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公开(公告)号:WO2004050587A2
公开(公告)日:2004-06-17
申请号:PCT/EP0313624
申请日:2003-12-03
Applicant: BASF AG , BASSLER PETER , SIEGEL WOLFGANG , ACHHAMMER GUENTHER , NEGELE ANTON , MENIG HELMUTH , RUPPEL WILHELM , ZEHNER PETER , LUYKEN HERMANN , VOGT VOLKER
Inventor: BASSLER PETER , SIEGEL WOLFGANG , ACHHAMMER GUENTHER , NEGELE ANTON , MENIG HELMUTH , RUPPEL WILHELM , ZEHNER PETER , LUYKEN HERMANN , VOGT VOLKER
CPC classification number: C01C3/0204 , B01J12/007 , B01J15/005 , B01J19/02 , B01J19/2415 , B01J23/866 , B01J2219/00135 , B01J2219/0236
Abstract: The invention relates to a method for producing hydrocyanic acid (HCN) by means of catalytic dehydration of gaseous formamide in a reactor having an inner reactor surface consisting of a steel-containing iron, chromium and nickel. The invention also relates to a reactor for producing hydrocyanic acid by means of catalytic dehydration of gaseous formamide, said reactor having an inner reactor surface consisting of a steel-containing iron, chromium and nickel. The invention further relates to the use of the inventive reactor in a method for producing hydrocyanic acid by means of catalytic dehydration of gaseous formamide.
Abstract translation: 本发明涉及一种通过气态甲酰胺的催化脱水反应器中制备由气态催化脱水具有用于生产氢氰酸的由钢制成的反应器内表面,包括铁和铬和镍,以及一个反应器氢氰酸(HCN) 甲酰胺,其具有由包含铁和铬和镍,以及在方法中的用途本发明的反应器用于通过气态甲酰胺的催化脱水制备氢氰酸的钢的反应器内表面的反应器中。
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公开(公告)号:WO2006131467A3
公开(公告)日:2007-04-19
申请号:PCT/EP2006062751
申请日:2006-05-31
Applicant: BASF AG , DECKERS ANDREAS , SCHNEIDER THOMAS , MENIG HELMUTH
Inventor: DECKERS ANDREAS , SCHNEIDER THOMAS , MENIG HELMUTH
Abstract: The invention relates to a method for producing a solution of hydrocyanic acid salts, said method comprising the following steps: a) a raw gas containing hydrocyanic acid is produced by dehydrating formamide to a formamide transformation percentage of = 97; b) optionally the raw gas obtained in step a) is subjected to acid washing; c) the raw gas obtained in step a) or optionally step b) is then reacted with an aqueous solution of a hydroxide M(OH) x , where M is selected from the group of alkali metals and earth alkali metals and x represents 1 or 2 according to the oxidation number of M.
Abstract translation: 本申请涉及一种用于制备包含的制造通过甲酰胺的脱水含有氰化氢的= 97%甲酰胺转化的原料气体的步骤)氰化物盐的溶液; b)任选地,步骤a)中获得的粗制气体的酸洗; c)以步骤a在步骤b所获得的),或可选地)将原料气体与氢氧化物的水溶液的随后的反应中,M(OH) X SUB>,其中M选自选自碱金属和碱土金属和 X M的氧化态和为1或依赖性的。2
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公开(公告)号:DE102005026326A1
公开(公告)日:2006-12-14
申请号:DE102005026326
申请日:2005-06-07
Applicant: BASF AG
Inventor: DECKERS ANDREAS , SCHNEIDER THOMAS , MENIG HELMUTH
IPC: C01C3/08
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公开(公告)号:DE59705306D1
公开(公告)日:2001-12-13
申请号:DE59705306
申请日:1997-12-09
Applicant: BASF AG
Inventor: FETZER THOMAS , DEMUTH DIRK , RUETTER HEINZ , MENIG HELMUTH , RESCH PETER , RUPPEL WILHELM , WACHE HARRO
IPC: B01J23/72 , C07C45/38 , C07C45/39 , C07C47/127
Abstract: PCT No. PCT/EP97/06856 Sec. 371 Date Jun. 16, 1999 Sec. 102(e) Date Jun. 16, 1999 PCT Filed Dec. 23, 1997 PCT Pub. No. WO98/28251 PCT Pub. Date Jul. 2, 1998In a process for preparing carbonyl compounds of the formula where R1 is a hydrogen atom or an alkyl radical having from 1 to 3 carbon atoms, R2 is a hydrogen atom or a radical of the formula where R3 is a hydrogen atom or together with R4 is an oxygen atom, R4 is the radical OR6 or together with R3 is an oxygen atom, R5 is a hydrogen atom, an alkyl radical having from 1 to 8 carbon atoms or a cyclohexyl or cyclopentyl radical and R6 is an alkyl radical having from 1 to 4 carbon atoms, a cyclohexyl or cyclopentyl radical or a radical of the formula -CH2-CHO or -CH2-CH2-O-CH2-CHO, by gas-phase oxidation of methanol or alcohols of the formula where R1 and R5 are as defined above and R7 is a hydrogen atom or a radical OR8 and R8 is a hydrogen atom, an alkyl radical having from 1 to 4 carbon atoms, a cyclohexyl or cyclopentyl radical or a radical for the formula -CH2-CH2-OH or -CH2-CH2-O-CH2-CH2-OH, using an oxygen-containing gas in the presence of copper- and/or silver-containing catalysts and an amount of a phosphorus compound which is volatile under the reaction conditions which is such that the amount of phosphorus (calculated as P) is up to 20 ppm, based on the weight of alcohol used, the phosphorus is introduced within the catalyst bed.
