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公开(公告)号:ES2225142T3
公开(公告)日:2005-03-16
申请号:ES00931194
申请日:2000-05-11
Applicant: BASF AG
Inventor: JUNGLING STEPHAN , SCHADE CHRISTIAN , GAUSEPOHL HERMANN , WARZELHAN VOLKER , MOORS RAINER , SCHACH HANSJORG
IPC: C08F2/06 , C08F2/38 , C08F4/60 , C08F4/62 , C08F2/00 , C08F4/639 , C08F4/642 , C08F4/646 , C08F36/04 , C08F236/10 , C08F279/02 , C08F297/04 , C08L55/02
Abstract: Procedimiento para la polimerización de dienos en un disolvente, que contiene monómeros vinilaromáticos, caracterizado porque la polimerización se lleva a cabo en presencia de a) un compuesto organometálico de Ti, Zr, Hf, V, Nb, Ta, Cr, Mo o de W a modo de catalizador, b) un ácido de Lewis a modo de cocatalizador, c) en caso dado de un agente de alquilación y d) en caso dado de un regulador.
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公开(公告)号:ES2211047T3
公开(公告)日:2004-07-01
申请号:ES99907420
申请日:1999-01-26
Applicant: BASF AG
Inventor: SCHADE CHRISTIAN , GAUSEPOHL HERMANN , FISCHER WOLFGANG , MOORS RAINER , WARZELHAN VOLKER
IPC: C08F4/42 , C08F279/02 , C08F287/00
Abstract: A process prepares impact-modified thermoplastic molding compositions which comprise a soft phase made from a rubber dispersed in a hard matrix composed of vinylaromatic monomers, where the hard matrix is prepared by anionic polymerization in the presence of a metal alkyl compound or a metal aryl compound of an element of the second or third main group, or of the second subgroup, of the Periodic Table.
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公开(公告)号:ES2127576T3
公开(公告)日:1999-04-16
申请号:ES95940174
申请日:1995-11-14
Applicant: BASF AG
Inventor: MC KEE GRAHAM EDMUND , MOORS RAINER , HECKMANN WALTER , LARBIG HARALD , ROSENAU BERNHARD
IPC: C08L15/00 , C08F2/18 , C08F220/12 , C08F265/04 , C08F285/00 , C08L51/00
Abstract: PCT No. PCT/EP95/04476 Sec. 371 Date May 12, 1997 Sec. 102(e) Date May 12, 1997 PCT Filed Nov. 14, 1995 PCT Pub. No. WO96/15164 PCT Pub. Date May 23, 1996In the preparation of a rubber-modified molding material, in a first stage, a first mixture (A) contains at least one alkyl acrylate or methacrylate (a) of the formula (I) (I) where R1 is hydrogen or methyl and R2 is alkyl of 1 to 32 carbon atoms, if required a first monomer (b) having two or more double bonds and, if required, also a second monomer (c) or a plurality thereof is polymerized, preferably with free radicals, to give a rubber (B), in a second stage, a third monomer (d) or a plurality thereof is added to the resulting rubber (B) to form a second mixture (C), whereby the rubber (B) is dissolved or swollen in the third monomer (d), with or with the addition of a solvent, and in a third stage, the second mixture (C) formed is polymerized with free radicals to give the rubber-modified molding material (D), and the mixture is reacted at >120 DEG C., during or after this polymerization, with a compound (e) which contains at least two peroxy groups.
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公开(公告)号:ES2174648T3
公开(公告)日:2002-11-01
申请号:ES99959328
申请日:1999-11-25
Applicant: BASF AG
Inventor: SCHWABEN HANS-DIETER , MOORS RAINER , MODERSHEIM NORBERT
IPC: C08F279/02 , C08L9/00 , C08L25/06
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公开(公告)号:BR9907648A
公开(公告)日:2002-04-30
申请号:BR9907648
申请日:1999-01-26
Applicant: BASF AG
Inventor: SCHADE CHRISTIAN , GAUSEPOHL HERMANN , FISCHER WOLFGANG , MOORS RAINER , WARZELHAN VOLKER
IPC: C08F4/42 , C08F279/02 , C08F287/00
Abstract: A process prepares impact-modified thermoplastic molding compositions which comprise a soft phase made from a rubber dispersed in a hard matrix composed of vinylaromatic monomers, where the hard matrix is prepared by anionic polymerization in the presence of a metal alkyl compound or a metal aryl compound of an element of the second or third main group, or of the second subgroup, of the Periodic Table.
