBSTITUTED OR SUBSTITUTED BY 1,2, 3, 4, 5 OR 6 SUBSTITUTUENTS SELECTED INDEPENDENTLY OF ONE ANOTHER FROM THE GROUP CONSISTING OF ALKYL, CYCLOALKYL AND ARYL, BY CONVERSION OF AN W-AMINOCARBONITRILE OF THE FORMULA 2;ER1N -A – CN WHERE R1 AND A ARE EACH AS DEFINED ABOVE, IN THE PRESENCE OF AT LEAST ONE CATALYST, WHICH COMPRISES CONVERTING SAID NITRILE II INTO AN OLIGOMER MIXTURE, AND TREATING WITH SUPERHEATED STEAM.

公开(公告)号：CA2319745C

公开(公告)日：2006-05-09

申请号：CA2319745

申请日：1999-02-02

Applicant: BASF AG

Inventor： MOHRSCHLADT RALF ,  HILDEBRANDT VOLKER ,  FUCHS EBERHARD

IPC: C08G69/04 ,  C08G69/00 ,  C08G69/08 ,  C08G69/16 ,  C08G69/28 ,  C08K3/00 ,  C08K3/011

Abstract: The invention relates to a continuous method for producing a polyamide, comprising the following steps: (1) reaction of at least one aminonitrile with water at a temperature of between 90 and 400 .degree.C and a pressure of between 0.1 and 35 .times. 10 6 Pa in a tubular flow reactor containing a Bronsted acid catalyst selected from a beta zeolite, sheet silicate or titanium dioxide catalyst (2) further reaction of the reaction mixture at a temperature of between 150 and 400 .degree.C and a pressure which is lower than the pressure in step 1, where the temperature and pressure are selected such that a first gaseous phase and a first liquid or first solid phase or a mixture of a first solid and first liquid phase is obtained, and the first gaseous phase is separated; an d (3) addition of the first liquid and/or first solid phase to a gaseous or liquid phase containing water, at a temperature of between 150 and 370 .degree.C and a pressure of between 0.1 and 30 x 10 6 Pa, resulting in a product mixture.

公开(公告)号：FI115906B

公开(公告)日：2005-08-15

申请号：FI965229

申请日：1996-12-27

Applicant: BASF AG

Inventor： FUCHS EBERHARD ,  WITZEL TOM

IPC: C07D201/08

Abstract: Cyclic lactams are prepared by reacting an aminocarboxylic acid compound of the formula I H2N-(CH2)m-COR1 I where R1 is -OH, -O-C1-C12-alkyl or -NR2R3 and R2 and R3, independently of one another, are each hydrogen, C1-C12-alkyl or C5-C8-cycloalkyl and m is an integer from 3 to 12, with water by a process in which the reaction is carried out in the liquid phase using a heterogeneous catalyst.

公开(公告)号：SK284227B6

公开(公告)日：2004-11-03

申请号：SK63697

申请日：1995-11-29

Applicant: BASF AG

Inventor： FUCHS EBERHARD ,  ACHHAMMER GUNTHER

IPC: C07D201/08 ,  C07D223/10

Abstract: Method for preparing caprolactam by heating 6-aminocapric acid nitrile in the presence of heterogeneous catalysts and water under elevated pressure, wherein (a) 6-aminocapric acid nitrile or a mixture containing essentially 6-aminocapric acid nitrile as well as water and a low-boiling or a high-boiling alcohol is heated in the presence of a heterogeneous catalyst in a reactor A to produce a mixture (I); then (b) mixture (I) is distilled, yielding a head fraction, caprolactam and a bottom product, with any ammonia in mixture (I) being removed prior to distillation; and then (c1) the head fraction is fed into the reactor of step (a), with the head fraction optionally being mixed with the alcohol and/or water and/or 6-aminocapric nitrile used in step (a) before being fed into reactor (A); or (c2) the head fraction, optionally with the bottom product from step (b), is fed into a reactor (B), the first fraction optionally being mixed with the alcohol and/or water and/or 6-aminocapric acid nitrile before being fed into reactor (B), and then analogously to step (b) caprolactam is produced by distillation; and either (d1) the bottom product from step (b) is fed into reactor A of step (a); or (d2) optionally water and possibly a low-boiling or a high-boiling alcohol are added to the bottom product which then, analogously to step (a) is heated in a reactor (C) to give a reaction product which is distilled to yield caprolactam; or (d3) water is added to the bottom product which is heated in a reactor (D) without added catalyst to give a reaction product which is distilled to yield caprolactam; or (d4) water and a base are added to the bottom product which is heated in reactor (E) to give a reaction product which is distilled to yield caprolactam.

