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    PROCESS FOR PRODUCING OF CATALYST FOR ALPHA-OLEFIN POLYMERIZATION AND FOR POLYMERIZATION OF ALPHA-OLEFIN
    1.
    发明专利
    PROCESS FOR PRODUCING OF CATALYST FOR ALPHA-OLEFIN POLYMERIZATION AND FOR POLYMERIZATION OF ALPHA-OLEFIN 未知

    公开(公告)号：HUT65998A

    公开(公告)日：1994-08-29

    申请号：HU9302677

    申请日：1993-09-22

    Applicant: BASF AG

    Inventor： SAIVE ROLAND ,  FUNK GUIDO ,  FOLLMER GODOFREDO ,  MUELLER HANS-JOACHIM ,  KONRAD RAINER ,  LUX MARTIN ,  GOERTZ HANS-HELMUT

    IPC: C08F4/02 ,  C08F4/22 ,  C08F4/24 ,  C08F10/00

    Abstract: Process for the preparation of a supported catalyst for the polymerisation of alpha -olefins, in which (1) a support gel containing silicon dioxide is prepared by (1.1) introducing a sodium or potassium waterglass solution into a rotating stream of an aqueous mineral acid both longitudinally and tangentially to the stream, spraying the silicic acid hydrosol thus formed in droplet form into a gaseous medium, allowing it to solidify into a hydrogel and freeing the hydrogel thus obtained of salt by washing without prior aging, (1.2) drying the hydrogel resulting from (1.1) to form the support gel, and (2) the support gel (1) is loaded with chromium trioxide or a chromium compound which can be converted into chromium trioxide under the conditions of the process step (3), which results in a chromium-containing support gel, and (3) the chromium-containing support gel (2) is heated in an anhydrous gas stream containing oxygen in a concentration of over 10% by volume for from 10 to 1000 minutes at from 400 to 1100 DEG C, the hydrogel resulting from the process step (1.1) being dried in the process step (1.2) over a time of not more than 60 seconds in a shaping flash dryer at an inlet temperature of from 80 to 400 DEG C .

    PROCESS FOR PRODUCING CARRYING CATALIST USED IN POLYMERIZATION OF ALPHA-OLEFINES
    3.
    发明专利
    PROCESS FOR PRODUCING CARRYING CATALIST USED IN POLYMERIZATION OF ALPHA-OLEFINES 未知

    公开(公告)号：HU9302677D0

    公开(公告)日：1993-12-28

    申请号：HU9302677

    申请日：1993-09-22

    Applicant: BASF AG

    Inventor： MUELLER HANS-JOACHIM ,  FOLLMER GODOFREDO ,  KONRAD RAINER ,  SAIVE ROLAND ,  LUX MARTIN ,  GOERTZ HANS-HELMUT ,  FUNK GUIDO

    IPC: C08F4/02 ,  C08F4/22 ,  C08F4/24 ,  C08F10/00

    Abstract: Process for the preparation of a supported catalyst for the polymerisation of alpha -olefins, in which (1) a support gel containing silicon dioxide is prepared by (1.1) introducing a sodium or potassium waterglass solution into a rotating stream of an aqueous mineral acid both longitudinally and tangentially to the stream, spraying the silicic acid hydrosol thus formed in droplet form into a gaseous medium, allowing it to solidify into a hydrogel and freeing the hydrogel thus obtained of salt by washing without prior aging, (1.2) drying the hydrogel resulting from (1.1) to form the support gel, and (2) the support gel (1) is loaded with chromium trioxide or a chromium compound which can be converted into chromium trioxide under the conditions of the process step (3), which results in a chromium-containing support gel, and (3) the chromium-containing support gel (2) is heated in an anhydrous gas stream containing oxygen in a concentration of over 10% by volume for from 10 to 1000 minutes at from 400 to 1100 DEG C, the hydrogel resulting from the process step (1.1) being dried in the process step (1.2) over a time of not more than 60 seconds in a shaping flash dryer at an inlet temperature of from 80 to 400 DEG C .

    5.
    发明专利
    未知

    公开(公告)号：FI922990A0

    公开(公告)日：1992-06-26

    申请号：FI922990

    申请日：1992-06-26

    Applicant: BASF AG

    Inventor： MUELLER HANS-JOACHIM ,  KONRAD RAINER ,  SCHWEIER GUENTHER ,  WEBER SIEGFRIED ,  SAIVE ROLAND ,  KOELLE PETER

    IPC: C08F4/02 ,  C08F4/24 ,  C08F4/60 ,  C08F4/69 ,  C08F10/00 ,  C08F10/02 ,  C08F

    Abstract: A novel Phillips catalyst for the homopolymerisation of ethylene and the copolymerisation of ethylene with alpha -olefins contains, as catalytically active components, a specific aluminium phosphate-supported chromium catalyst and cocatalysts of the general formulae I to IV MR M R2 M R 3-nXn MM RR@ (I) (II) (III) (IV> in which the index and variables have the following meanings: M is lithium, sodium or potassium, M is magnesium or zinc, M is boron or aluminium, R is C1- to C10-alkyl or C6- to C20-aryl, R is R or C1- to C10-alkoxy or C6- to C20-aryloxy, X is chlorine, bromine or iodine, N is 0, 1 or 2. The aluminium phosphate-supported chromium catalyst is obtainable by applying chromium compounds to a finely divided aluminium phosphate having a P:Al molar ratio of close or equal to 1 and a pore volume of > 1 cm /g, and activating the resulting intermediate at elevated temperatures in an oxidising atmosphere. The novel Phillips catalyst has an extremely long mean service life, and its productivity can be further increased by adding hydrogen.