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公开(公告)号:CA2610981A1
公开(公告)日:2006-12-14
申请号:CA2610981
申请日:2006-05-31
Applicant: BASF AG
Inventor: SCHNEIDER THOMAS , MENIG HELMUTH , DECKERS ANDREAS
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公开(公告)号:AU2006256840A1
公开(公告)日:2006-12-14
申请号:AU2006256840
申请日:2006-05-31
Applicant: BASF AG
Inventor: MENIG HELMUTH , SCHNEIDER THOMAS , DECKERS ANDREAS
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公开(公告)号:DE10144891A1
公开(公告)日:2003-03-27
申请号:DE10144891
申请日:2001-09-12
Applicant: BASF AG
Inventor: KLEIN OLIVER , NEGELE ANTON , RUPPEL WILHELM , VOGT VOLKER , SCHNEIDER THOMAS , ACHHAMMER GUENTHER , RESCH PETER , SIEGEL WOLFGANG , BASLER PETER , MENIG HELMUTH
Abstract: Production of hydrogen cyanide and water comprises contacting gaseous formamide with a catalyst at 350-800 deg C in a flow-type reactor with electric resistance heating. An Independent claim is also included for the apparatus for carrying out the above process, comprising either: (a) a flow reactor containing one or more catalyst-coated heating elements that can be heated by means of a voltage source; or (b) one or more flow tubes that can be heated by means of a voltage source and contain a bed of catalyst.
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公开(公告)号:AU2003293755B2
公开(公告)日:2009-12-24
申请号:AU2003293755
申请日:2003-12-03
Applicant: BASF AG
Inventor: BASSLER PETER , ZEHNER PETER , LUYKEN HERMANN , MENIG HELMUTH , ACHHAMMER GUNTHER , RUPPEL WILHELM , VOGT VOLKER , SIEGEL WOLFGANG , NEGELE ANTON
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公开(公告)号:MX2007015207A
公开(公告)日:2008-02-22
申请号:MX2007015207
申请日:2006-05-31
Applicant: BASF AG
Inventor: SCHNEIDER THOMAS , MENIG HELMUTH , DECKERS ANDREAS
Abstract: La invencion se relaciona con un metodo para producir una solucion de sales de acido cianhidrico, el metodo comprendiendo los siguientes pasos: a) se produce un gas crudo que contiene acido cianhidrico, deshidratando formamida a un porcentaje de transformacion de formamida de =97; b) opcionalmente el gas crudo obtenido en el paso a) se somete a lavado con acido; c) el gas crudo obtenido en el paso a) u opcionalmente el paso b) luego se hace reaccionar con una solucion acuosa de un hidroxido M(OH)x, en donde M se selecciona del grupo de metales alcalinos y metales alcalino terreos y x representa 1 o 2 de conformidad con el numero de oxidacion de M.
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公开(公告)号:DE59909810D1
公开(公告)日:2004-07-29
申请号:DE59909810
申请日:1999-02-25
Applicant: BASF AG
Inventor: DEMUTH DIRK , FETZER THOMAS , PRATSCH VOLKER , WENDRICH THOMAS , MENIG HELMUTH , WAMBACH LUDWIG , HARTH KLAUS
Abstract: Carbonyl compounds of the formulawhere R1 is a hydrogen atom or an alkyl radical having from 1 to 3 carbon atoms, R2 is a hydrogen atom, an unsubstituted or C1-C3-alkyl-monosubstituted to -trisubstituted C2-C4-alkenyl radical or a radical of the formulawhere R3 is a hydrogen atom or together with R4 is an oxygen atom, R4 is the radical OR6 or together with R3 is an oxygen atom, R5 is a hydrogen atom, an alkyl radical having from 1 to 8 carbon atoms, an unsubstituted or C1-C3-alkyl-monosubstituted to -trisubstituted C2-C4-alkenyl radical or a cyclohexyl or cyclopentyl radical and R6 is an alkyl radical having from 1 to 4 carbon atoms, a cyclohexyl or cyclopentyl radical or a radical of the formula -CH2-CHO or -CH2-CH2-O-CH2-CHO, are prepared by gas-phase oxidation of methanol or alcohols of the formulawhere R1 and R5 are as defined above, by means of an oxygen-containing gas in the presence of copper- and/or silver-containing catalysts, the catalyst system used comprising at least one phosphorus-containing copper- and/or silver-containing catalyst.
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