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公开(公告)号:DE3004652A1
公开(公告)日:1981-08-13
申请号:DE3004652
申请日:1980-02-08
Applicant: BASF AG
Inventor: HANSEN GUENTER DIPL CHEM DR , KERMER WOLF-DIETER DIPL CHEM D , STUCK JOCHEN-WILFRIED ING GRAD
Abstract: Dye mixtures, containing dyes of the formula I I where X is hydrogen, chlorine or bromine, R1 is hydrogen, methoxy, ethoxy or phenoxy, R2 is hydrogen, methyl, ethyl, n-propyl or iso-propyl and R is where R3 is allyl, methallyl, crotonyl, prenyl or benzyl, R4 is C1-C5-alkyl, allyl, methallyl, crotonyl, prenyl or benzyl and R4 is C1-C5-alkyl, the mixtures containing not less than 60% of dyes wherein R is or NHC2H4CN, from 0 to 40% of one or more dyes wherein R is and from 0 to 40% of one or more dyes wherein R is the two last-mentioned components accounting for not less than 5% of the mixture. The mixtures are exceptionally useful for dyeing polyesters.
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公开(公告)号:DE2849471A1
公开(公告)日:1980-06-04
申请号:DE2849471
申请日:1978-11-15
Applicant: BASF AG
Abstract: An azo dye comprising a heterocyclic diazo component, of the general formula I where D is a radical of the formula Y is nitro, chlorine or bromine, Z is hydrogen, chlorine, bromine, cyano or nitro, R1 is C1-C4-alkyl which is unsubstituted or substituted by hydroxyl, C1-C4-alkoxy, cyano, C1-C4-alkanoyloxy, C1-C4-alkoxycarbonyl, C1-C4-alkanoylamino, C1-C4-alkylaminocarbonyloxy, C1-C4-alkoxycarbonyloxy, chlorine, phenyl and/or phenoxy, or is cyclohexyl, propargyl or C3-C5-alkenyl, or is a radical of the formula (A-O)n-R2, R2 is C1-C4-alkyl, phenyl or, if n>1, may also be hydrogen, R3 is C1-C8-alkyl, which may be substituted by phenyl or phenoxy, R4 is hydrogen, methyl, ethyl, methoxy, ethoxy or phenoxy, X is oxygen or a direct bond, A is -CH2CH2-, -CH2CH2CH2-, and n is 1, 2 or 3. The dyes of the formula I are very suitable for dyeing synthetic textile materials, especially polyesters.
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公开(公告)号:DE2415690A1
公开(公告)日:1975-10-23
申请号:DE2415690
申请日:1974-04-01
Applicant: BASF AG
Abstract: The parent patent describes soluble trisazo dyes of formula (I): (in which A is the gp. of an aromatic diazo component; B is the gp. of a coupling component contg. an OH and/or amino gp.; n is 1 or 2; one X is OH and the other NH2; Z is a gp. of formula: R is H, OH, Cl, Br, NO2, CH3, C2H5 or COOH, and R1 is H, Cl, Br, CN, NO2, CH3, C2H5, COOH or alkoxycarbonyl). In this addn. Z is a gp. of formula: (in which R3 is methyl, ethyl, n-propyl, n-butyl, 2-hydroxy-ethyl or -propyl, carboxymethyl or 2-carboxyethyl, benzyl, 2-methoxy-or 2-ethoxy-ethyl or -propyl, 2-chlorethyl or -propyl). Cpds. (I) are used for dyeing cellulose, cotton, regenerated cellulose, wool, silk, nylon, paper or esp. leather, in green to black shades with good fastness.
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公开(公告)号:DE3125869A1
公开(公告)日:1983-01-20
申请号:DE3125869
申请日:1981-07-01
Applicant: BASF AG
Inventor: WEGERLE DIETER DIPL CHEM DR , BAUMGARTE ULRICH DIPL CHEM DR , KERMER WOLF-DIETER DIPL CHEM D , KRALLMANN REINHOLD ING GRAD , WEBER HANS ING GRAD
Abstract: The invention relates to a process for dyeing and/or printing cellulose fibres in the presence of swelling agents, characterised in that the cellulose fibres are treated with a padding liquor or print paste and the dye is fixed at temperatures
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7.
