公开(公告)号：DE3676875D1

公开(公告)日：1991-02-21

申请号：DE3676875

申请日：1986-04-11

Applicant: BASF AG

Inventor： HARTIG JUERGEN DR ,  STOESSEL ARMIN DR ,  LUCAS EKHART DR

IPC: C07C27/12 ,  C07C27/00 ,  C07C27/26 ,  C07C29/132 ,  C07C29/50 ,  C07C35/08 ,  C07C45/00 ,  C07C45/33 ,  C07C45/53 ,  C07C45/80 ,  C07C45/82 ,  C07C49/403 ,  C07C67/00 ,  C07C407/00 ,  C07C409/06 ,  C07C409/14

Abstract: Reaction mixtures which contain cyclohexanol, cyclohexanone and cyclohexyl hydroperoxide and are obtained in the oxidation of cyclohexane with molecular oxygen, or with a gas containing this, in the liquid phase are worked up by a process in which the reaction mixture is hydrogenated in the presence of a noble metal catalyst at elevated temperatures and under superatmospheric pressure, the resulting mixture is treated with an aqueous alkali metal carbonate solution, and cyclohexanol and cyclohexanone are separated off by distillation.

公开(公告)号：DE2860624D1

公开(公告)日：1981-05-07

申请号：DE2860624

申请日：1978-10-05

Applicant: BASF AG

Inventor： WEITZ HANS-MARTIN DR ,  HARTIG JUERGEN DR ,  SCHNABEL ROLF DR

IPC: C07C69/16 ,  B01J23/00 ,  B01J23/40 ,  B01J27/00 ,  C07B61/00 ,  C07C67/05

公开(公告)号：CH596133A5

公开(公告)日：1978-02-28

申请号：CH447075

申请日：1975-04-08

Applicant: BASF AG

Inventor： WEITZ HANS-MARTIN DR ,  HARTIG JUERGEN DR ,  VOGEL LUDWIG DIPL ING ,  HETZEL ECKHART DIPL ING

IPC: C07C69/16 ,  B01J23/00 ,  B01J23/644 ,  B01J27/00 ,  B01J27/057 ,  C07B61/00

公开(公告)号：DE3328771A1

公开(公告)日：1985-02-28

申请号：DE3328771

申请日：1983-08-10

Applicant: BASF AG

Inventor： HARTIG JUERGEN DR ,  SCHUCH GUNTER DR ,  STOESSEL ARMIN DR ,  HERRMANN GUENTER DR ,  BRUNNER ARTHUR ,  ZEHNER PETER DR ,  GROSSKINSKY OTTO-ALFRED DR

IPC: C07C27/12 ,  C07C27/00 ,  C07C29/50 ,  C07C35/08 ,  C07C45/33 ,  C07C49/403 ,  C07C51/16 ,  C07C51/215 ,  C07C51/265 ,  C07C67/00

Abstract: Oxygen-containing compounds are prepared by oxidizing a hydrocarbon in the liquid phase with a gas containing molecular oxygen, at elevated temperatures and under superatmospheric pressure, by a continuous process in which the said gas is fed into the liquid reaction mixture, in a downward direction, at several points along the reaction zone via nozzle apertures, so that it emerges at each nozzle aperture with a velocity of from 0.01 to 1 m/sec in an amount of from 0.001 to 10 liters per second per nozzle aperture, and the said reaction mixture is brought into substantially uniform contact with the gas containing molecular oxygen, over the volume of the reaction zone.

公开(公告)号：DE3060081D1

公开(公告)日：1982-01-28

申请号：DE3060081

申请日：1980-01-02

Applicant: BASF AG

Inventor： PLATZ ROLF DR ,  HARTIG JUERGEN DR ,  WEITZ HANS-MARTIN DR

IPC: C07C67/05 ,  C07C67/48 ,  C07C67/54 ,  C07C67/56 ,  C07C69/16

公开(公告)号：DE2960385D1

公开(公告)日：1981-09-03

申请号：DE2960385

申请日：1979-04-27

Applicant: BASF AG

Inventor： WEITZ HANS-MARTIN DR ,  HARTIG JUERGEN DR ,  MAROSI LASZLO DR

IPC: C07C67/05 ,  B01J23/10 ,  B01J23/16 ,  B01J23/44 ,  B01J23/52 ,  B01J23/70 ,  B01J23/84 ,  B01J23/89 ,  B01J27/02 ,  C07C67/055 ,  C07C69/16

Abstract: Diesters of olefinically unsaturated 1,2- and/or 1,4-diols are prepared by reacting a conjugated diolefin, oxygen and a fatty acid, in the gas phase or liquid phase, over a solid catalyst which contains palladium and/or platinum and a further metal, which has an atomic number of from 21 to 30, from 39 to 48 or from 57 to 80, but is not a platinum metal, the catalyst having been obtained by reduction of compounds, applied to a carrier, of platinum and/or palladium and the further metal, and heating at 400 DEG C. or above.

