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    SUBSTITUTED PYRAZOLE-3-YL BENZAZOLES
    1.
    发明申请
    SUBSTITUTED PYRAZOLE-3-YL BENZAZOLES 审中-公开
    取代的吡唑-3- YLBENZAZOLE

    公开(公告)号：WO9827090A3

    公开(公告)日：1998-09-17

    申请号：PCT/EP9706715

    申请日：1997-12-01

    Applicant: BASF AG ,  ZAGAR CYRILL ,  HAMPRECHT GERHARD ,  MENGES MARKUS ,  MENKE OLAF ,  SCHAEFER PETER ,  WESTPHALEN KARL-OTTO ,  MISSLITZ ULF ,  WALTER HELMUT

    Inventor： ZAGAR CYRILL ,  HAMPRECHT GERHARD ,  MENGES MARKUS ,  MENKE OLAF ,  SCHAEFER PETER ,  WESTPHALEN KARL-OTTO ,  MISSLITZ ULF ,  WALTER HELMUT

    IPC: A01N43/56 ,  A01N43/74 ,  C07D413/04 ,  C07D417/04 ,  C07D417/00

    CPC classification number: C07D413/04 ,  A01N43/74 ,  C07D417/04

    Abstract: The invention concerns substituted pyrazole-3-yl benzazoles of formula (I) and salts thereof, in the formula R designating H, C1-C4 alkyl, C1-C4 alkyl halide; R designating CN, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C1-C4-alkylthio, C1-C4-haloalkylthio, C1-C4-alkylsulphinyl, C1-C4-haloalkylsulphinyl, C1-C4-alkylsulphonyl, C1-C4-haloalkylsulphonyl; R = H, CN, NO2, halogen, C1-C4-alkyl, C1-C4-haloalkyl; R designating H, halogen; R designating H, CN, halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy or C1-C4-haloalkoxy; Z designating -N=C(XR )-O- or -N=C(XR )-S-, bonded to alpha by the nitrogen, oxygen or sulphur; X designating a chemical bond, oxygen, sulphur, -S(O)-, -SO2-, -NH- or -N(R ); R , R designating C1-C6-alkyl, C1-C6-haloalkyl, cyano-C1-C4-alkyl, hydroxy-C1-C4-alkyl, C3-C6-alkenyl, cyano-C3-C6-alkenyl, C3-C6-haloalkenyl, C3-C6-alkinyl, cyano-C3-C6-alkinyl, C3-C6-haloalkinyl, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-haloalkoxy-C1-C4-alkyl, C3-C4-alkenyloxy-C1-C4-alkyl, C3-C4-alkinyloxy-C1-C4-alkyl, C3-C8-cycloalkyloxy-C1-C4-alkyl, amino-C1-C4-alkyl, C1-C4-alkylamino-C1-C4-alkyl, di(C1-C4-alkyl)amino-C1-C4-alkyl, C1-C4-alkylthio-C1-C4-alkyl, C1-C4-haloalkylthio-C1-C4-alkyl, C3-C4-alkenylthio- C1-C4-alkyl, C3-C4-alkinylthio-C1-C4-alkyl, C1-C4-alkyl-sulphinyl-C1-C4-alkyl, C1-C4-haloalkylsulphinyl-C1-C4-alkyl, C3-C4-alkenylsulphinyl-C1-C4-alkyl, C3-C4-alkinylsulphinyl-C1-C4-alkyl, C1-C4-alkylsulphonyl-C1-C4-alkyl, C1-C4-haloalkylsulphonyl-C1-C4-alkyl, C3-C4-alkenylsulphonyl-C1-C4-alkyl, C3-C4-alkinylsulphonyl-C1-C4-alkyl, hydroxycarbonyl-C1-C4-alkyl, C1-C4-alkoxycarbonyl-C1-C4-alkyl, which can carry a CN oder C1-C4-alkoxycarbonyl group, C1-C4-alkylthiocarbonyl-C1-C4-alkyl, aminocarbonyl-C1-C4-alkyl, C1-C4-alkylaminocarbonyl-C1-C4-alkyl, di(C1-C4-alkyl)aminocarbonyl-C1-C4-alkyl, di(C1-C4-alkyl)-phosphonyl-C1-C4-alkyl, C1-C4-alkoxyimino-C1-C4-alkyl, C3-C4-alkenyloxyimino-C1-C4-alkyl, optionally substituted C3-C8-cycloalkyl, C3-C8-cycloalkyl-C1-C4-alkyl, phenyl, phenyl-C1-C4-alkyl, 3- to 7-member heterocyclic or heterocyclyl-C1-C4-alkyl, wherein each cycloalkyl ring and each heterocyclyl ring contain a CO or CS ring member; if X is a chemical bond, -O-, -S-, -NH- or -N(R )-, R also being C1-C4 alkylcarbonyl, C1-C4 haloalkylcarbonyl, C1-C4 alkoxycarbonyl, C1-C4 alkylsulphonyl or C1-C4 haloalkylsulphonyl; if X is a chemical bond, R additionally designating CN, SH, NH2, halogen, -CH2-CH(halogen)-R , -CH=CH-R or -CH=C(halogen)-R , R designating COOH, C1-C4 alkoxycarbonyl, C1-C4 alkylthiocarbonyl, CONH2, C1-C4 alkylaminocarbonyl, di(C1-C4 alkyl)aminocarbonyl or di(C1-C4 alkyl)phosphonyl; or R plus R designating an optionally substituted 1,3-propylene, tetramethylene, pentamethylene or ethylene oxyethylene chain. The invention also concerns the use of these substances as herbicides and for the desiccation and/or defoliation of plants. 00000

