公开(公告)号：JPH11335361A

公开(公告)日：1999-12-07

申请号：JP2568099

申请日：1999-02-03

Applicant: BASF AG

Inventor： GYPSER ANDREAS ,  SAUTER HUBERT ,  BAYER HERBERT ,  GEWEHR MARKUS ,  GRAMMENOS WASSILIOS ,  GROTE THOMAS ,  GOETZ ROLAND ,  MUELLER BERND ,  PTOCK ARNE ,  ROEHL FRANZ ,  HARRIES VOLKER ,  AMMERMANN EBERHARD ,  LORENZ GISELA ,  STRATHMANN SIEGFRIED

IPC: A01N43/653 ,  A01N43/76 ,  C07C271/10 ,  C07D249/12 ,  C07D263/44 ,  C07D403/12 ,  C07D413/12

Abstract: PROBLEM TO BE SOLVED: To obtain the subject new compound useful for controlling harmful animals and harmful fungi. SOLUTION: This compound is shown by formula I Y is a halogen, a 1-4C alkyl or the like; (n) is 0-2; E is a group of formula II (V is O or the like); T is O or oxymethylene; Z is a group X [X is a (substituted) heterocyclyl, a (substituted) aryl or the like], N=CWR [W is a (substituted) 1-6C alkyl or the like; R is H, cyano or the like] or the like} such as N-methyl-5-[2-(o-tolyloxymethylene)phenyl]-1,3- oxazolidine-2,4-dione.The compound of formula I, for example, in the case in which it is a compound of formula III, is obtained by a process for acylating an alkyl α- hydroxy-α-phenylacetate with phosgene or the like to give a compound of formula IV and further reacting the compound with a primary amine of the formula H2 N-R αto cause a ring formation and in the case of not advancing the ring formation by the strength of the amine, by a process for hydrolyzing an ester amide of formula V, then treating the resultant substance with an acid and reacting the treated substance with a compound of the formula Z-OH.

公开(公告)号：WO0142185A3

公开(公告)日：2002-05-02

申请号：PCT/EP0011817

申请日：2000-11-27

Applicant: BASF AG ,  GOETZ ROLAND ,  GOETZ NORBERT ,  KEIL MICHAEL ,  WOLF BERND ,  STEINMETZ ADRIAN ,  STAMM ARMIN ,  HENKELMANN JOCHEM

Inventor： GOETZ ROLAND ,  GOETZ NORBERT ,  KEIL MICHAEL ,  WOLF BERND ,  STEINMETZ ADRIAN ,  STAMM ARMIN ,  HENKELMANN JOCHEM

IPC: C07C51/58 ,  C07B61/00 ,  C07C51/60 ,  C07C57/76 ,  C07C63/10

CPC classification number: C07C51/60 ,  C07C63/10

Abstract: The invention relates to a method for producing o-chloromethyl benzoic acid chlorides of formula (I), in which R to R can be the same or different and represent hydrogen C1-C4 alkyl, halogen or trifluoromethyl, by reacting benzo-condensed lactones of formula (II), in which R to R have the above-mentioned meaning, with thionyl chloride. The inventive method is characterized in that the reaction is carried out in the presence of catalytic quantities of a Lewis acid and in the presence of catalytic quantities of a phosphine derivative.

Abstract translation: 本发明涉及一种用于制备式（I），其中R <1> -R <4>相同或不同，并代表氢，C1-C4烷基，卤素或三氟甲基，由反应的邻 - 氯甲基苯甲酰氯 苯并稠合的式（II）的内酯，其中R <1> -R <4>具有上述含义，与亚硫酰氯，其特征在于，一个执行在路易斯酸催化量和催化量的膦的存在下进行反应。

公开(公告)号：WO9940082A3

公开(公告)日：1999-10-21

申请号：PCT/EP9900470

申请日：1999-01-26

Applicant: BASF AG ,  PTOCK ARNE ,  SAUTER HUBERT ,  KIRSTGEN REINHARD ,  GRAMMENOS WASSILIOS ,  GROTE THOMAS ,  GYPSER ANDREAS ,  BAYER HERBERT ,  GEWEHR MARKUS ,  CULLMANN OLIVER ,  MUELLER BERND ,  GOETZ ROLAND ,  ROEHL FRANZ ,  AMMERMANN EBERHARD ,  LORENZ GISELA ,  HARRIES VOLKER ,  STRATHMANN SIEGFRIED