公开(公告)号：ES2012792B3

公开(公告)日：1990-04-16

申请号：ES87115415

申请日：1987-10-21

Applicant: BASF AG

Inventor： NEUBAUER GERALD ,  SCHNABEL ROLF ,  RITZ JOSEF ,  HARTIG JUERGEN DR

IPC: C07C27/00 ,  B01J21/06 ,  B01J23/16 ,  B01J23/44 ,  C07B61/00 ,  C07C29/132 ,  C07C29/88 ,  C07C35/08 ,  C07C45/00 ,  C07C45/33 ,  C07C45/53 ,  C07C49/403 ,  C07C67/00

公开(公告)号：DE3700336A1

公开(公告)日：1988-07-21

申请号：DE3700336

申请日：1987-01-08

Applicant: BASF AG

Inventor： NEUBAUER GERALD DR ,  SCHNABEL ROLF DR ,  RITZ JOSEF DR ,  HARTIG JUERGEN DR

IPC: C07C29/132 ,  C07C29/88 ,  C07C35/08 ,  C07C29/50 ,  C07C49/403

Abstract: A further embodiment of the method for processing reaction mixtures which contain cyclohexyl hydrogen peroxide which have been obtained by oxidising cyclohexane using molecular oxygen, or gases containing molecular oxygen, in the liquid phase at a temperature of 130 to 200@C under a pressure of 5 to 125 bar, by reacting cycloolefins at elevated temperature in the presence of catalysts, cyclohexyl hydrogen peroxide being reacted with cyclohexene at elevated temperature in the presence of compounds of transition metals of group 4 to 6 of the Periodic Table which are soluble in cyclohexane, then hydrogenating the cyclohexene oxide formed in a manner known per se in the presence of hydrogenation catalysts at elevated temperature to give cyclohexanol in accordance with Patent ... (Patent Application P 3636056.2), characterised in that the reaction of cyclohexyl hydrogen peroxide with cyclohexene is carried out in the presence of at least one cyclohexane-insoluble compound of a transition metal of group 4 to 6, selenium, tellurium or a boride.

公开(公告)号：DE3513568A1

公开(公告)日：1986-10-16

申请号：DE3513568

申请日：1985-04-16

Applicant: BASF AG

Inventor： HARTIG JUERGEN DR ,  STOESSEL ARMIN DR ,  LUCAS EKHART DR

IPC: C07C27/12 ,  C07C27/00 ,  C07C27/26 ,  C07C29/132 ,  C07C29/50 ,  C07C35/08 ,  C07C45/00 ,  C07C45/33 ,  C07C45/53 ,  C07C45/80 ,  C07C45/82 ,  C07C49/403 ,  C07C67/00 ,  C07C407/00 ,  C07C409/06 ,  C07C409/14

Abstract: Reaction mixtures which contain cyclohexanol, cyclohexanone and cyclohexyl hydroperoxide and are obtained in the oxidation of cyclohexane with molecular oxygen, or with a gas containing this, in the liquid phase are worked up by a process in which the reaction mixture is hydrogenated in the presence of a noble metal catalyst at elevated temperatures and under superatmospheric pressure, the resulting mixture is treated with an aqueous alkali metal carbonate solution, and cyclohexanol and cyclohexanone are separated off by distillation.

公开(公告)号：DE3763474D1

公开(公告)日：1990-08-09

申请号：DE3763474

申请日：1987-01-13

Applicant: BASF AG

Inventor： HARTIG JUERGEN DR ,  HERRMANN GUENTER DR ,  LUCAS EKHART DR

IPC: C07C49/403 ,  B01J31/00 ,  B01J31/18 ,  B01J31/26 ,  C07C27/00 ,  C07C27/12 ,  C07C27/26 ,  C07C29/50 ,  C07C35/08 ,  C07C45/00 ,  C07C45/33 ,  C07C45/53 ,  C07C45/78 ,  C07C45/80 ,  C07C67/00 ,  C07C409/06

Abstract: Reaction mixtures which contain cyclohexyl hydroperoxide, cyclohexanol and cyclohexanone and are obtained by oxidizing cyclohexane with molecular oxygen, or a gas containing this, in the liquid phase at from 130 DEG to 200 DEG C. under from 5 to 25 bar are worked up by treatment with an aqueous alkali solution in the presence of a cobalt salt at elevated temperatures by an improved process wherein a phosphonic acid compound of the formula I where X is alkylene or 2 to 6 carbon atoms, R1 is -CH2PO3H and R2, R3 and R4 may be identical or different and are each -CH2PO3H, -CH2OH, hydrogen or alkyl of 1 to 4 carbon atoms, is concomitantly used.