公开(公告)号:DE2748978A1
公开(公告)日:1979-05-03
申请号:DE2748978
申请日:1977-11-02
Applicant: BASF AG
Inventor: DIMMLER MANFRED DIPL CHEM DR , EILINGSFELD HEINZ DIPL CHEM DR , HANSEN GUENTER DIPL CHEM DR , KERMER WOLF-DIETER DIPL CHEM D
IPC: C09B29/01 , C09B29/08 , C09B29/32 , C09B29/33 , C09B29/40 , C09B29/44 , C09B29/46 , C09B29/52 , C09B29/36
Abstract: Monoazo dyes of formula (I) are new. In (I), K is the residue of a coupler; R is phenylthio or phenylsulphonyl opt. substd. by Cl, Br, CH3, CH3O, C2H5O, NO2 or SO3H; X = H, CL, Br or Cn. Pref. K has formula (II) In (II), R1 = h, CH3, CH3O or C2H5O. R2 is H, Cl, CH3, CH3O or 1-4C alkanoylamino. R3 = H, opt. substd. 1-4C alkyl, allyl, benzyl, phenethyl, cyclohexyl, phenyl or propargyl. R4 = opt. substd. 1-4C alkyl, allyl or propargyl. (I) are made by coupling a diazotised 2,4-dinitroaniline to HK. Used for dyeing or printing textiles, esp. polyester when no water-solubilising gps. are present.
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公开(公告)号:DE3142609A1
公开(公告)日:1983-05-05
申请号:DE3142609
申请日:1981-10-28
Applicant: BASF AG
Inventor: BERGMANN UDO DIPL ING DR , DEGEN HELMUT , HANSEN GUENTER DIPL CHEM DR , KRALLMANN REINHOLD DIPL ING , KERMER WOLF-DIETER DIPL CHEM D
IPC: C09B29/08 , C09B29/085 , C09B67/22 , D06P3/54 , C09B67/38
Abstract: Navy mixtures which contain dyes of the formula I I where X is chlorine or bromine, Y is hydrogen, methoxy or ethoxy and R is N(C2H5)2, N(CH2CH=CH2)2 or N(C2H4OCOCH3)2, the mixtures being composed of 10-70% of dyes with Y=H and R=N(C2H5)2, 5-40% of dyes with Y=OCH3 or OC2H5 and R=N(CH2-CH=CH2)2 and 5-80% of dyes with Y=OCH3 or OC2H5 and R=N(C2H4OCOCH3)2. The novel mixtures have excellent tinctorial properties and give very fast dyeings on synthetic polyesters.
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公开(公告)号:DE3117366A1
公开(公告)日:1982-11-18
申请号:DE3117366
申请日:1981-05-02
Applicant: BASF AG
Inventor: BERGMANN UDO DIPL ING DR , DEGEN HELMUT , HANSEN GUENTER DIPL CHEM DR , KRALLMANN REINHOLD ING GRAD , KERMER WOLF-DIETER DIPL CHEM D
Abstract: Navy dye mixtures which contain, as essential components, compounds of the general formula I I where X is chlorine or bromine, Y is methoxy or ethoxy, and R is NHC2H4CN, NHCH2CH=CH2 or N(C2H4OCOCH3)2, and wherein the dye of the above formula where X is Br, Y is OCH3 or OC2H5 and R is N(C2H4OCOCH3)2 is present in an amount of 25-45%, based on the total weight of the mixture, are very useful for dyeing synthetic polyesters.
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10.
公开(公告)号:DE2752941A1
公开(公告)日:1979-05-31
申请号:DE2752941
申请日:1977-11-26
Applicant: BASF AG
IPC: C09B29/08 , C09B31/043 , C09B39/00
Abstract: New monoazo dyes are of formula (I). In (I) D is the gp. of a diazo component; R1 is H, Cl, Br, 1-2C alkyl or alkoxy; R2 is as R1, 1-4C alkyl-sulphonyl amino, -alkanoyl amino or -alkoxycarbonyl amino, phenyl sulphoxyl amino or benzoylamino; A1 is a substd. aliphatic or araliphatic gp.; A2 is 2-6C alkylene opt. interrupted by O; A3 is 2-4C alkylene; A4 is 1-4C alkyl; n is 1, 2 or 3. Used as dispersion dyes for hydrophobic fibres, e.g. cellulose acetates, polyamides, and esp. polyesters, and in some cases for use in the process claimed in DT1811796. Good fastness to light, wet treatments and thermofixing is achieved.
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