    Abstract translation: 00000

    SUBSTITUTED 3-BENZYLPYRAZOLES AND THEIR USE AS HERBICIDES AND FOR LOWERING THE SUGAR CONTENT IN BLOOD
    3.
    发明申请
    SUBSTITUTED 3-BENZYLPYRAZOLES AND THEIR USE AS HERBICIDES AND FOR LOWERING THE SUGAR CONTENT IN BLOOD 审中-公开
    取代的3- benzylpyrazoles及其作为除草剂和降低血糖浓度

    公开(公告)号：WO9820000A2

    公开(公告)日：1998-05-14

    申请号：PCT/EP9706057

    申请日：1997-11-03

    Applicant: BASF AG ,  ZAGAR CYRILL ,  HAMPRECHT GERHARD ,  MENGES MARKUS ,  MENKE OLAF ,  SHAEFER PETER ,  WESTPHALEN KARL OTTO ,  MISSLITZ ULF ,  WALTER HELMUT ,  REINHARD ROBERT ,  JONES ROBERT BRIAN

    Inventor： ZAGAR CYRILL ,  HAMPRECHT GERHARD ,  MENGES MARKUS ,  MENKE OLAF ,  SHAEFER PETER ,  WESTPHALEN KARL-OTTO ,  MISSLITZ ULF ,  WALTER HELMUT ,  REINHARD ROBERT ,  JONES ROBERT BRIAN

    IPC: A01N43/56 ,  A61K31/415 ,  A61K31/4152 ,  A61K31/4155 ,  A61K31/454 ,  A61K31/5377 ,  A61P3/10 ,  C07D231/20 ,  C07D401/10 ,  C07D401/12 ,  C07D403/10 ,  C07D403/12 ,  C07D405/12

    CPC classification number: C07D401/10 ,  C07D231/20 ,  C07D401/12 ,  C07D403/10 ,  C07D403/12 ,  C07D405/12