Inventor： PTOCK ARNE ,  SAUTER HUBERT ,  KIRSTGEN REINHARD ,  GRAMMENOS WASSILIOS ,  GROTE THOMAS ,  GYPSER ANDREAS ,  BAYER HERBERT ,  GEWEHR MARKUS ,  CULLMANN OLIVER ,  MUELLER BERND ,  GOETZ ROLAND ,  ROEHL FRANZ ,  AMMERMANN EBERHARD ,  LORENZ GISELA ,  HARRIES VOLKER ,  STRATHMANN SIEGFRIED

IPC: A01N43/56 ,  C07D401/12 ,  C07D401/14 ,  A01N43/48

CPC classification number: C07D401/12 ,  A01N43/56

Abstract: The present invention relates to compounds of the general formula (I) and to the salts thereof, wherein the substituents and the n index have the following values: Q represents -C(=CHCH3)-COOCH3, -C(=CHOCH3)-COOCH3, -C(=NOCH3)-COOCH3 or -C(=NOCH3)-CONH(CH3); R represents hydrogen, halogen, C1-C4 alkyl, C1-C2 halogenalkyl, C1-C4 alkoxy or C1-C2 halogenalkoxy; R represents halogen, C1-C4 alkyl, C1-C2 halogenalkyl or C1-C4 alkoxy; n is 0, 1 or 2, wherein the R substituents can be different when n = 2; and R represents phenyl, pyridyle or pyrimidyle. This invention also relates to agents containing these compounds as well as to the use of said compounds (I) and agents against noxious fungi and animal parasites.

Abstract translation: 通式（I）和它们的盐，其中取代基和指数n具有以下含义的化合物：Q是-C（= CHCH 3）-COOCH 3，-C（= CHOCH 3）-COOCH 3，C（= NOCH 3） - COOCH 3或-C（= NOCH 3）-CONH（CH 3）; R 1是氢，卤素，C 1 -C 4烷基，C 1 -C 2卤代烷基，C 1 -C 4烷氧基或C 1 -C 2卤代烷氧基; R 2是卤素，C 1 -C 4烷基，C 1 -C 2卤代烷基，C 1 -C 4烷氧基; n是0,1或2，其中当n = 2时取代基R 2可以不同; R 3苯基，吡啶基或嘧啶基，含有它们的试剂以及化合物（I）和防治有害真菌和动物害虫的试剂的用途。

公开(公告)号：WO0142182A3

公开(公告)日：2001-12-06

申请号：PCT/EP0011810

申请日：2000-11-27

Applicant: BASF AG ,  GOETZ ROLAND ,  GOETZ NORBERT ,  KEIL MICHAEL ,  WOLF BERND ,  STEINMETZ ADRIAN ,  STAMM ARMIN ,  HENKELMANN JOCHEM

Inventor： GOETZ ROLAND ,  GOETZ NORBERT ,  KEIL MICHAEL ,  WOLF BERND ,  STEINMETZ ADRIAN ,  STAMM ARMIN ,  HENKELMANN JOCHEM

IPC: C07C51/60 ,  C07C63/04 ,  C07C63/10

CPC classification number: C07C51/60 ,  C07C63/04 ,  C07C63/10

Abstract: The invention relates to a method for producing o-chloromethyl benzoic acid chlorides of formula (I), in which R to R can be the same or different and represent hydrogen C1-C4 alkyl, halogen or trifluoromethyl, by reacting benzo-condensed lactones of formula (II), in which R to R have the above-mentioned meaning, with thionyl chloride. The inventive method is characterized in that the reaction is carried out in the presence of catalytic quantities of a boric acid, boric acid anhydride, borate, boronic acid or boronic acid ester and in the presence of catalytic quantities of a quaternary ammonia salt.