    6.
    发明专利
    未知

    公开(公告)号：DE3634534A1

    公开(公告)日：1988-04-14

    申请号：DE3634534

    申请日：1986-10-10

    Applicant: BASF AG

    Inventor： KONRAD RAINER ,  HEMMERICH RAINER ,  MUELLER-MALL RUDOLF ,  SCHWEIER GUENTHER

    IPC: C08F4/02 ,  C08F4/24 ,  C08F4/48 ,  C08F4/62 ,  C08F10/02

    Abstract: Ethene homopolymers and ethene copolymers with minor amounts of higher alpha -monoolefins are prepared by polymerization of the monomer or monomers using a chromium trioxide catalyst which is obtained by a method in which (1) a finely divided, porous, silicate carrier is laden with (2) chromium trioxide or a chromium compound which is converted to chromium trioxide under the conditions of stage (3), and then (3) the intermediate resulting from stage (2) is heated in an oxygen-containing gas stream. In this process, a cocatalyst which consists of a lithiumalkyl used in addition to the chromium trioxide catalyst.

    8.
    发明专利
    未知

    公开(公告)号：NO942828L

    公开(公告)日：1995-02-01

    申请号：NO942828

    申请日：1994-07-29

    Applicant: BASF AG

    Inventor： LUX MARTIN ,  FUNK GUIDO ,  SAIVE ROLAND ,  GOERTZ HANS-HELMUT ,  KONRAD RAINER

    IPC: C09K3/16 ,  C08F2/34 ,  C08F2/44 ,  C08F10/00 ,  C08F10/02 ,  C08F110/02 ,  C08K5/17 ,  C08K5/20 ,  C08L23/02

    Abstract: A process for the preparation of homopolymers of ethylene or copolymers of ethylene with secondary amounts of other C3- to C12-alk-1-enes by catalytic polymerisation in a suspension or in the gas phase in the presence of an antistatic at a temperature of from 50 to 120 DEG C and at a pressure of from 5 to 50 bar, characterised in that the antistatic employed is a mixture of the following substances: a) a metal salt of medialanic acid of formula (I) , b) a metal salt of an anthranilic acid of formula (II) , where the organic radical R is either alpha ) -CO-(CH2)x-CH3 (III alpha ) or ss) -CO-(CH2)y-CH=CH-(CH2)z-CH3 (IIIss), where x, y and z are each an integer, and x is in the range from 6 to 18, y is in the range from 1 to 16, z is in the range from 1 to 16 and y + z is in the range from 4 to 17, and c) a polyamine obtainable by reacting epichlorohydrin with an aliphatic primary monoamine or an N-alkylalkylenediamine of the formula (IV> R NH-R -NH2 (IV), where R is a C8-C24-alkyl radical and R is a C2-C6-alkylene radical. d

    9.
    发明专利
    未知

    公开(公告)号：FI943522A

    公开(公告)日：1995-02-01

    申请号：FI943522

    申请日：1994-07-27

    Applicant: BASF AG

    Inventor： LUX MARTIN ,  FUNK GUIDO ,  SAIVE ROLAND ,  GOERTZ HANS-HELMUT ,  KONRAD RAINER

    IPC: C09K3/16 ,  C08F2/34 ,  C08F2/44 ,  C08F10/00 ,  C08F10/02 ,  C08F110/02 ,  C08K5/17 ,  C08K5/20 ,  C08L23/02 ,  C08F210/16

    Abstract: A process for the preparation of homopolymers of ethylene or copolymers of ethylene with secondary amounts of other C3- to C12-alk-1-enes by catalytic polymerisation in a suspension or in the gas phase in the presence of an antistatic at a temperature of from 50 to 120 DEG C and at a pressure of from 5 to 50 bar, characterised in that the antistatic employed is a mixture of the following substances: a) a metal salt of medialanic acid of formula (I) , b) a metal salt of an anthranilic acid of formula (II) , where the organic radical R is either alpha ) -CO-(CH2)x-CH3 (III alpha ) or ss) -CO-(CH2)y-CH=CH-(CH2)z-CH3 (IIIss), where x, y and z are each an integer, and x is in the range from 6 to 18, y is in the range from 1 to 16, z is in the range from 1 to 16 and y + z is in the range from 4 to 17, and c) a polyamine obtainable by reacting epichlorohydrin with an aliphatic primary monoamine or an N-alkylalkylenediamine of the formula (IV> R NH-R -NH2 (IV), where R is a C8-C24-alkyl radical and R is a C2-C6-alkylene radical. d

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