    Abstract: The invention relates to substituted 3-benzylpyrazoles of formula (I), their precursors of formulas (IIa), (IIb), (IIc), their byproducts of formula (III) as well as their salts, wherein R stands for H, C1-C4 alkyl, C1-C4 halogen alkyl, C1-C4 alkyl sulfonyl, C1-C4 halogen alkyl sulfonyl; R stands for C1-C4 alkyl, C1-C4 halogen alkyl, C1-C4 alkoxy, C1-C4 halogen alkoxy, C1-C4 alkyl thio, C1-C4 halogen alkyl thio, C1-C4 alkyl sulfinyl, C1-C4 halogen alkyl sulfinyl, C1-C4 alkyl sulfonyl, C1-C4 halogen alkyl sulfonyl; R stands for H, CN, NO2, halogen, C1-C4 alkyl, C1-C4 halogen alkyl; X -X stands for chemical bond, optionally substituted methylene-, ethylene-, ethene-1,2-diyl or oxymethylene or thiamethylene chain linked through the heteroatom to the phenyl ring; R -R stands for H, CN, NO2, halogen -O-Y -R , -O-CO-Y -R , -N(Y -R ) (Y -R ), -N(Y -R )-SO2-Y -R , -N(SO2-Y -R ) (SO2-Y -R ), -N(Y -R )-CO-Y -R , -N(Y -R ) (O-Y -R ), -S-Y -R , -SO-Y -R , -SO2-Y -R , -SO2-O-Y -R , -SO2-N(Y -R ) (Y -R ), -CO-Y -R , -C(=NOR )-Y -R , -C(=NOR )-O-Y -R , -C(=NOR )-CO-O-Y -R , -CO-O-Y -R , -CO-S-Y -R , -CO-N(Y -R ) (Y -R ), -CO-N(Y -R ) (O-Y -R ); R stands C1-C4 alkyl, C1-C4 halogen alkyl. The invention further relates to the use of (I) as herbicide, for the desiccation/defoliation of plants, and of (I), (IIa), (IIb), (IIc) and (III) for lowering the sugar content in blood.

    Abstract translation: 式的取代的3- benzylpyrazoles（I），它们在Formuln（IIA），（IIB），（IIC）的前体，和式（III）中，副产物和它们的盐，其中R <1> = H，C1-C4烷基 ，C1-C4卤代烷基，C1-C4烷基磺酰基，C1-C4卤代烷基磺酰基; [R <2> = C1-C4烷基，C1-C4卤代烷基，C1-C4烷氧基，C1-C4卤代烷氧基，C1-C4烷硫基，C1-C4卤代烷硫基，C1-C4烷基亚磺酰基，C1-C4 卤代烷，C1-C4烷基磺酰基，C1-C4卤代烷基磺酰基; [R <3> = H，CN，NO 2，卤素，C1-C4烷基，C1-C4卤代烷基; X <1> - X <5> =化学键，任选取代的亚甲基，亚乙基，乙烯-1,2-二基，或通过结合到苯环或甲醛蒂亚姆乙烯链中的杂原子; [R <4> - R的<8> = H，CN，NO 2，卤素，-OY <1> -R <9> -O-CO-Y <1> -R <9> -N（Y <1 > -R <9>）（Y <2> -R <10>）， - N（Y <1> -R <9>） - SO2-Y <2> -R <10>，-N（SO 2 Y'> -R <9>）（SO 2-Y <2> -R <10>）， - N（Y <1> -R <9>） - CO-Y <2> -R <10>， -N（Y <1> -R <9>）（OY <2> -R <10>），-SY <1> -R <9>，-SO-Y <1> -R <9>， - SO2-Y <1> -R <9>，-SO 2 OY <1> -R <9>，-SO2-N（Y <1> -R <9>）（Y <2> -R <10> ）， - CO-Y <1> -R <9>，-C（= NOR <11>） - Y'> -R <9>，-C（= NOR <11>） - OY <1> - [R <9>，-C（= NOR <11>） - CO-OY <1> -R <9> -CO-OY <1> -R <9> -CO-SY <1> -R < 9>，-CO-N（Y <1> -R <9>）（Y <2> -R <10>），-CO-N（Y <1> [R <9>）（OY <2> - [R <10>）; [R <12> = C1-C4烷基，C1-C4卤代烷基; 使用：（Ⅰ）作为除草剂：用于植物干燥/落叶; （I），（IIA），（IIB），（IIC）和（III）用于降低血糖含量。