Abstract translation: 本发明涉及一种用于制备式（I）的邻 - 氯甲基苯甲酰氯，于R的处理<4>可以<1>是相同的或R不同，并代表氢，C1-C4烷基，卤素或三氟甲基，通过使 苯并稠合的式内酯（II），至R <4>具有R <1>如上所定义，与亚硫酰氯，其特征在于gekennzeichet，在催化量的硼酸，的存在下进行反应硼酸酐，硼酸盐，硼酸或Boronsäureester一个和 催化量的季铵盐。

公开(公告)号：WO9959982A3

公开(公告)日：2000-03-16

申请号：PCT/EP9903003

申请日：1999-05-04

Applicant: BASF AG ,  BAYER HERBERT ,  GOETZ ROLAND ,  KEIL MICHAEL ,  SAUTER HUBERT ,  CULLMANN OLIVER ,  GEWEHR MARKUS ,  GRAMMENOS WASSILIOS ,  GYPSER ANDREAS ,  MUELLER BERND ,  PTOCK ARNE ,  AMMERMANN EBERHARD ,  GROTE THOMAS ,  LORENZ GISELA ,  STRATHMANN SIEGFRIED ,  HARRIES VOLKER

Inventor： BAYER HERBERT ,  GOETZ ROLAND ,  KEIL MICHAEL ,  SAUTER HUBERT ,  CULLMANN OLIVER ,  GEWEHR MARKUS ,  GRAMMENOS WASSILIOS ,  GYPSER ANDREAS ,  MUELLER BERND ,  PTOCK ARNE ,  AMMERMANN EBERHARD ,  GROTE THOMAS ,  LORENZ GISELA ,  STRATHMANN SIEGFRIED ,  HARRIES VOLKER

IPC: C07C251/38 ,  A01N37/40 ,  C07C49/303 ,  C07C251/42 ,  C07C251/50 ,  C07C251/52 ,  C07C251/60 ,  A01N37/50 ,  C07C49/35

CPC classification number: C07C251/60 ,  C07C2601/14

Abstract: The invention relates to bisoximether derivatives of formula (I) in which the variables have the following meanings: R represents halogen, C1-C4 alkyl, C1-C4 alkyl halide, C1-C4 alkoxy or C1-C4 alkoxy halide; n is 1 to 5, whereby the radicals R can be different if n is not equal to 1; R represents C1-C4 alkyl, C3-C6 alkenyl or C3-C6 alkynyl, whereby these groups can be partially or completely halogenated; Q represents C(=CHOCH3)-COOCH3, C(=CHCH3)-COOCH3, C(=NOCH3)-COOCH3 or C(=NOCH3)-CONHCH3. The invention also relates to the salts of the bisoximether derivatives, to methods and intermediate products for the production of these compounds and to their use for combating animal pests and fungicidal pests.

Abstract translation: 式（I），其中各变量具有以下含义的双肟醚衍生物，R <1>为卤素，C1-C4烷基，C1-C4卤代烷基，C1-C4烷氧基或C1-C4卤代烷氧基; n为1至5，其中基团可以是与R <1>不同的，当n不为1; [R <2> C1-C4烷基，C3-C6链烯基或C3-C6炔基，其中这些基团可以部分或完全被卤代; Q为C（= CHOCH 3）-COOCH 3，C（= CHCH 3）-COOCH 3，C（= NOCH 3）-COOCH 3或C（= NOCH 3）-CONHCH 3; 和它们的盐，方法和中间体制备这些化合物和它们用于控制动物害虫和有害真菌中的用途。

公开(公告)号：WO9957111A9

公开(公告)日：2001-03-01

申请号：PCT/EP9902703

申请日：1999-04-22

Applicant: BASF AG ,  WITSCHEL MATTHIAS ,  LANGEMANN KLAUS ,  DEYN WOLFGANG VON ,  MISSLITZ ULF ,  BAUMANN ERNST ,  ENGEL STEFAN ,  MAYER GUIDO ,  NEIDLEIN ULF ,  WAGNER OLIVER ,  GOETZ ROLAND ,  OTTEN MARTINA ,  WESTPHALEN KARL OTTO ,  WALTER HELMUT

Inventor： WITSCHEL MATTHIAS ,  LANGEMANN KLAUS ,  VON DEYN WOLFGANG ,  MISSLITZ ULF ,  BAUMANN ERNST ,  ENGEL STEFAN ,  MAYER GUIDO ,  NEIDLEIN ULF ,  WAGNER OLIVER ,  GOETZ ROLAND ,  OTTEN MARTINA ,  WESTPHALEN KARL-OTTO ,  WALTER HELMUT