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公开(公告)号:AU1654500A
公开(公告)日:2000-06-19
申请号:AU1654500
申请日:1999-11-25
Applicant: BASF AG
Inventor: SCHWABEN HANS-DIETER , MOORS RAINER , MODERSHEIM NORBERT
IPC: C08F279/02 , C08L9/00 , C08L25/06
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公开(公告)号:DE19828104A1
公开(公告)日:1999-12-30
申请号:DE19828104
申请日:1998-06-24
Applicant: BASF AG
Inventor: SCHADE CHRISTIAN , GAUSEPOHL HERMANN , FISCHER WOLFGANG , MOORS RAINER , WARZELHAN VOLKER
IPC: C08J5/00 , C08F4/50 , C08F279/02 , C08F287/00 , C08F297/04 , C08L51/04 , C08L91/00 , C08F4/52 , C08F212/08 , C08F236/06
Abstract: A process for the production of impact-modified thermoplastic moulding materials with a rubber-based soft phase dispersed in a hard matrix derived from vinyl-aromatic monomers, in which these monomers are subjected to anionic polymerization in presence of a metal-organyl compound of an element of Main Group II or III or Sub-Group II.
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公开(公告)号:ES2124596T3
公开(公告)日:1999-02-01
申请号:ES95937073
申请日:1995-11-14
Applicant: BASF AG
Inventor: MC KEE GRAHAM EDMUND , GAUSEPOHL HERMANN , MOORS RAINER , ROSENAU BERNHARD , HECKMANN WALTER
IPC: C08F265/04 , C08F20/12 , C08F285/00
Abstract: In a process for producing modified rubber moulding materials, a first mixture (A) that contains at least one alkyl acrylate or methacrylate (a) having the general formula (I), in which R stands for a hydrogen atom or a methyl group and R stands for an alkyl group with 1 to 32 carbon atoms, a first monomer (b) with two or more double bonds and optionally a second or several other monomers (c), is in a first step polymerised into a rubber (B), preferably together with free radicals. In a second step, the thus obtained rubber (B) is dissolved into or swollen with a third or several other monomers (d), optionally with admixture of a solvent, and in a third step, the second mixture (C) obtained by dissolving or swelling is polymerised into the modified rubber moulding material (D).
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公开(公告)号:DE59901025D1
公开(公告)日:2002-04-25
申请号:DE59901025
申请日:1999-11-25
Applicant: BASF AG
Inventor: SCHWABEN HANS-DIETER , MOORS RAINER , MOEDERSHEIM NORBERT
IPC: C08F279/02 , C08L9/00 , C08L25/06
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10.
公开(公告)号:AU4920900A
公开(公告)日:2000-12-12
申请号:AU4920900
申请日:2000-05-11
Applicant: BASF AG
Inventor: JUNGLING STEPHAN , SCHADE CHRISTIAN , GAUSEPOHL HERMANN , WARZELHAN VOLKER , MOORS RAINER , SCHACH HANSJORG , QUEISSER JOACHIM , LUINSTRA GERRIT , DEMETER JURGEN
IPC: C08F2/00 , C08F2/06 , C08F2/38 , C08F4/60 , C08F4/62 , C08F4/639 , C08F4/642 , C08F4/646 , C08F36/04 , C08F236/10 , C08F279/02 , C08F297/04 , C08L55/02
Abstract: In a process for polymerizing dienes in a solvent comprising vinylaromatic monomers, the polymerization is carried out in the presence of a metal compound of Ti, Zr, Hf, V, Nb, Ta, Cr, Mo or W as catalyst and a Lewis acid as cocatalyst and, if desired, an alkylating agent and, if desired, a regulator. This process can be used for preparing high-impact polystyrene, acrylonitrile-butadiene-styrene copolymers or methyl methacrylate-butadiene-styrene copolymers.
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