    ЗАМЕЩЕННЫЕ (4-БРОМПИРАЗОЛ-3-ИЛ)БЕНЗАЗОЛЫ
    4.
    发明专利
    ЗАМЕЩЕННЫЕ (4-БРОМПИРАЗОЛ-3-ИЛ)БЕНЗАЗОЛЫ 未知

    公开(公告)号：EA003590B1

    公开(公告)日：2003-06-26

    申请号：EA200001090

    申请日：1999-04-22

    Applicant: BASF AG

    Inventor： ZAGAR CYRILL ,  HAMPRECHT GERHARD ,  MENGES MARKUS ,  MENKE OLAF ,  REINHARD ROBERT ,  SCHAFER PETER ,  WESPHALEN KARL-OTTO ,  OTTEN MARTINA ,  WALTER HELMUT

    IPC: C07D231/20 ,  A01N43/74 ,  A01N43/76 ,  A01N43/78 ,  C07D231/16 ,  C07D413/04 ,  C07D417/04 ,  C07D417/14 ,  C07F9/6541 ,  C07F9/6558

    Abstract: Замещенные (4-бромпиразол-3-ил)бензазолыформулы Iатакжеихсоли, причемR- Н, C-C-алкил, C-C-галогеналкил;R- CN, C-C-алкил, C-C-галогеналкил, C-C-алкокси, C-C-галогеналкокси, C-C-алкилтио, C-C-галогеналкилтио, C-C-алкилсульфинил, C-C-галогеналкилсульфинил, C-C-алкилсульфонилили C-C-галогеналкилсульфонил;R- H, галоген;R- Н, галоген, CN, C-C-алкил, C-C-галогеналкил, C-C-алкоксиили C-C-галогеналкокси;Z - -N=C(XR)-O- или -N=C(XR)-S-, котораячерезкислород, серуилиазотсвязанас α;Хозначаетхимическуюсвязь, кислород, серу, группу -S(O)-, -SO-, -NH- или -N(R)-;R, R- C-C-алкил, C-C-галогеналкил, циано-C-C-алкил, гидрокси-C-C-алкил, C-C-алкенил, циано-C-C-алкенил, C-C-галогеналкенил, C-C-алкинил, циано-C-C-алкинил, C-C-галогеналкинил, C-C-алкокси-C-C-алкил, C-C-галогеналкокси-C-C-алкил, C-C-алкенилокси-C-C-алкил, C-C-алкинилокси-C-C-алкил, C-C-циклоалкилокси-C-C-алкил, амино-C-C-алкил, C-C-алкиламино-C-C-алкил, ди(C-C-алкил)амино-C-C-алкил, C-C-алкилтио-C-C-алкил, C-C-галогеналкилтио-C-C-алкил, C-C-алкенилтио-C-C-алкил, C-C-алкинилтио-C-C-алкил, C-C-алкилсульфинил-C-C-алкил, C-C-галогеналкилсульфинил-C-C-алкил, C-C-алкенилсульфинил-C-C-алкил, C-C-алкинилсульфинил-C-C-алкил, C-C-алкилсульфонил-C-C-алкил, C-C-галогеналкилсульфонил-C-C-алкил, C-C-алкенилсульфонил-C-C-алкил, C-C-алкинилсульфонил-C-C-алкил, гидроксикарбонил-C-C-алкил, (C-C-алкокси)карбонил-C-C-алкил, которыйможетиметьциано- или (C-C-алкокси)карбонильнуюгруппу, (C-C-алкилтио)карбонил-C-C-алкил, аминокарбонил-C-C-алкил, C-C-алкиламинокарбонил-C-C-алкил, ди(C-C-алкил)аминокарбонил-C-C-алкил, ди(C-C-алкил)фосфонил-C-C-алкил, (C-C-алкокси)имино-C-C-алкил, (C-C-алкенилокси)имино-C-C-алкил, C-C-циклоалкил, C-C-циклоалкил-C-C-алкил, фенил, фенил-C-C-алкил, 3- до 7-членныйгетероциклилилигетероциклил-C-C-алкил, причемкаждоециклоалкильноеи каждоегетероциклильноекольцоможетиметькарбонильныйилитиокарбонильныйчленкольца, ипричемкаждоециклоалкильное, фенильноеи гетероциклильноекольцоможетбытьнезамещеннымили