IPC: A01N43/08 ,  A01N43/18 ,  A01N43/32 ,  A01N43/36 ,  A01N43/54 ,  A01N43/56 ,  A01N43/653 ,  A01N43/80 ,  A01N43/84 ,  C07D335/06 ,  C07D339/08 ,  C07D409/06 ,  C07D409/08 ,  C07D413/06 ,  C07D413/08

CPC classification number: C07D335/06 ,  A01N43/08 ,  A01N43/18 ,  A01N43/36 ,  A01N43/54 ,  A01N43/56 ,  A01N43/653 ,  A01N43/80 ,  A01N43/84 ,  C07D339/08 ,  C07D409/08

Abstract: The invention relates to cyclohexenondioxothiochromanoyl derivatives of formula (I) wherein the variables have the following meanings: X is oxygen, sulphur, S=O, S(=O)2, CR R , C=O or C=NR ; R is hydrogen, nitro, halogen, cyano, alkyl, alkyl halide, alkoxy, halogenalkoxy, alkylthio, halogenalkylthio, alkylsulfinyl, halogenalkylsulfinyl, alkylsulfonyl, halogenalkylsulfonyl, optionally substituted aminosulfonyl or optionally substituted sulfonylamino; R is alkyl, alkyl halide, alkoxy or halogenalkoxy; R is hydrogen, alkyl or halogen; and R , R are hydrogen, nitro, halogen, cyano, alkyl, alkyl halide, alkoxy, halogenalkoxy, alkylthio, halogenalkylthio, alkylsulfinyl, halogenalkylsulfinyl, alkylsulfonyl, halogenalkylsulfonyl or substituted amino; or R and R together form a chain which can be substituted and/or interrupted by oxygen or sulphur; or an optionally substituted methylide group; l is 0 to 4; R is substituted (3-oxo-1-cyclohexen-2-yl)-carbonyl or substituted (1,3-dioxo-2-cyclohexyl-methylides. The invention also relates to the agriculturally usable salts of said derivatives, to methods for producing the derivatives, to substances containing them, and to the use of the derivatives or substances containing them for combating undesirable plants.

Abstract translation: 式（I），其中各变量具有以下含义的Cyclohexenondioxothiochromanoyl衍生物：X是氧，硫，S = O，S（= O）2，CR <4> - [R <5>，C = O或C = NR < 6>; [R <1>是氢，硝基，卤素，氰基，烷基，卤代烷基，烷氧基，卤代烷氧基，烷硫基，卤代烷硫基，烷基亚磺酰基，卤代烷，烷基磺酰基，卤代烷基磺酰基，任选子氨基磺酰基，磺酰氨基或可能子..; [R <2>是烷基，卤代烷基，烷氧基或卤代烷氧基; [R <3>是氢，烷基或卤素; [R <4>，R <5>为氢，硝基，卤素，氰基，烷基，卤代烷基，烷氧基，卤代烷氧基，烷硫基，卤代烷硫基，烷基亚磺酰基，卤代烷，烷基磺酰基，卤代烷基磺酰基或亚氨基。 或R <4>和R <5>一起形成取代和/或可以被氧或硫中断的链条; 或任选取代的亚甲基团的; 1 0至4; [R <7>取代的（3-氧代-1-环己烯-2-基） - 羰基，或取代的（1,3-二氧代-2-环己基）亚甲基; 及其可农用盐; 一种用于Cyclohexenondioxothiochromanoyl衍生物的制备方法; 含有它们并使用这些衍生物或包含它们用于控制不希望的植物的组合物的组合物。

公开(公告)号：WO0031042A3

公开(公告)日：2000-10-26

申请号：PCT/EP9908516

申请日：1999-11-06

Applicant: BASF AG ,  MAYWALD VOLKER ,  STEINMETZ ADRIAN ,  RACK MICHAEL ,  GOETZ NORBERT ,  GOETZ ROLAND ,  HENKELMANN JOCHEM ,  BECKER HEIKE ,  AISCAR BAYETO JUAN JOSE