公开(公告)号：ES2201127T3

公开(公告)日：2004-03-16

申请号：ES95942198

申请日：1995-12-22

Applicant: BASF AG

Inventor： ACHHAMMER GUNTHER ,  BASSLER PETER ,  FISCHER ROLF ,  FUCHS EBERHARD ,  LUYKEN HERMANN ,  SCHNURR WERNER

IPC: C07D201/02 ,  C07C209/48 ,  C07C211/12 ,  C07D201/08 ,  C07D223/10

Abstract: The invention concerns the simultaneous preparation of caprolactam and hexamethylene diamine from adipodinitrile, by the following steps: (a) the adipodinitrile is partially hydrogenated, producing a mixture substantially containing 6-aminocapronitrile, hexamethylene diamine, ammonia, adipodinitrile and hexamethylene imine (= "the mixture"); (b) the mixture obtained in step (a) is distilled, producing ammonia, as the forerunnings, and a residue I, in the presence of a compound A which is inert in the distillation conditions, the ammonia not being separated totally; (c) the residue I, substantially containing "the mixture", inert compound A and ammonia, the ammonia content being less than that of the mixture used in step (b), is subjected to a second distillation, producing a mixture of the inert compound A and ammonia, as the forerunnings, and a residue II; (d) the base II, substantially containing "the mixture" and inert compound A, is subjected to distillation in a third column, producing the inert compound A, as the forerunnings, and a residue III; (e) the base III, substantially containing "the mixture" and optionally an inert compound B, is subjected to distillation in a fourth column, producing forerunnings KP1, which substantially contain hexamethylene imine, optionally inert compound B and hexamethylene diamine, and a residue IV; (f) the forerunnings KP1 are subjected in a fifth column to distillation, producing forerunnings KP2, which substantially contain hexamethylene imine and optionally inert compound B, and a residue V, which substantially contains hexamethylene diamine with a degree of purity of at least 95 %, the forerunnings KP2 being fed to the third column or optionally only partially fed to the third column, and the rest being discarded; and (g) the residue IV, substantially containing 6-aminocapronitrile and adipodinitrile, is subjected in a sixth column to distillation, producing 6-aminocapronitrile with a degree of purity of at least 95 %, as forerunnings, and adiponitrile in the residue. The resultant 6-aminocapronitrile is cyclized to form caprolactam.

公开(公告)号：CA2176741C

公开(公告)日：2004-02-03

申请号：CA2176741

申请日：1994-11-15

Applicant: BASF AG

Inventor： FUCHS EBERHARD ,  WITZEL TOM

IPC: C07D223/10 ,  C07D201/08

Abstract: A process is proposed for manufacturing cyclic lactams by allowing aminocarbozyGc acid nitrites to react with water. This is done in the liquid phase in the presence of heterogeneous catalysts based ou ntanium dioxide, zirconium ozide, cerium oxide and aluminium oxide.

公开(公告)号：PL186443B1

公开(公告)日：2004-01-30

申请号：PL32116295

申请日：1995-12-22

Applicant: BASF AG

Inventor： RITZ JOSEF ,  FISCHER ROLF ,  SCHNURR WERNER ,  ACHHAMMER GUENTHER ,  LUYKEN HERMANN ,  FUCHS EBERHARD

IPC: C07D201/08 ,  C07B63/02 ,  C07D201/16

Abstract: Crude capronitrile is purified by hydrogenation, subsequent treatment in an acidic medium and subsequent distillation in an alkaline medium, by a process in which (a) 6-aminocapronitrile is converted into crude caprolactam by reaction with water, (b) high boilers and low boilers are separated off from the crude caprolactam from step (a), (c) the crude caprolactam from step (b) is treated with hydrogen at from 50 DEG to 150 DEG C. and from 1.5 to 250 bar in the presence of a hydrogenation catalyst and, if desired, of a solvent to give a mixture A, (d1) mixture A in a solvent is passed, at from 30 DEG to 80 DEG C. and from 1 to 5 bar, over an ion exchanger containing terminal acid groups to give a mixture B1, or (d2) mixture A is distilled in the presence of sulfuric acid, any solvent present being removed before the addition of the sulfuric acid, to give a mixture B2, and (e) mixture B1 or mixture B2 is distilled in the presence of a base to give pure caprolactam.