    6.
    发明专利
    未知

    公开(公告)号：AT219774T

    公开(公告)日：2002-07-15

    申请号：AT99920734

    申请日：1999-04-22

    Applicant: BASF AG

    Inventor： ZAGAR CYRILL ,  HAMPRECHT GERHARD ,  MENGES MARKUS ,  MENKE OLAF ,  REINHARD ROBERT ,  SCHAEFER PETER ,  WESTPHALEN KARL-OTTO ,  OTTEN MARTINA ,  WALTER HELMUT

    IPC: C07D231/20 ,  A01N43/74 ,  A01N43/76 ,  A01N43/78 ,  C07D231/16 ,  C07D413/04 ,  C07D417/04 ,  C07D417/14 ,  C07F9/6541 ,  C07F9/6558

    Abstract: Substituted (4-bromopyrazol-3-yl)benzazoles Iand their salts whereR1=H, C1-C4-alkyl, C1-C4-haloalkyl;R2=CN, Cl-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C1-C4-alkylthio, C1-C4-haloalkylthio, C1-C4-alkylsulfinyl, C1-C4-haloalkylsulfinyl, C1-C4-alkylsulfonyl, C1-C4-haloalkylsulfonyl;R4=H, halogen;R5=H, CN, halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy or C1-C4-haloalkoxy;Z=-N=C(XR6)-O- or -N=C(XR6)-S-, attached to alpha via the nitrogen, oxygen or sulfur;X=a chemical bond, oxygen, sulfur, -S(O)-, -SO2-, -NH- or -N(R7)-;R6, R7=Cl-C6-alkyl, Cl-C6-haloalkyl, cyano-Cl-C4-alkyl, hydroxy-C1-C4-alkyl, C3-C6-alkenyl, cyano-C3-C6-alkenyl, C3-C6-haloalkenyl, C3-C6-alkynyl, cyano-C3-C6-alkynyl, C3-C6-haloalkynyl, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-haloalkoxy-C1-C4-alkyl, C3-C4-alkenyloxy-C1-C4-alkyl, C3-C4-alkynyloxy-C1-C4-alkyl, C3-C8-cycloalkyloxy-C1-C4-alkyl, amino-Cl-C4-alkyl, C1-C4-alkylamino-C1-C4-alkyl, di(C1-C4-alkyl)amino-C1-C4-alkyl, Cl-C4-alkylthio-C1-C4-alkyl, C1-C4-haloalkylthio-C1-C4-alkyl, C3-C4-alkenylthio-C1-C4-alkyl, C3-C4-alkynylthio-C1-C4-alkyl, C1-C4-alkylsulfinyl-Cl-C4-alkyl, C1-C4-haloalkylsulfinyl-C1-C4if X=a chemical bond, -O-, -S-, -NH- or -N(R7)-, R6 may also be C1-C4-alkylcarbonyl, C1-C4-haloalkylcarbonyl, C1-C4-alkoxycarbonyl, C1-C4-alkylsulfonyl or C1-C4-haloalkylsulfonyl;if X=a chemical bond, R6 may furthermore be CN, SH, NH2, halogen, -CH2-CH(halogen)-R8, -CH=CH-R8 or -CH=C(halogen)-R8, where R8=COOH, C1-C4-alkoxycarbonyl, C1-C4-alkylthiocarbonyl, CONH2, C1-C4-alkylaminocarbonyl, di(C1-C4-alkyl)aminocarbonyl or di(C1-C4-alkyl)phosphonyl;or R6+R7=an unsubstituted or substituted 1,3-propylene, tetramethylene, pentamethylene or ethyleneoxyethylene chain.Use: As herbicides; for the desiccation/defoliation of plants.

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