Inventor： MAYWALD VOLKER ,  STEINMETZ ADRIAN ,  RACK MICHAEL ,  GOETZ NORBERT ,  GOETZ ROLAND ,  HENKELMANN JOCHEM ,  BECKER HEIKE ,  AISCAR BAYETO JUAN JOSE

IPC: C07D231/20

CPC classification number: C07D231/20

Abstract: The invention relates to a method for producing 1-substituted 5- and/or 3-hydroxypyrazoles of formulas (I) and (II), wherein R represents C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkinyl, C3-C6-cycloalkyl or C1-C4-alkoxy, whereby these groups can be substituted by halogen, C1-C4-alkoxy, phenoxy, C1-C6-alkoxycarbonyl, C1-C6-alkylthiocarbonyl or a cyclic ring system with 3-14 ring atoms, by reacting a 3-alkoxyacrylic acid alkyl ester of formula (III), wherein R , R independently mean C1-C6-alkyl or C3-C6-cycloalky, with a hydrazine of formula (IV), wherein R has the above cited meaning, a) at a pH value of 6-11 to form 5-hydroxypyrazoles of formula (I), or b) at a pH value of 11-14 to form 3-hydroxypyrazoles of formula (II).

Abstract translation: 本发明涉及一种制备1-取代的5和/或所述式（I）和（II），其中R <1> C1-C6-烷基，C2-C6链烯基，C2-C6的3-羟基吡 炔基，C3-C6环烷基或C1-C4烷氧基，其中这些基团被卤素，C1-C4烷氧基，苯氧基，C1-C6烷氧羰基，C1-C6烷硫基羰基或具有3-14个环原子的环系 可以由式（III）的烷基3- alkoxyacrylates被取代，其中R <2>，R <3>独立地是C1-C6烷基或C3-C6环烷基与式的肼（Ⅳ） 其中R <1>具有上面给出的含义，a）在pH值下式I）的6-11（约5-羟基吡唑反应而，或b）在pH为11-14，得到3- hydroxypyrazoles 的式（II）。

公开(公告)号：WO0142183A2

公开(公告)日：2001-06-14

申请号：PCT/EP0011814

申请日：2000-11-27

Applicant: BASF AG ,  STAMM ARMIN ,  GOETZ ROLAND ,  GOETZ NORBERT ,  HENKELMANN JOCHEM ,  KNEUPER HEINZ JOSEF ,  WOLF BERND

Inventor： STAMM ARMIN ,  GOETZ ROLAND ,  GOETZ NORBERT ,  HENKELMANN JOCHEM ,  KNEUPER HEINZ-JOSEF ,  WOLF BERND

IPC: C07C51/58 ,  C07B61/00 ,  C07C51/09 ,  C07C57/76 ,  C07C51/00

CPC classification number: C07C51/09 ,  C07C63/04

Abstract: The invention relates to a method for producing o-chloromethyl benzenecarbonyl chlorides of formula (I), wherein R -R can be the same or different and stand for hydrogen, C1-C4-alkyl, halogen or trifluoromethyl, by converting benzocondensed lactones of formula (II), wherein R -R have the aforementioned meaning, with gaseous or liquid phosgene and the dimers or trimers thereof. The inventive method is characterised in that the conversion is carried out in the presence of catalytical amounts of a Lewis acid and catalytical amounts of a phosgenation catalyst.

Abstract translation: 本发明涉及一种用于制备式（I），其中R <1> -R <4>相同或不同，并代表氢，C1-C4烷基，卤素或三氟甲基，由反应的邻 - 氯甲基苯甲酰氯 苯并稠合的式（II）的内酯，其中R <1> -R <4>具有上述含义，与gesförmigem或液体光气，其二聚体或三聚体，其特征在于，在催化量的路易斯的存在下的反应 进行酸和催化量的光气化催化剂。

公开(公告)号：WO0031041A3

公开(公告)日：2000-11-09

申请号：PCT/EP9908515

申请日：1999-11-06

Applicant: BASF AG ,  MAYWALD VOLKER ,  STEINMETZ ADRIAN ,  RACK MICHAEL ,  GOETZ NORBERT ,  GOETZ ROLAND ,  HENKELMANN JOCHEM ,  BECKER HEIKE ,  AISCAR BAYETO JUAN JOSE

Inventor： MAYWALD VOLKER ,  STEINMETZ ADRIAN ,  RACK MICHAEL ,  GOETZ NORBERT ,  GOETZ ROLAND ,  HENKELMANN JOCHEM ,  BECKER HEIKE ,  AISCAR BAYETO JUAN JOSE

IPC: C07B61/00 ,  C07D231/20

CPC classification number: C07D231/20

Abstract: The invention relates to a method for the production of 1-substituted 5-hydroxypyrazoles of formula (I) wherein R is C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkinyl, C3-C6-cycloalkyl or C1-C4-alkoxy, whereby these groups can be substituted by halogen, C1-C4-alkoxy, phenoxy, C1-C6-alkoxycarbonyl, C1-C6-alkylthiocarbonyl or a cyclic ring system with 3-14 ring atoms, by reacting a) an alkylvinylether of general formula (III) wherein R is C1-C6-alkyl or C3-C6-cycloalkyl, with phosgene (IVa), "diphosgene" (IVb) or "triphosgene" (IVc) to form acid chlorides of formula (V), b) transforming said acid chlorides by eliminating hydrogen chloride into the corresponding 3-alkoxyacrylic acid chloride of formula (VI) and c) reacting said acid chloride with hydrazines of formula (VII) wherein R has the above cited meaning, to form 5-hydroxypyrazoles of formula (I).

Abstract translation: 本发明涉及一种制备1-取代的式（I）的5-羟基吡唑，其中R <1> C1-C6-烷基，C2-C6链烯基，C2-C6炔基，C3-C6环烷基，或 C1-C4烷氧基，其中这些基团被卤素，C1-C4烷氧基，苯氧基，C1-C6烷氧羰基，C1-C6烷硫基羰基或具有3-14个环原子的环系中，可以通过a）取代 通式烷基乙烯基醚（III）其中R <2> C 1 -C 6 - 烷基或C 3 -C 6 - 环烷基与光气（IVa）中，“双光气”（IVb）的或“三光气”（IVc）的下式的酰氯 （V），b）使由消除氯化氢转化成相应的式3-alkoxyacryloyl（VI）这和c）VII）其中R <1>具有上述这表明（与式肼至5的含义 式（I）的-Hydroxypyrazolen。

公开(公告)号：WO9920615A3

公开(公告)日：1999-06-24

申请号：PCT/EP9806299

申请日：1998-10-05

Applicant: BASF AG ,  BAYER HERBERT ,  GEWEHR MARKUS ,  GROTE THOMAS ,  MUELLER BERND ,  SAUTER HUBERT ,  GRAMMENOS WASSILIOS ,  GYPSER ANDREAS ,  PTOCK ARNE ,  GOETZ ROLAND ,  RACK MICHAEL ,  ROEHL FRANZ ,  AMMERMANN EBERHARD ,  HARRIES VOLKER ,  LORENZ GISELA ,  STRATHMANN SIEGFRIED

Inventor： BAYER HERBERT ,  GEWEHR MARKUS ,  GROTE THOMAS ,  MUELLER BERND ,  SAUTER HUBERT ,  GRAMMENOS WASSILIOS ,  GYPSER ANDREAS ,  PTOCK ARNE ,  GOETZ ROLAND ,  RACK MICHAEL ,  ROEHL FRANZ ,  AMMERMANN EBERHARD ,  HARRIES VOLKER ,  LORENZ GISELA ,  STRATHMANN SIEGFRIED

IPC: A01N43/82 ,  A01N43/836 ,  C07C259/14 ,  C07C265/12 ,  C07D271/06 ,  C07D271/07 ,  C07D413/12 ,  C07C239/12 ,  C07C251/38 ,  C07D413/14

CPC classification number: C07D271/07 ,  A01N43/82 ,  C07C259/14 ,  C07C265/12 ,  C07D413/12

Abstract: The invention relates to substituted phenyl carbamates of formula (I), wherein E represents a group A or B, # characterises the bond with the phenyl ring, and R , R , Y, n, T, and Z have the meanings given in the description.

Abstract translation: 本发明涉及式（I），其中E是基团A或B，其中＃为键合到苯基环的特征的取代的苯基氨基甲酸酯，且R <阿尔法>，R <克（B）>，Y，N，T 和Z具有描述中给出的含义。